Search results for "Oat"

showing 10 items of 4347 documents

Dipeptidyl Enoates As Potent Rhodesain Inhibitors That Display a Dual Mode of Action

2015

Dipeptidyl enoates were prepared through a high-yielding two-step synthetic route. They have a dipeptidic structure with a 4-oxoenoate moiety as a warhead with multiple reactive sites. Dipeptidyl enoates were screened against rhodesain and human cathepsins B and L, and were found to be potent and selective inhibitors of rhodesain. Among them (S,E)-ethyl 5-((S)-2-{[(benzyloxy)carbonyl]amino}-3-phenylpropanamido)-7-methyl-4-oxooct-2-enoate (6) was the most potent, with an IC50 value of 16.4 nm and kinact/Ki=1.6×106 m−1 s−1 against rhodesain. These dipeptidyl enoates display a reversible mode of inhibition at very low concentrations and an irreversible mode at higher concentrations. Inhibition…

trypanosomiasisStereochemistrysleeping sicknessCathepsin LDrug Evaluation PreclinicalChemistry Techniques SyntheticInhibition kineticsCysteine Proteinase InhibitorsBiochemistryCathepsin BInhibitory Concentration 50Structure-Activity RelationshipinhibitorsDrug DiscoveryHumansMoietyMolecular Targeted TherapyGeneral Pharmacology Toxicology and PharmaceuticsIC50Volume concentrationrhodesainPharmacologyChemistryOrganic ChemistryDual modeDipeptidesTrypanocidal AgentsCombinatorial chemistryMolecular Docking SimulationCysteine EndopeptidasesKineticsdipeptidyl enoatesTrypanosomiasis AfricanDocking (molecular)Molecular MedicineCysteine thiolateChemMedChem
researchProduct

Effect of the extensional flow on the properties of oriented nanocomposite films for twist wrapping

2011

In this study, we examined the mechanical behavior of nanocomposite films based on polyethylene (PE) and pristine PE films. The films were prepared by film blowing and were then cold-drawn at low temperature. The experimental results show that cold drawing significantly enhanced the orientation; with increasing draw ratio (DR), the elastic modulus and tensile strength of the PE films strongly increased, particularly in the presence of the organoclay. To obtain polymeric films suitable for twist wrapping, the films must be sufficiently stiff so that no shrinkage or elastic recovery occur during or after twisting. The elongation at break and the yield strain sharply decreased with orientation…

twist wrappingNanocompositeMaterials sciencePolymers and PlasticsNanoparticleGeneral ChemistryPolyethyleneSurfaces Coatings and Filmschemistry.chemical_compoundclay particleschemistryUltimate tensile strengthpolyethylene-based nanocomposite filmMaterials ChemistryOrganoclayElongationComposite materialElastic modulusShrinkage
researchProduct

Pirate John Gow and Literary Renderings of his Career by Daniel Defoe and Sir Walter Scott

2018

This article analyses two literary representations - by Daniel Defoe and Sir Walter Scott - of the career of an early-18th century Orkney pirate in order to confront the contemporary view of John Gow as an unprincipled cutthroat with later literary images of a Romantic corsair. It therefore examines evolving literary approaches in the period to socially transgressive behaviour.

unprincipled cutthroatOrkney pirateRomantic outlaw
researchProduct

Bunker culturel : la régénération du patrimoine militaire urbain à Saint-Nazaire

2011

Au cours des deux dernières décennies Saint-Nazaire a relancé son développement sans se référer nécessairement aux modèles des métropoles européennes. Concentrées autour de la zone portuaire, près de la base sous-marine allemande, les nouvelles opérations urbaines ont contribué à définir un important projet touristique et culturel. La spécificité symbolique et la valorisation du patrimoine militaire ont permis à Saint-Nazaire de montrer que l’identité d’une ville pouvait activer sa croissance.Over the last two decades, the port city of Saint-Nazaire has encouraged urban redevelopment without necessarily following the models suggested by other European cities. An important cultural and touri…

urban regenerationSaint-Nazairelcsh:Fine Artsmedia_common.quotation_subjectSettore ICAR/14 - Composizione Architettonica E UrbanaUrban regenerationpatrimoine militaire Saint-Nazaire Atlantic Wall bunker U-Boat régénération urbaine infrastructure culturelle waterfront military heritage Atlantic Wall Saint-Nazaire U-Boat bunker urban regeneration cultural infrastructure waterfrontArtAtlantic Wallbunker U-Boatcultural infrastructuremilitary heritageU-Boat bunkerpatrimoine militairerégénération urbainelcsh:NHumanitieswaterfrontinfrastructure culturellemedia_common
researchProduct

Sisävesien mikrotonnisto : pienet höyrylaivat Suomen ja erityisesti Kainuun sisävesiliikenteessä 1870-luvulta 1960-luvulle

2016

The significance in Finland of shipping on inland waterways has been great. This is due to the topography of the country with its many lakes and to the fact that the vast waterways in their natural state were easily navigable. The construction of canals resulted in even more extensive interconnected inland waterways. This study explores the tasks of the steamships plying these internal waterways, their numbers and significance, and also changes and the reasons for these between different inland waterways, as regards different types of vessels and shipowners in the period from the 1870s to the 1960s. Special attention is paid to steamships smaller than 19 net register tons. This limit was ch…

vesiliikenneuittoeconomic historysteamshipslaivanvarustusrahdinkuljetuskauppamerenkulkuproomuttaloushistoriahöyrylaivattimber floatingseafaringhenkilöliikenneSuomitugboatsinland waterwaysmerenkulkuvarustamotfreight carrying vesselssisävesiliikenneshipsFinland1800-luku1900-lukuKainuu
researchProduct

The effect of PLC-inhibitor on echovirus 1 internalization probed with fluorescently labeled echovirus 1

2014

Echovirus 1 (EV1) kuuluu Pikornavirusperheeseen ja tarkemmin luokiteltuna Enterovirusten sukuun. EV1 on pieni ja vaipaton RNA-virus, jonka proteiinikuori koostuu neljästä proteiinista VP1-VP4. Infektion on osoitettu alkavan, kun EV1 tarttuu α2β1-integriiniin solun pinnalla, jonka jälkeen virus otetaan solun sisään kaveoliinivälitteistä endosytoosia sekä makropinosytoosia muistuttavalla mekanismilla. Toisaalta sitä, kuinka virus avautuu sekä vapauttaa RNA:nsa, ei vielä tarkalleen tiedetä. Tässä tutkimuksessa EV1 puhdistettiin ensin sakkaroosigradientilla, jonka jälkeen virus leimattiin fluoresoivalla amiinireaktiivisella värillä. Tulokset osoittivat, että leimauksen onnistumiseksi tarvitaan …

viruksetfluoresenssifluorescent labelingECHO-viruksetEchovirus 1uncoatingendocytosis inhibitorendosytoosiinhibiittorit
researchProduct

Conformational Dynamics of the Dengue Virus Protease Revealed by Fluorescence Correlation and Single-Molecule FRET Studies.

2021

The dengue virus protease (DENV-PR) represents an attractive target for counteracting DENV infections. It is generally assumed that DENV-PR can exist in an open and a closed conformation and that active site directed ligands stabilize the closed state. While crystal structures of both the open and the closed conformation were successfully resolved, information about the prevalence of these conformations in solution remains elusive. Herein, we address the question of whether there is an equilibrium between different conformations in solution which can be influenced by addition of a competitive inhibitor. To this end, DENV-PR was statistically labeled by two dye molecules constituting a FRET …

virusesFluorescence correlation spectroscopyCrystal structureDengue virusViral Nonstructural Proteins010402 general chemistrymedicine.disease_cause01 natural sciencesCatalytic Domain0103 physical sciencesMaterials ChemistrymedicineFluorescence Resonance Energy TransferMoleculePhysical and Theoretical Chemistry010304 chemical physicsbiologyChemistrySerine EndopeptidasesActive siteSingle-molecule FRETDengue VirusFluorescence0104 chemical sciencesSurfaces Coatings and FilmsFörster resonance energy transferbiology.proteinBiophysicsThe journal of physical chemistry. B
researchProduct

VIOLENZA DI PROSSIMITÀ. CURA PASTORALE E VULNERABILITÀ SOCIALE

2022

Nel capitolo introduttivo vendono spiegate le ragioni scientifiche che collegano il paradigma della violenza di prossimità alle rappresentazioni culturali che orientano comportamenti proattivi e, allo stesso tempo, alle dinamiche relazionali che marginalizzano i soggetti più vulnerabili.

vulnerabilità sociale comportamenti proattivi violenza di prossimitàSettore SPS/07 - Sociologia Generale
researchProduct

Biopolymer Recovery from Aerobic Granular Sludge and Conventional Flocculent Sludge in Treating Industrial Wastewater: Preliminary Analysis of Differ…

2022

The recovery of biopolymers from sewage sludge could be a crucial step in implementing circular economy principles in wastewater treatment plants (WWTP). In this frame, the present study was aimed at evaluating the simultaneous production of polyhydroxyalkanoates (PHA) and extracellular polymeric substances (EPS) obtainable from the treatment of agro-industrial wastewater. Two biological enrichment systems, aerobic granular sludge (AGS) and a conventional activated sludge operating as a sequencing batch reactor (SBR), were monitored for 204 and 186 days, respectively. The maximum biopolymers accumulation capacity was close to 0.60 mgPHA-EPS gVSS−1 in the AGS when operating at 3 kgCODm…

wastewater treatmentsewage sludgeSettore ICAR/03 - Ingegneria Sanitaria-Ambientalebiopolymercircular economyaerobic granular sludge; biopolymers; circular economy; extracellular polymeric substances; polyhydroxyalkanoates; sewage sludge; wastewater treatmentGeography Planning and Developmentpolyhydroxyalkanoateaerobic granular sludgeAquatic Scienceextracellular polymeric substanceBiochemistryWater Science and TechnologyWater
researchProduct

Waterfront e patrimonio militare: la base sottomarina di Saint-Nazaire

2012

Isolated from its harbour by the submarine base built during World War II, Saint-Nazaire has added to its development over the last two decades, without referring to major European models. An important arts and tourist center has been built around the port zone, close to the German submarine base. The converted military structure, which is situated in an impressive public space, has been endowed with a new sense of identity. It stands out as the main element in the urban regeneration process, focusing on the cultural and tourist character of the programme and aiming to reinforce the relationship between the city and its port.

waterfront Atlantic Wall infrastruttura militare rigenerazione Saint-Nazaire bunker U-boatSettore ICAR/14 - Composizione Architettonica E Urbana
researchProduct