Search results for "OPTICS"
showing 10 items of 10033 documents
Raman and optical reflection spectra of germanate and silicate glasses
2005
Abstract Germanate and phosphosilicate glasses made in oxygen surplus conditions were studied by Raman and optical reflection methods. We found that the optical reflection spectra of the germanate glasses are quite similar to the one those of a GeO 2 crystal with the α-quartz structure. The reflection of phosphosilicate glasses is very close to silica glass-related spectra. Hence, the determining influence of the tetrahedral structure on reflection spectra is revealed. The Raman spectra of germanate samples are similar to those reported the one known in the literature. Octahedral entities, namely bands similar to stishovite vibration modes, were difficult to detect in phosphosilicate glasse…
Analytical characteristics, applications and perspectives in thermal lens spectrometry
1993
Abstract The following selected aspects of thermal lens spectrometry are briefly outlined: fundamentals, sensitivity and background noise, detection approaches, flowing samples, multi-wavelength experiments, thermal lens circular dichroism, associated colateral phenomena and physico-chemical applications and requirements of analytical procedures. The state-of-the-art and problems encountered are discussed.
Nano-lithography by electron exposure using an Atomic Force Microscope
1999
Abstract We have used a conductive Atomic Force Microscope (AFM) tip to expose a very thin resist film. An exposing current of low energy electrons was induced from the tip to the substrate by applying a small bias voltage. Uniform resist films as thin as 10 nm were fabricated using the Langmuir–Blodgett technique. To orient the defined pattern and to make electrical connections a special larger scale alignment structure was first defined by conventional electron beam lithography, either directly in the Langmuir–Blodgett resist film or in a separate first lift-off process with a thicker resist. The results from the one resist process gave conducting 50 nm lines with a 60 A thick vacuum depo…
Visible-NIR reflectance spectroscopy and manifold learning methods applied to the detection of fungal infections on citrus fruit
2015
Abstract The development of systems for automatically detecting decay in citrus fruit during quality control is still a challenge for the citrus industry. The feasibility of reflectance spectroscopy in the visible and near infrared (NIR) regions was evaluated for the automatic detection of the early symptoms of decay caused by Penicillium digitatum fungus in citrus fruit. Reflectance spectra of sound and decaying surface parts of mandarins cv. ‘Clemenvilla’ were acquired in two different spectral regions, from 650 nm to 1050 nm (visible–NIR) and from 1000 nm to 1700 nm (NIR), pointing to significant differences in spectra between sound and decaying skin for both spectral ranges. Three diffe…
Numerical 3D study of FZ growth: dependence on growth parameters and melt instability
2001
Three-dimensional modelling of the floating zone (needle-eye) crystal growth process is carried out to analyse numerically the stability of the melt flow and the influence of the crystal rotation rate and inductor slit width on the 3D flow field and on the grown crystal resistivity. The unsteadiness of the melt is simulated and it is found that for the considered growth parameters a steady-state flow can be a reasonable approximation to the unsteady melt motion. The parametric studies have shown that increasing the rotation rate essentially changes the flow pattern and weakens the rotational striations, while the inductor slit width has a more local influence on these characteristics.
Photokinetic examination of (Z,E,E)-4,4′-distyrylazobenzene
1995
Abstract 4,4′-Distyrylazobenzenes demonstrate a photokinetic equilibrium and a superimposed thermal backward reaction in which the absorption coefficient of one of the partners in the equilibrium is principally unknown. Using the dependence of the photostationary state on the irradiation intensity, the photochemical quantum yields ϕ 1 A and ϕ 2 B were determined, as well as the thermal rate constant k , as a function of the irradiation and observation wavelengths. Experimental difficulties and the wavelength dependence of ϕ 1 A and ϕ 2 B are discussed.
Thioxanthone: on the shape of the first absorption band
2010
The equilibrium ground state geometry of thioxanthone (TX) has been investigated and its effect on the vertical excitation energies and photophysical behaviour has been explained. In line with this purpose, the first absorption band of TX has been simulated and analysed in detail. The calculations show that TX is planar, C(2v) symmetric in its ground state. The energy of the low-lying excited states seems to be rather insensitive along the butterfly motion coordinate. The shoulder in the first absorption band (at around 3.43 eV) is shown to be caused by vibrational progression of various in-plane modes and does not justify the hypothesis that two photophysically distinct conformers of TX ex…
Instrument Characterization and First Application of the Single Particle Analysis and Sizing System (SPASS) for Atmospheric Aerosols
2005
We describe here the instrumental setup and first experiments with the mobile single particle analysis and sizing system (SPASS) for the on-line characterization of single atmospheric aerosol particles. Aerosols are introduced into the SPASS via a differentially pumped particle inlet system using an aerodynamic lens that forms a narrow particle beam. The particles are sized with a two-laser velocimeter and subsequently desorbed and ionized with a high-power pulsed Nd:YAG laser operating at 266 nm. Positive and negative ions formed are simultaneously detected in a bipolar time-of-flight mass spectrometer. Thus, the size and chemical composition of single aerosol particles can be characterize…
Cluster formation and rheology of photoreactive nanoparticle dispersions.
2008
We show how photocrosslinking of small nanoparticles within a very dilute colloidal dispersion leads to the formation of large fractal particle clusters, which have a strong influence on the viscosity of the dispersion although the overall solid content is well below 5 wt %. Furthermore, the solvent plays an important role because of its function as an optical filter, for example, in toluene only photocrosslinking but no photocleavage takes place. Therefore, a diffusion-controlled cluster growth mechanism, leading to clusters with low fractal dimension, is expected; on the other hand, in tetrahydrofuran the photoreaction is partially reversible. Therefore, the cluster growth in this case is…
Material quality characterization of CdZnTe substrates for HgCdTe epitaxy
2006
Cd1−xZnxTe (CZT) substrates were studied to investigate their bulk and surface properties. Imperfections in CZT substrates affect the quality of Hg1−xCdxTe (MCT) epilayers deposited on them and play a role in limiting the performance of infrared (IR) focal plane arrays. CZT wafers were studied to investigate their bulk and surface properties. Transmission and surface x-ray diffraction techniques, utilizing both a conventional closed-tube x-ray source as well as a synchrotron radiation source, and IR transmission micro-spectroscopy, were used for bulk and surface investigation. Synchrotron radiation offers the capability to combine good spatial resolution and shorter exposure times than conv…