Search results for "Oil shale"
showing 10 items of 32 documents
Effect of the mineralogical composition on the elastoplastic hydromechanical response of Opalinus Clay shale
2021
Abstract Opalinus Clay is the shale currently under investigation as the host formation for geological radioactive waste disposal in Switzerland. Its hydromechanical response has been widely studied, and the experimental results show a range of values whose dispersion needs to be clarified. This work aims to explain the dispersion in the literature results by correlating the hydro-mechanical response to the mineralogical variability of the tested specimens . Based on published microstructural studies, the Opalinus Clay shale is herein schematised as a sequence of two kinds of layers: the shaly (high in clay-mineral content) and the sandy (low in clay-mineral content) layers. The mineralogic…
1D Compression Behaviour of Opalinus Clay
2017
One of the main concerns related to tunnel excavations, drilling operations and wellbore stability in shales is the generation of excess pore water pressure due to changes in mechanical stress; therefore the consolidation of shales is a fundamental process that must be considered. This paper presents a compre- hensive methodology for analysing the compression and consolidation behaviour of shales. An apparatus to perform high-pressure oedometric tests is presented and an analytical method is introduced to analyse the shale consolidation behaviour, which allows information to be gathered on the coeffi cient of consolidation, stiffness, poroelastic properties, and permeability of the tested m…
On the hydro-mechanical behaviour of remoulded and natural Opalinus Clay shale
2016
The geo-energy sector makes use of advanced technologies such as shale gas extraction, CO2 sequestration and nuclear waste geological disposal that rely on the exploitation of shale formations. Due to the great depths involved in these applications and the difficulties in retrieving intact samples, remoulded shale specimens are often adopted for hydro-mechanical testing. Remoulded and intact shales may substantially differ in their hydro-mechanical behaviour due to the particular structure of the natural material, which is the result of diagenesis and burial history. This paper presents an experimental campaign aimed at (i) characterizing the role of diagenesis and depth for Opalinus Clay s…
Experimental analysis of the water retention behaviour of shales
2014
Shales are among the most commonly considered geomaterials in current energy-related geomechanical investigations, as they are involved in engineering applications such as the unconventional extraction of natural gas, CO2 sequestration and nuclear waste geological storage. A deep understanding of their behaviour with regard to variations in the degree of saturation is of primary significance for such applications. With the aim to establish a sound protocol for shale retention behaviour analysis, this paper presents an advanced experimental methodology that takes into account the specificities of shales such as small pore size dimensions and the large variations in water potential to be appl…
Anisotropic Volumetric Response of Shales upon Suction Changes
2016
Anisotropic fabric and volumetric response to suction changes represent two main features of shales, which are involved in several engineering applications. However, a comprehensive understanding of the interaction between these two aspects is still missing. The present work aims to provide a detailed analysis of the coupling between the water retention capacity of shales and their anisotropic behaviour through an advanced experimental methodology. Among the various tested facies of the Opalinus Clay Shale (Mont Terri, Switzerland), the results from the shaly facies are presented in this study. The behaviour of the material is characterized by swelling and shrinkage respectively upon wettin…
Anisotropic volumetric behaviour of Opalinus clay shale upon suction variation
2016
Opalinus clay shale is under consideration to serve as the host geomaterial for the underground storage of nuclear waste in Switzerland. Water retention behaviour and anisotropic behaviour represent two main features of this geomaterial; however, a comprehensive understanding of the interaction between these two features is still lacking. This paper aims to provide a detailed experimental analysis of the coupling between the water retention capacity and the anisotropic behaviour of two facies (shaly and sandy) of the Opalinus clay shale. The response of the tested geomaterials is characterised by an unequal swelling and shrinkage response in directions parallel and perpendicular to the bed…
Continental weathering and climatic changes inferred from clay mineralogy and paired carbon isotopes across the early to middle Toarcian in the Paris…
2014
Abstract Lower Toarcian strata (Lower Jurassic) have been extensively studied with a view to understanding the oceanographic, climatic and biological processes that drove the Earth's system into an Oceanic Anoxic Event (OAE). For this time period, the evolution of the European marine seaways is now relatively well constrained owing to multiple geochemical studies, but investigations regarding climatic trends in the continental realm remain sparse. In the present study, we test the clay mineralogy as a continental climate-sensitive proxy in the well-documented Sancerre core (southern Paris Basin). We compare variations in the kaolinite content with p CO 2 fluctuations (derived from paired ca…
An insight on the thermo-mechanical behaviour of a shale
2016
In recent years, several shale formations have been employed in geo-energy related engineering fields that foresee the presence of high thermal loads or significant temperature variations. Such thermal conditions are related to a need to reach great depths (several hundred of meters), as in the case of CO2 sequestration and Enhanced Geothermal System (EGS) technologies, or to the presence of thermal sources, as in the context of nuclear waste geological disposal. In addition, thermal changes can occur in shale formations through the injection of drilling and fracturing fluids at great depths, where a higher temperature with respect to the one of the injected fluid is encountered as a result…
Identification of metalloporphyrins extracted from the copper bearing black shale of fore sudetic monocline (Poland)
2006
Abstract Metalloporphyrins were isolated from copper-bearing black shale ores. The shale originates from the Lubin copper mine (Poland). The porphyrins have been extracted by way of a Soxhlet apparatus, and then purified using column chromatography. In order to identify the extracted porphyrins complexes UV–Vis, mass spectrometry and EPR analytical techniques have been used.
Benchmark study of undrained triaxial testing of Opalinus Clay shale: Results and implications for robust testing
2021
Triaxial testing of argillaceous rocks and shales is significantly more challenging than conventional rock mechanical testing. The challenges are mainly related to the very low permeability of these geomaterials, and their sensitivity to exposure of atmosphere and brines, which induces variations of water content, suction and effective stress. There are currently no international standards to guide service laboratories for robust testing procedures for shales. A benchmark study of undrained triaxial testing was therefore initiated with three leading service laboratories in shale testing, performing 13 tests and using two different methods of establishing sample saturation prior to deformati…