Search results for "Onium"

showing 10 items of 2091 documents

CCDC 173965: Experimental Crystal Structure Determination

2003

Related Article: G.Marinescu, R.Lecouezec, D.Armentano, G.De Munno, M.Andruh, S.Uriel, R.Llusar, F.Lloret, M.Julve|2002|Inorg.Chim.Acta|336|46|doi:10.1016/S0020-1693(02)00880-0

tetraphenylphosphonium (22'-bipyrimidine)-bis(oxalato)-chromium(iii) monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Oxidation-responsive and "clickable" poly(ethylene glycol) via copolymerization of 2-(methylthio)ethyl glycidyl ether

2016

Poly(ethylene glycol) (PEG) is a widely used biocompatible polymer. We describe a novel epoxide monomer with methyl-thioether moiety, 2-(methylthio)ethyl glycidyl ether (MTEGE), which enables the synthesis of well-defined thioether-functional poly(ethylene glycol). Random and block mPEG-b-PMTEGE copolymers (Mw/Mn = 1.05-1.17) were obtained via anionic ring opening polymerization (AROP) with molecular weights ranging from 5 600 to 12 000 g·mol-1. The statistical copolymerization of MTEGE with ethylene oxide results in a random microstructure (rEO = 0.92 ± 0.02 and rMTEG E = 1.06 ± 0.02), which was confirmed by in situ 1H NMR kinetic studies. The random copolymers are thermorespon…

thioether-functional PEGoxidation-responsiveEpoxide02 engineering and technology010402 general chemistry01 natural sciencesBiochemistryRing-opening polymerizationMicelleCatalysischemistry.chemical_compoundColloid and Surface ChemistryPolymer chemistryCopolymerMoiety2-(methylthio)ethyl glycidyl etherEthylene oxidepoly(ethylene glycol)sulfoniumGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesmulti-functional PEGMonomerchemistryPEOpolyetherthermoresponsive0210 nano-technologyEthylene glycol
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Characteristics of acute toxicity dynamics of selected toxicants on aquatic crustaceans

2019

Determining the value of a half-effective or half-life concentration or dose of toxicant is the main purpose of acute toxicity studies, and this is also the most commonly used value in the toxicity characteristics of substances. By conducting tests that meet the criteria and requirements for the determination of acute toxicity, due to the use of appropriate mathematical tools and concentrations resulting in complete lethal effects in the studied groups, considerably more important values can be achieved, which give a possibility for the analysis of the entire process's dynamics, as well as determining the threshold values of the effect time and toxicant concentration. This was the purpose o…

threshold concentrationDaphnia magnaacute toxicityCypris puberacopper and ammonium ionsEcological Chemistry and Engineering S-Chemia I Inzynieria Ekologiczna S
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CCDC 1985141: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, E. Daiann Sosa Carrizo, Corentin Magnoux, Esteban Lobato, Hélène Cattey, Philippe Richard, Stéphane Brandès, Charles H. Devillers, Anthony Romieu, Pierre Le Gendre, Paul Fleurat-Lessard|2021|Chemical Science|12|253|doi:10.1039/D0SC04736H

trichloro-(1133-tetraphenyl-13-bis(phenylimino)-13-triphosphan-2-yl)-zirconium(iv) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1996430: Experimental Crystal Structure Determination

2020

Related Article: Júlia Mayans, Constantinos C. Stoumpos, Mercé Font-Bardia, Albert Escuer|2020|Chem.-Eur.J.|26|11158|doi:10.1002/chem.202001900

trimethylammonium potassium tris(mu-hydroxybis(pyridin-2-yl)methanolato)-tris(mu-pyrazolato)-hexakis(mu-azido)-(mu-carbonato)-hexa-nickel(ii) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 299920: Experimental Crystal Structure Determination

2011

Related Article: M.Seredyuk, I.O.Fritsky, R.Kramer, H.Kozlowski, M.Haukka, P.Gutlich|2010|Tetrahedron|66|8772|doi:10.1016/j.tet.2010.08.071

tris(1H-pyrazol-4-yl)selenonium ethylseleniteSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1951519: Experimental Crystal Structure Determination

2019

Related Article: Walter Cañón-Mancisidor, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, Guillermo Mínguez Espallargas|2019|Chem.Commun.|55|14992|doi:10.1039/C9CC07868A

tris(tetra-n-butylammonium) (mu-phosphato)-(mu-hydroxo)-tricosakis(mu-oxido)-bis(110-phenanthroline)-undecakis(oxido)-undeca-tungsten(vi)-gadolinium(iii) monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1482839: Experimental Crystal Structure Determination

2016

Related Article: José J. Baldoví, Yan Duan, Carlos Bustos, Salvador Cardona-Serra, Pierre Gouzerh, Richard Villanneau, Geoffrey Gontard, Juan M. Clemente-Juan, Alejandro Gaita-Ariño, Carlos Giménez-Saiz, Anna Proust, Eugenio Coronado|2016|Dalton Trans.|45|16653|doi:10.1039/C6DT02258H

tris(tetra-n-butylammonium) octadecakis(mu-oxido)-octakis(mu-methoxo)-bis((4-nitrophenyl)diazene)-octaoxo-deca-molybdenum-dysprosium chloroform solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Neuronal effects of Sugammadex in combination with Rocuronium or Vecuronium.

2017

Rocuronium (ROC) and Vecuronium (VEC) are the most currently used steroidal non-depolarizing neuromuscular blocking (MNB) agents. Sugammadex (SUG) rapidly reverses steroidal NMB agents after anaesthesia. The present study was conducted in order to evaluate neuronal effects of SUG alone and in combination with both ROC and VEC. Using MTT, CASP-3 activity and Western-blot we determined the toxicity of SUG, ROC or VEC in neurons in primary culture. SUG induces apoptosis/necrosis in neurons in primary culture and increases cytochrome C (CytC), apoptosis-inducing factor (AIF), Smac/Diablo and Caspase 3 (CASP-3) protein expression. Our results also demonstrated that both ROC and VEC prevent these…

vecuroniumNecrosisEstrès oxidatiuPrimary Cell CulturerocuroniumCaspase 3NeuronesPharmacologySugammadexSugammadex03 medical and health sciences0302 clinical medicine030202 anesthesiologymedicineAnimalsHumansAndrostanolsRocuroniumCell damageNeuronsVecuronium BromideDose-Response Relationship DrugCaspase 3business.industryapoptosis.Apoptosis Inducing FactorCytochromes c030208 emergency & critical care medicineGeneral Medicinemedicine.diseaseneuronRatsDrug Combinationsmedicine.anatomical_structureGene Expression RegulationApoptosisToxicityNeuronNeuromuscular Blocking Agentsmedicine.symptombusinessResearch Papergamma-Cyclodextrinsmedicine.drug
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NH4HCO3–water solutions regeneration in RED closed loop applications

2017

Reverse Electrodialysis (RED) in closed loop arrangement (Reverse Electrodialysis Heat Engine - REDHE) is a promising technology to convert low-grade waste heat into electricity. RED is a membrane process exploiting the salinity gradient between a concentrated and a diluted solution to generate electrical current. Due to the transfer phenomena occurring in the RED unit, the two exiting solutions are partially mixed. Thermal regeneration processes can be used to restore the initial conditions of the two solutions, thus closing the loop. In this regard, ammonium hydrogen carbonate (NH4HCO3) salt solutions are suitable for such applications, being able to decompose at temperatures above 40-45 …

waste heatSalinity Gradient PowerAmmonium bicarbonate RED SGP.Keywords: Reverse Electrodialysis Heat Engine
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