Search results for "OXIDATION"

showing 10 items of 1913 documents

MoSi2 laser cladding—a comparison between two experimental procedures: Mo–Si online combination and direct use of MoSi2

2001

International audience; There are very strong interests in developing low density advanced material systems for service at temperatures up to 1300°C. These materials should mainly have moderate fracture toughness at low and intermediate temperatures and should exhibit oxidation resistant behaviour. The intermetallic compound, MoSi2 has been considered to be an attractive candidate due to its melting point (2030°C) and excellent oxidation resistance at high temperatures. In this paper, we compare the results obtained with two different techniques for laser cladding, one using an online combination between Mo and Si powders, the second using direct injection of the MoSi2 powder.

TechnologyMaterials scienceOxidation resistantIntermetallic[ PHYS.COND.CM-MS ] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Laser02 engineering and technology01 natural scienceslaw.inventionFracture toughnesslaw0103 physical sciencesLow densityElectrical and Electronic EngineeringComposite materialOxidation resistance010302 applied physicsMaterial system021001 nanoscience & nanotechnologyLaserAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsMelting point[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Powders0210 nano-technology
researchProduct

Evaluation of Rhodamine B Photocatalytic Degradation over BaTiO

2021

This research was funded by UIDB/50006/2020 with funding from FCT/MCTES through national funds and from the Institute of General and Ecological Chemistry of Lodz University of Technology. Susana L.H. Rebelo and Iwona Kuźniarska-Biernacka thank FCT (Fundação para a Ciência e Tecnologia) for funding through program DL 57/2016–Norma transitória (RE-QUIMTE/EEC2018/30 (SLHR) and REQUIMTE/EEC2018/14 (IKB)).

TechnologyMaterials scienceScanning electron microscopeInfrared spectroscopyImpedance spectroscopy02 engineering and technology010402 general chemistryPerovskite01 natural sciencesArticlephotocatalystschemistry.chemical_compoundRhodamine BPhoto-oxidationGeneral Materials ScienceWater treatmentCeramicPhotodegradationperovskiteMicroscopyQC120-168.85impedance spectroscopyTFerroelectric ceramicsQH201-278.5water treatmentEngineering (General). Civil engineering (General)021001 nanoscience & nanotechnologyphoto-oxidationTK1-99710104 chemical sciencesDielectric spectroscopyDescriptive and experimental mechanicschemistryvisual_artPhotocatalystsPhotocatalysisvisual_art.visual_art_medium:NATURAL SCIENCES [Research Subject Categories]Electrical engineering. Electronics. Nuclear engineeringTA1-20400210 nano-technologyNuclear chemistryMaterials (Basel, Switzerland)
researchProduct

Impact of Si on the high-temperature oxidation of AlCr(Si)N coatings

2022

The resistance of wear protective coatings against oxidation is crucial for their use at high temperatures. Here, three nanocomposite AlCr(Si)N coatings with a fixed Al/Cr atomic ratio of 70/30 and a varying Si-content of 0 at.%, 2.5 at.% and 5 at.% were analyzed by differential scanning calorimetry, thermogravimetric analysis and X-ray in order to understand the oxidation behavior depending on their Si-content. Additionally, a partially oxidized AlCrSiN coating with 5 at.% Si on a sapphire substrate was studied across the coating thickness by depth-resolved cross-sectional X-ray nanodiffraction and scanning trans-mission electron microscopy to investigate the elemental composition, morphol…

TechnologyThermogravimetric analysisSTRESSMaterials sciencePolymers and PlasticsAnnealing (metallurgy)Materials SciencenanomateriaalitOxideTHERMAL-STABILITYMaterials Science Multidisciplinaryengineering.materialoxidation behaviourchemistry.chemical_compoundDifferential scanning calorimetryCoatingResidual stressMaterials ChemistrykomposiititpinnoitteetScience & TechnologyAlCrSiNNanocompositenanocompositeMechanical EngineeringhapettuminenMetals and AlloysMECHANICAL-PROPERTIESEVOLUTIONcross-sectional X-ray nanodiffractionALChemical engineeringchemistryMechanics of MaterialsCeramics and CompositesengineeringMetallurgy & Metallurgical EngineeringAtomic ratioALCRN COATINGSRESISTANCEBEHAVIORSYSTEMNANOCOMPOSITE COATINGScathodic arcJournal of Materials Science & Technology
researchProduct

Oxidation State and Local Structure of Chromium Ions in LaOCl

2021

This research is funded by the Latvian Council of Science, project “Novel transparent nanocomposite oxyfluoride materials for optical applications”, project No. LZP-2018/1-0335. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017- TeamingPhase2 under grant agreement No. 739508, project CAMART2.

Technologyelectron-nuclear double resonance (ENDOR)Materials sciencechemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesArticlelaw.inventionChromiumLattice constantX-ray photoelectron spectroscopyLaOCl; chromium; X-ray photoelectron spectroscopy (XPS); X-ray absorption spectroscopy; electron paramagnetic resonance (EPR); electron-nuclear double resonance (ENDOR)lawOxidation state:NATURAL SCIENCES:Physics [Research Subject Categories]General Materials ScienceElectron paramagnetic resonanceMicroscopyQC120-168.85X-ray absorption spectroscopyTReducing atmosphereQH201-278.5X-ray absorption spectroscopy600X-ray photoelectron spectroscopy (XPS)Engineering (General). Civil engineering (General)021001 nanoscience & nanotechnologyXANESTK1-99710104 chemical sciences3. Good healthLaOClelectron paramagnetic resonance (EPR)Descriptive and experimental mechanicschemistry13. Climate actionPhysical chemistryElectrical engineering. Electronics. Nuclear engineeringchromiumTA1-20400210 nano-technologyddc:600Materials
researchProduct

Glutathione regulates telomerase activity in 3T3 fibroblasts.

2004

Changes in telomerase activity have been associated either with cancer, when activity is increased, or with cell cycle arrest when it is decreased. We report that glutathione, a physiological antioxidant present at high intracellular concentrations, regulates telomerase activity in cells in culture. Telomerase activity increases in 3T3 fibroblasts before exponential cell growth. The peak of telomerase activity takes place 24 h after plating and coincides with the maximum levels of glutathione in the cells. When cells are treated with buthionine sulfoximine, which decreases glutathione levels in cells, telomerase activity decreases by 60%, and cell growth is delayed. Glutathione depletion in…

TelomeraseAntioxidantCell cycle checkpointTime FactorsCell divisionmedicine.medical_treatmentBlotting WesternImmunoblottingE2F4 Transcription FactorBiochemistryGene Expression Regulation Enzymologicchemistry.chemical_compoundMicemedicineAnimalsButhionine sulfoximineColoring AgentsMolecular BiologyButhionine SulfoximineTelomeraseInhibitor of Differentiation Protein 2Cell growthCell CycleCell BiologyGlutathione3T3 CellsTrypan BlueCell cycleFibroblastsFlow CytometryMolecular biologyGlutathioneDNA-Binding ProteinsRepressor ProteinschemistryOxidation-ReductionCell DivisionTranscription FactorsThe Journal of biological chemistry
researchProduct

ChemInform Abstract: Synthesis and Isolation of Enantiomerically Enriched Cyclopenta[b]benzofurans Based on Products from Anodic Oxidation of 2,4-Dim…

2015

Tetramer (I) is obtained by anodic oxidation of 2,4-dimethylphenol as reported in a previous paper.

TetramerChemistryAnodic oxidationGeneral MedicineCombinatorial chemistryChemInform
researchProduct

Characterization of the Oxidation of Magnetite Nanoparticles during Their Synthesis by Different Structural Analysis Techniques

2020

Water colloidal solutions of iron oxide nanoparticles coated with tetramethylammonium hydroxide were synthesized by co-precipitation methods. Dimensional analyses were accomplished by transmission ...

Tetramethylammonium hydroxide010401 analytical chemistryBiochemistry (medical)Clinical Biochemistry02 engineering and technology021001 nanoscience & nanotechnology01 natural sciencesBiochemistry0104 chemical sciencesAnalytical ChemistryCharacterization (materials science)chemistry.chemical_compoundMagnetite Nanoparticlessymbols.namesakeColloidchemistryChemical engineeringElectrochemistrysymbolsMagnetic nanoparticlesOxidation process0210 nano-technologyRaman spectroscopySpectroscopyIron oxide nanoparticlesAnalytical Letters
researchProduct

Surface properties and catalytic performance for ethane combustion of La1−xKxMnO3+δ perovskites

2001

Abstract The influence of K substitution in LaMnO3 perovskite on the surface properties and catalytic oxidation of ethane has been studied. La1−xKxMnO3+δ perovskites (x=0.05, 0.10, 0.15, 0.20 and 0.25) with BET surface area of 20–26 m2 g−1 have been prepared by the freeze-drying method and characterized by X-ray diffraction patterns (XRD), TPR, TPD and XPS. The XRD analyses showed the presence of a single crystalline phase (x≤0.15) with the linear increase of the lattice parameter corroborating the incorporation of potassium in the perovskite structure. The XPS studies revealed an enrichment of the perovskite surface with potassium accompanied by an increase in the surface Mn4+/Mn3+ ratio. …

Thermal desorption spectroscopyProcess Chemistry and TechnologyInorganic chemistrychemistry.chemical_elementOxygenCatalysisPotassium oxideCatalysischemistry.chemical_compoundCatalytic oxidationchemistryDesorptionPerovskite (structure)BET theoryApplied Catalysis A: General
researchProduct

Biomass-based composite catalysts for catalytic wet peroxide oxidation of bisphenol A : preparation and characterization studies

2019

Abstract The wet granulation process was used to prepare new, efficient, and cost-effective granular biomass-based composite catalysts for catalytic wet peroxide oxidation (CWPO) of bisphenol A (BPA). The most stable composite granules was prepared by mixing biomass-based carbon residue (CR) with metakaolin (MK) combined with calcium oxide (CaO) or cement and a solvent (NaOH or KOH). For all the prepared composite granules, the optimized binding agents to carbon ratio was 0.3, the solvent to carbon ratio 1.2, and the agitation rate 1200 rpm. The specific surface area of the prepared catalysts was 152–205 m2/g. The composite granular catalyst (CR + MK + CaO + NaOH) had the most durable and s…

Thermal desorption spectroscopybiomassacomposite catalystComposite numbergranular activated carbon02 engineering and technologyjätevesi010501 environmental sciences01 natural sciencesPeroxidewastewater purificationCatalysisGranulationchemistry.chemical_compoundSpecific surface areaChemical Engineering (miscellaneous)Calcium oxideWaste Management and Disposalta116komposiitit0105 earth and related environmental sciencesjäteveden käsittelybiomassProcess Chemistry and Technology021001 nanoscience & nanotechnologyPollutionSolventchemistryaktiivihiilioxidation of bisphenol A0210 nano-technologyNuclear chemistryJournal of Environmental Chemical Engineering
researchProduct

Photodissociation Mechanisms of Major Mercury(II) Species in the Atmospheric Chemical Cycle of Mercury

2020

7 pags., 4 figs.

Thermal oxidationChemical substance010405 organic chemistryPhotodissociationchemistry.chemical_elementElemental mercuryGeneral MedicineGeneral Chemistry010402 general chemistryPhotochemistry7. Clean energy01 natural sciencesCatalysis0104 chemical sciencesMercury (element)Metalchemistry13. Climate actionvisual_artAtmospheric chemistryThermalvisual_art.visual_art_medium
researchProduct