Search results for "OXIDE"
showing 10 items of 6424 documents
High time resolution fluctuations in volcanic carbon dioxide degassing from Mount Etna
2014
Abstract We report here on the first record of carbon dioxide gas emission rates from a volcano, captured at ≈ 1 Hz. These data were acquired with a novel technique, based on the integration of UV camera observations (to measure SO2 emission rates) and field portable gas analyser readings of plume CO2/SO2 ratios. Our measurements were performedat the North East crater of Mount Etna, southern Italy, and the data reveal strong variability in CO2 emissions over timescales of tens to hundreds of seconds, spanning two orders of magnitude. This carries importantimplications for attempts to constrain global volcanic CO2 release to the atmosphere, and will lead to an increased insight into short te…
Modelling nitrous oxide emissions from cropland at the regional scale
2006
Arable soils are a large source of nitrous oxide (N2O) emissions, making up half of the biogenic emissions worldwide. Estimating their source strength requires methods capable of capturing the spatial and temporal variability of N2O emissions, along with the effects of crop management. Here, we applied a process-based model, CERES, with geo-referenced input data on soils, weather, and land use to map N2O emissions from wheat-cropped soils in three agriculturally intensive regions in France. Emissions were mostly controlled by soil type and local climate conditions, and only to a minor extent by the doses of fertilizer nitrogen applied. As a result, the direct emission factors calculated at …
Characterisation of the magmatic signature in gas emissions from Turrialba Volcano, Costa Rica
2014
The equilibrium composition of volcanic gases with their magma is often overprinted by interaction with a shallow hydrothermal system. Identifying the magmatic signature of volcanic gases is critical to relate their composition to properties of the magma (temperature, fO2, gas-melt segregation depth). We report measurements of the chemical composition and flux of the major gas species emitted from Turrialba Volcano during March 2013. Measurements were made of two vents in the summit region, one of which opened in 2010 and the other in 2012. We determined an average SO2 flux of 5.2 ± 1.9 kg s-1 using scanning ultraviolet spectroscopy, and molar proportions of H2O, CO2, SO2, HCl, CO and H2 ga…
Chlorine Partitioning Between a Basaltic Melt and H2O-CO2 Fluids at Mount Etna
2009
Partitioning experiments between a basaltic melt from Mt. Etna and a low-density hydrous fluid or vapor containing H(2)O or H(2)O-CO(2) were performed at 1200-1260 degrees C, at pressures between 1 and 200 MPa, either near the nickel-nickel oxide (NNO) buffer or at two log units above it (NNO + 2), and with different chloride concentrations. Most of the experiments were done at chloride-brine-undersaturated conditions, although at the highest Cl concentrations explored brine saturation might have been reached. The average partition coefficients (D(Cl)(fluid/melt)) over the range of Cl concentrations were derived on a weight basis by plotting the calculated concentrations of Cl in the fluid …
Simulation of nitrous oxide emissions from wheat-cropped soils using CERES
2005
Estimation of nitrous oxide (N2O) emissions from arable soils, in relation to crop fertilization, is essential to devise strategies to mitigate the impact of agriculture on global warming. This paper presents the development and test of a N2O model resulting from the linkage of a dynamic soil-crop simulation model (CERES) with two sub-models of N2O production and reduction in soils. These sub-models (NOE and NGAS) account for both the nitrification and denitrification pathways. The resulting models (CERES–NOE and CERES–NGAS) were tested against experimental data collected on three contrasting wheat-cropped soils representative of the Beauce agricultural region in France. Although the input …
Rare earth element and neodymium isotope tracing of sedimentary rock weathering
2020
Chemical weathering plays an important role in sequestering atmospheric CO2, but its potential influence on global climate over geological timescales remains debated. To some extent, this uncertainty arises from the difficulty in separating the respective contribution of sedimentary and crystalline silicate rocks to past weathering rates in the geological record; two types of rocks having presumably different impact on the long-term carbon cycle. In this study, we investigate the use of rare earth element (REE) and neodymium isotopes (εNd) in leached iron oxide fractions of river sediments for tracing the origin of weathered rocks on continents. A new index, called ‘concavity index’ (CI), i…
Mercury emissions from soils and fumaroles of Nea Kameni volcanic centre, Santorini (Greece)
2013
There have been limited studies to date targeting mercury emissions from volcanic fumarolic systems, and no mercury flux data exist for soil or fumarolic emissions at Santorini volcanic complex, Greece. We present results from the first geochemical survey of Hg and major volatile (CO2, H2S, H2O and H-2) concentrations and fluxes in the fumarolic gases released by the volcanic/hydrothermal system of Nea Kameni islet; the active volcanic center of Santorini. These data were obtained using a portable mercury spectrometer (Lumex 915+) for gaseous elemental mercury (GEM) determination, and a Multi-component Gas Analyzer System (Multi-GAS) for major volatiles. Gaseous Elemental Mercury (GEM) conc…
In situ carbon and oxygen isotopes measurements in carbonates by fiber coupled laser diode-induced calcination: A step towards field isotopic charact…
2021
International audience; Natural stable isotopes ratios (δ13Ccarb and δ18Ocarb) of carbonates archived in the geological record are routinely used to reconstruct local and global paleo temperatures and the secular evolution of the biogeochemical carbon cycle. The state-of-the-art technique, employed since the mid 20th century, to measure these isotopic ratios starts with field sampling followed by several steps of physical and chemical laboratory preparation including: (i) microdrilling and/or sawing and crushing, (ii) CO2 release by wet acid digestion, (iii) gas equilibration, purification and transfer, before (iv) gas phase IRMS measurements. While these steps are time and resource consumi…
Consolidation of earthen building materials: a comparative study
2019
The consolidation and protection of mud bricks are a challenge in the field of conservation of archeological sites. One of the solutions is represented by the coverage of the entire excavation that assures a protection against mud dissolution. Unfortunately, this is not always feasible, both for economical and practical issues. For these reasons, alternative solutions are needed. In this work, laboratory experimentation has been carried out in order to test the efficacy of some products to slow down the dissolution process and increase the brick toughness. Three typologies of raw materials taken from different outcrops (one from the Republic of Azerbaijan and two from Calabria region, Italy…
Ocre, hematites y óxido de hierro: el problema terminológico = Ochre, Hematite and Iron Oxid: The Terminological Issue
2016
Los óxidos de hierro son prácticamente omnipresentes al analizar contextos, no solo referentes al arte rupestre, sino también en relación con toda una serie de actividades que podríamos considerar cotidianas en ambientes prehistóricos. Sin embargo, su estudio sistemático no ha comenzado hasta tiempos muy recientes. Fruto de ello, podría decirse que una parte de la literatura arqueológica no especializada en el campo de la pigmentología muestra, en ocasiones, cierta inexactitud terminológica. Con este documento pretendemos, a través de un análisis tanto de su funcionamiento, como de las propiedades geoquímicas y mineralógicas del ocre, la hematites y los propios óxidos de hierro, exponer la …