Search results for "ORBIT"
showing 10 items of 1104 documents
Bioactive Compounds and Antioxidant Properties with Involved Mechanisms of Eugenia involucrata DC Fruits
2022
In this study, the phytochemical profile and the antioxidative properties of Eugenia involucrata fruits were evaluated. Spectrophotometric assays indicated that these berries are a rich source of polyphenols with very high radical-scavenging and metal-reducing activities. High-performance liquid chromatography–Orbitrap analysis was able to carry out the annotation of 36 different compounds, mainly belonging to the flavonol, flavan-3-ol, and anthocyanin families. Antioxidant activity of the fruit extract was evaluated in a cell-based lipid peroxidation model. Obtained data showed that the extract, at very low concentration, was able to prevent oxidative damage in HepG2 cells exposed to oxida…
Electronic structure of tetraphenyldithiapyranylidene : A valence effective Hamiltonian theoretical investigation
1992
We present a theoretical investigation of the electronic structure of tetraphenyldithiapyranylidene (DIPSΦ4) using the nonempirical valence effective Hamiltonian (VEH) method. Molecular geometries are optimized at the semiempirical PM3 level which predicts an alternating nonaromatic structure for the dithiapyranylidene (DIPS) framework. The VEH one‐electron energy level distribution calculated for DIPSΦ4 is presented as a theoretical XPS simulation and is analyzed by comparison to the electronic structure of its molecular components DIPS and benzene. The theoretical VEH spectrum is found to be fully consistent with the experimental solid‐state x‐ray photoelectron spectroscopy (XPS) spectrum…
Joint User Association and Dynamic Beam Operation for High Latitude Muti-beam LEO Satellites
2021
In Low Earth Orbit (LEO) satellites, which run in polar orbit, the area of overlap among beams becomes wider as the latitude of satellites increases, which leads to intolerable interference and extra energy consumption. To minimize the onboard power with QoS requirements, we propose an energy optimization model with considering power allocation, user association and dynamic beam ON/OFF operation jointly. Moreover, the frequent beam ON/OFF operations lead to the large number of user handovers, so handover cost is also considered in the model. The original problem is decomposed into two levels due to the high coupling of variables and the successive convex approximation is employed. A low com…
Target Quantification and Semi-Target Screening of Undesirable Substances in Pear Juices Using Ultra-High-Performance Liquid Chromatography-Quadrupol…
2020
Fruit juices are common products in modern diets due to the supply of vegetal nutrients combined with its tastiness. Nevertheless, potential contaminants, such as mycotoxins and pesticides, can be present in commercial products due to a potential carry-over. Therefore, the aim of this study was to investigate for the first time the presence of 14 Fusarium mycotoxins using a quick, easy, cheap, effective, rugged, and safe (QuEChERS)-based extraction followed by an ultra-high-performance liquid chromatography-quadrupole Orbitrap high-resolution mass spectrometry in 21 pear juice samples from Italian markets. Up to nine different mycotoxins were detected, particularly an extensive presence of …
Spatially localized solutions of the Hammerstein equation with sigmoid type of nonlinearity
2016
Abstract We study the existence of fixed points to a parameterized Hammerstein operator H β , β ∈ ( 0 , ∞ ] , with sigmoid type of nonlinearity. The parameter β ∞ indicates the steepness of the slope of a nonlinear smooth sigmoid function and the limit case β = ∞ corresponds to a discontinuous unit step function. We prove that spatially localized solutions to the fixed point problem for large β exist and can be approximated by the fixed points of H ∞ . These results are of a high importance in biological applications where one often approximates the smooth sigmoid by discontinuous unit step function. Moreover, in order to achieve even better approximation than a solution of the limit proble…
3 He NMR studies on helium-pyrrole, helium-indole, and helium-carbazole systems: a new tool for following chemistry of heterocyclic compounds
2014
The 3He nuclear magnetic shieldings were calculated for free helium atom and He–pyrrole, He–indole, and He–carbazole complexes. Several levels of theory, including Hartree–Fock (HF), Second-order Moller-Plesset Perturbation Theory (MP2), and Density Functional Theory (DFT) (VSXC, M062X, APFD, BHandHLYP, and mPW1PW91), combined with polarization-consistent pcS-2 and aug-pcS-2 basis sets were employed. Gauge-including atomic orbital (GIAO) calculated 3He nuclear magnetic shieldings reproduced accurately previously reported theoretical values for helium gas. 3He nuclear magnetic shieldings and energy changes as result of single helium atom approaching to the five-membered ring of pyrrole, indo…
K-band spectroscopy of IGR J16358-4726 and IGR J16393-4643: two new symbiotic X-ray binaries
2009
Symbiotic X-ray Binaries (SyXBs) are a recently discovered subclass of Low Mass X-ray Binaries. Their growing number makes them an important evolutionary channel of X-ray Binaries. Our goal is to perform spectral analysis and classification of the proposed counterparts to IGR J16358-4726 and IGR J16393-4643 and to establish their nature as X-ray systems. We used the ESO/UT1 ISAAC spectrograph to observe the proposed counterparts to the two sources, obtaining K-band medium resolution spectra (R = 500) with a S/N > 140. Data reduction was performed with the standard procedure. We classified them by means of comparison with published atlases. We performed SED fitting in order to refine the …
Detailed study of the X-ray and optical/UV orbital ephemeris of X1822-371
2011
Recent studies of the optical/UV and X-ray ephemerides of X1822-371 have found some discrepancies in the value of the orbital period derivative. Because of the importance of this value in constraining the system evolution, we comprehensively analyse all the available optical/UV/X eclipse times of this source to investigate the origin of these discrepancies. We collected all previously published X-ray eclipse times from 1977 to 2008, to which we added the eclipse time observed by Suzaku in 2006. This point is very important to cover the time gap between the last RXTE eclipse time (taken in 2003) and the most recent Chandra eclipse time (taken in 2008). Similarly we collected the optical/UV e…
Correlated optical/X-ray variability in the high-mass X-ray binary SAX J2103.5+4545
2009
SAX J2103.5+4545 is the Be/X-ray binary with the shortest orbital period. It shows extended bright and faint X-ray states that last for a few hundred days. The main objective of this work is to investigate the relationship between the X-ray and optical variability and to characterise the spectral and timing properties of the bright and faint states. We have found a correlation between the spectral and temporal parameters that fit the energy and power spectra. Softer energy spectra correspond to softer power spectra. That is to say, when the energy spectrum is soft the power at high frequencies is suppressed. We also present the results of our monitoring of the Halpha line of the optical cou…
New ephemeris of the ADC source 2A 1822-371: a stable orbital-period derivative over 30 years
2010
We report on a timing of the eclipse arrival times of the low mass X-ray binary and X-ray pulsar 2A 1822-371 performed using all available observations of the Proportional Counter Array on board the Rossi X-ray Timing Explorer, XMM-Newton pn, and Chandra. These observations span the years from 1996 to 2008. Combining these eclipse arrival time measurements with those already available covering the period from 1977 to 1996, we obtain an orbital solution valid for more than thirty years. The time delays calculated with respect to a constant orbital period model show a clear parabolic trend, implying that the orbital period in this source constantly increases with time at a rate $\dot P_orb = …