Search results for "Oct"
showing 10 items of 3052 documents
Most of the field/inductive substituent effect works through the bonds
2019
AbstractAn application of the quantum chemical modeling allowed to investigate the nature of the field/inductive substituent effect (SE). For this purpose, series of X-tert-butyl···tert-butane (TTX) complexes (where X = NMe2, NH2, OH, OMe, Me, H, F, Cl, CF3, CN, CHO, COMe, CONH2, COOH, NO2, NO) were studied. A starting distance between central carbon atoms in substituted and unsubstituted fragments of TTX, dC1–C4, was the same as the distance C1–C4 in X-substituted bicyclo[2.2.2]octane (BCO), where the SE acts both via bonds and via space. A strength of interaction between substituted and unsubstituted components of TTX was described by deformation and interaction energies. The substituent …
A Look at the Future Hemophilia A Treatment
2018
The current treatment of patients with hemophilia A is safer and more effective than the previous one. Prophylactic substitution involves repeated intravenous administration of plasma-derived factor VIII or recombinant factor VIII products, with inconveniences and possible adverse effects. The occurrence of inhibitors requires the administration of activated prothrombin complex concentrate or activated factor VII - an expensive treatment. The immune tolerance induction is the ideal treatment for patients with high titres of inhibitors - the only potential way to eliminate inhibitors and very expensive. For these reasons, the medical world is interested in the advances that scientific resear…
The Role of Emotional Intelligence in Health Care Professionals Burnout
2017
The purpose of this study is to explore the relationship between Emotional Intelligence (EI) and burnout in health care professionals. More specifically, this survey has the purpose of demonstrating the role of EI as a protective factor against the risk of burnout. Health professionals (doctors, nurses, and other caregivers) composed the sample. Data, collected during professional training, provided 148 employees. Major results of this survey underline the relationship between EI and burnout. As we expected, there is a negative and significant correlation between burnout and Emotional Intelligence. Moreover, burnout varies depending on length of service: burnout increases between 5 and 10 y…
PhDs' early career trajectories strongly differentiated
2017
International audience
Application dans le temps de la convention de La Haye du 19 octobre 1996
2014
International audience; Civ. 1re, 20 mars 2013, 2 arrêts, n° 11-24.388 et 11-28.025, D. 2013. 837 ; AJ fam. 2013. 298, obs. A. Boiché
Knock onset prediction of propane, gasoline and their mixtures in spark ignition engines
2016
Gaseous fuels, such as Liquefied Petroleum Gas (LPG) and Natural Gas (NG), thanks to their excellent mixing capabilities and high knocking resistance, allow complete and cleaner combustion than gasoline in Spark Ignition (SI) engines, resulting in lower pollutant emissions, above all if particulate matter is considered. In previous works [1,2] the authors proved how the simultaneous combustion of gasoline and gaseous fuel (NG or LPG) may strongly reduce both fuel consumption and pollutant emissions with respect to pure gasoline operation without a significant power loss. These very encouraging results were obtained thanks to the strong knock resistance increase obtained adding gaseous fuel …
Experimental Determination of Liquefied Petroleum Gas–Gasoline Mixtures Knock Resistance
2014
The results of previous experimental researches showed that great advantages can be achieved, both in terms of fuel consumption and pollutant emissions, in bifuel vehicles by means of the double-fuel combustion, i.e., the simultaneous combustion of gasoline and a gaseous fuel, such as liquefied petroleum gas (LPG) or natural gas (NG). The substantial increase in knock resistance pursued by adding LPG to gasoline, which allowed to maintain an overall stoichiometric proportion with air also at full load, is not documented in the scientific literature and induced the authors to perform a proper experimental campaign. The motor octane number (MON) of LPG–gasoline mixtures has been hence determi…
An NTC zone compliant knock onset prediction model for spark ignition engines
2015
Abstract Pollutant emissions reduction and energy saving policies increased the production of Spark Ignition (SI) engines operated with gaseous fuels. Natural Gas (NG) and Liquefied Petroleum Gas (LPG), thanks to their low cost and low environmental impact represent the best alternative. Bi-fuel engines, which may run either with gasoline or with gas (NG or LPG), widely spread in many countries thanks to their versatility, high efficiency and low pollutant emissions: gas fueled vehicles, as example, are allowed to run in many limited traffic zones. In the last years, supercharged SI engines fueled with either gasoline or gaseous fuel, spread in the market. Thermodynamic simulations, widely …
Octane Rating of Natural Gas-Gasoline Mixtures on CFR Engine
2014
In the last years new and stricter pollutant emission regulations together with raised cost of conventional fuels resulted in an increased use of gaseous fuels, such as Natural Gas (NG) or Liquefied Petroleum Gas (LPG), for passenger vehicles. Bi-fuel engines represent a transition phase product, allowing to run either with gasoline or with gas, and for this reason are equipped with two separate injection systems. When operating at high loads with gasoline, however, these engines require rich mixtures and retarded combustions in order to prevent from dangerous knocking phenomena: this causes high hydrocarbon (HC) and carbon monoxide (CO) emissions together with high fuel consumption. With t…
A Refined Model for Knock Onset Prediction in Spark Ignition Engines Fueled With Mixtures of Gasoline and Propane
2015
In the last decade, gaseous fuels, such as liquefied petroleum gas (LPG) and natural gas (NG), widely spread in many countries, thanks to their prerogative of low cost and reduced environmental impact. Hence, bi-fuel engines, which allow to run either with gasoline or with gas (LPG or NG), became very popular. Moreover, as experimentally demonstrated by the authors in the previous works, these engines may also be fueled by a mixture of gasoline and gas, which, due to the high knock resistance of gas, allow to use stoichiometric mixtures also at full load, thus drastically improving engine efficiency and pollutant emissions with respect to pure gasoline operation without noticeable power los…