Search results for "Optica"

showing 10 items of 7696 documents

Stable amorphous calcium oxalate: synthesis and potential intermediate in biomineralization.

2014

Amorphous calcium oxalate nanoparticles with sizes of 10–30 nm were synthesized at room temperature by the hydrolysis of a dimethyl oxalate from ethanol solution.

Calcium OxalateEthanolHydrolysisInorganic chemistryMetals and AlloysCalcium oxalateTemperatureNanoparticleGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsAmorphous solidHydrolysischemistry.chemical_compoundCalcium ChloridechemistryMaterials ChemistryCeramics and CompositesNanoparticlesParticle SizeDimethyl oxalateBiomineralizationChemical communications (Cambridge, England)
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Reversible Tuning of Ca Nanoparticles Embedded in a Superionic CaF2 Matrix

2019

Controlling the size and shape of metallic colloids is crucial for a number of nanotechnological applications ranging from medical diagnosis to electronics. Yet, achieving tunability of morphological changes at the nanoscale is technically difficult and the structural modifications made on nanoparticles generally are irreversible. Here, we present a simple nonchemical method for controlling the size of metallic colloids in a reversible manner. Our strategy consists of applying hydrostatic pressure on a Ca cationic sublattice embedded in the irradiated matrix of CaF2 containing a large concentration of defects. Application of our method to CaF2 along with in situ optical absorption of the Ca…

Calcium-fluoridePhase-diagramMaterials scienceHigh-pressureHydrostatic pressureNanoparticle02 engineering and technology010402 general chemistry01 natural sciencesMetalColloidIrradiationColloidsPhysical and Theoretical ChemistryPolymorphismNanoscopic scalePlasmonPhase diagramSize evolutionCompression021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsGeneral EnergyChemical engineeringvisual_artvisual_art.visual_art_mediumMechanism0210 nano-technology
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Fibre Bragg gratings tuned and chirped using magnetic fields

1997

The authors report on the use of magnetic fields in conjunction with magnetostrictive materials for tuning and chirping optical fibre Bragg gratings. The Bragg wavelength shifts as a consequence of the strain induced in the fibre by a magnetostrictive rod when a magnetic field is applied. A tuning range of 1.1 nm has been achieved by a magnetic field of 103 mT and the grating has been chirped by applying non-uniform magnetic fields.

Camps magnèticsPHOSFOSOptical fiberMaterials sciencebusiness.industryPhysics::OpticsMagnetostrictionÒpticaGratinglaw.inventionMagnetic fieldSubwavelength-diameter optical fibreCondensed Matter::Materials ScienceOpticsFiber Bragg gratinglawChirpOptoelectronicsPhysics::Atomic PhysicsElectrical and Electronic EngineeringbusinessElectronics Letters
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Site-Coded Oral Squamous Cell Carcinoma Evaluation by Optical Coherence Tomography (OCT): A Descriptive Pilot Study

2022

Optical Coherence Tomography (OCT) is an emerging non-invasive method for oral diagnostics, proving to be a practicable device for epithelial and subepithelial evaluation. The potential validity of OCT in oral cancer assessment has been explored but, to date, there are very few investigations conducted with a systematic comparison between clinical/histological and OCT parameters, especially in strict reference to the anatomical site-codification of the oral mucosa. In this regard, our study performed a two-steps evaluation (in vivo OCT and histological investigations) of suspected OSCCs, progressively recruited, using as references the OCT images of the same site-coded healthy mucosa, to pr…

Cancer Researchoptical coherence tomography; early diagnosis; oral cancer; diagnostic pattern; optical biopsyoptical biopsyoptical coherence tomographyOncologyoral cancerdiagnostic patternearly diagnosis
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Silver Clusters of Five Atoms as Highly Selective Antitumoral Agents Through Irreversible Oxidation of Thiols

2022

Low atomicity clusters present properties dependent on the size, due to the quantum confinement, with well-defined electronic structures and high stability. Here it is shown that Ag5 clusters catalyze the complete oxidation of sulfur to S+6. Ag5 catalytic activity increases with different oxidant species in the order O2 ≪ H2O2 < OH•. Selective oxidation of thiols on the cysteine residues of glutathione and thioredoxin is the primary mechanism human cells have to maintain redox homeostasis. Contingent upon oxidant concentration, Ag5 catalyzes the irreversible oxidation of glutathione and thioredoxin, triggering apoptosis. Modification of the intracellular environment to a more oxidized state…

Cancer therapycatalysissilver clusterssulfur oxidationCondensed Matter PhysicsCatalysisSulfur oxidationElectronic Optical and Magnetic MaterialsBiomaterialsLow atomicity clustersSettore CHIM/03 - Chimica Generale E InorganicaElectrochemistrycancer therapylow atomicity clustersSilver clusters
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Simulation studies of gas-liquid transitions in two dimensions via a subsystem-block-density distribution analysis

1993

The finite-size scaling analysis of the density distribution function of subsystems of a system studied at constant total density is studied by a comparative investigation of two models: (i) the nearest-neighbor lattice gas model on the square lattice, choosing a total lattice size of 64×64 sites. (ii) The two-dimensional off-lattice Lennard-Jones system (truncated at a distance of 2.5 σ, σ being the range parameter of the interaction) withN=4096 particles, applying the NVT ensemble. In both models, the density distribution functionPL(ρ) is obtained forL×L subsystems for a wide range of temperaturesT, subblock linear dimensionsL and average densities . Particular attention is paid to the qu…

Canonical ensemblePhysicsDistribution functionComputer simulationLattice (order)CompressibilityGeneral Materials ScienceIsing modelStatistical physicsCondensed Matter PhysicsSquare latticeScalingElectronic Optical and Magnetic Materials
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Temperature concepts for small, isolated systems: 1/t decay and radiative cooling

2003

We report on progress in our investigations of cluster cooling. The analysis of measurements is based on introduction of the microcanonical temperature and a statistical description of the decay of an ensemble with a broad distribution in temperature. The resulting time dependence of the decay rate is a power law close to t �1 , replaced by nearly exponential decay after a characteristic time for quenching by radiative cooling. We focus on results obtained for fullerenes, both anions and cations and recently also neutral C60.

Canonical ensemblePhysicsQuenchingMicrocanonical ensembleRadiative coolingExcited statePhysics::Atomic and Molecular ClustersOptical physicsAtomic physicsExponential decayPower lawAtomic and Molecular Physics and Optics
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Remote sensing of vegetation dynamics in agro-ecosystems using smap vegetation optical depth and optical vegetation indices

2017

The ESA's SMOS and the NASA's SMAP missions, launched in 2009 and 2015, respectively, are the first two missions having on-board L-band microwave sensors, which are very sensitive to the water content in soils and vegetation. Focusing on the vegetation signal at L-band, we have implemented an inversion approach for SMAP that allows deriving vegetation optical depth (VOD, a microwave parameter related to biomass and plant water content) alongside soil moisture, without reliance on ancillary optical information on vegetation. This work aims at using this new observational data to monitor the phenology of crops in major global agro-ecosystems and enhance present agricultural monitoring and pre…

Canopy010504 meteorology & atmospheric sciences0208 environmental biotechnologyFOS: Physical sciencesApplied Physics (physics.app-ph)02 engineering and technology01 natural sciencesoptical depthVegetation indicesagro-ecosystemsVegetation DynamicsEcosystemWater content0105 earth and related environmental sciencesRemote sensingVegetationPhenologyBiosphereInversion (meteorology)Physics - Applied PhysicsSMAP15. Life on land020801 environmental engineeringEcological indicatorGeography13. Climate actionSoil water2017 IEEE International Geoscience and Remote Sensing Symposium (IGARSS)
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Mapping Carbon Stocks In Central And South America With Smap Vegetation Optical Depth

2019

Mapping carbon stocks in the tropics is essential for climate change mitigation. Passive microwave remote sensing allows estimating carbon from deep canopy layers through the Vegetation Optical Depth (VOD) parameter. Although their spatial resolution is coarser than that of optical vegetation indices or airborne Lidar data, microwaves present a higher penetration capacity at low frequencies (L-band) and avoid cloud masking. This work compares the relationships of airborne carbon maps in Central and South America with both (i) SMAP L-band VOD at 9 km gridding and (ii) MODIS Enhanced Vegetation Index (EVI). Models to estimate carbon stocks are built from these two satellite-derived variables.…

CanopyL bandTeledetecció010504 meteorology & atmospheric sciencesRadiofreqüència0208 environmental biotechnologyClimate changeOptical radar02 engineering and technology01 natural sciencesComunicacions òptiquesCarboniImage resolution0105 earth and related environmental sciencesRemote sensingVegetation mappingVegetationOptical communicationsTropicsEnhanced vegetation indexRemote sensing:Enginyeria de la telecomunicació [Àrees temàtiques de la UPC]Carbon020801 environmental engineering:Enginyeria de la telecomunicació::Telecomunicació òptica [Àrees temàtiques de la UPC]Climate change mitigationRemote sensing by laser beamSpatial ecologyEnvironmental scienceSistemes de gestió mediambientalIGARSS 2019 - 2019 IEEE International Geoscience and Remote Sensing Symposium
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Sensitivity of L-band vegetation optical depth to carbon stocks in tropical forests: a comparison to higher frequencies and optical indices

2019

Supplementary data to this article can be found online at https://doi.org/10.1016/j.rse.2019.111303. Monitoring vegetation carbon in tropical regions is essential to the global carbon assessment and to evaluate the actions oriented to the reduction of forest degradation. Mainly, satellite optical vegetation indices and LiDAR data have been used to this purpose. These two techniques are limited by cloud cover and are sensitive only to the top of vegetation. In addition, the vegetation attenuation to the soil microwave emission, represented by the vegetation optical depth (VOD), has been applied for biomass estimation using frequencies ranging from 4 to 30¿GHz (C- to K-bands). Atmosphere is t…

CanopyL bandTropical forestsL-band010504 meteorology & atmospheric sciencesCarbon densityCloud cover0208 environmental biotechnologySoil ScienceClimate change02 engineering and technologyCarbon sequestrationAtmospheric sciences01 natural sciencesClimate changeSatellite imageryVegetation optical depthComputers in Earth Sciences0105 earth and related environmental sciencesRemote sensingTropicsGeology:Enginyeria de la telecomunicació [Àrees temàtiques de la UPC]020801 environmental engineeringSistemes de comunicació de microonesLidarEnvironmental scienceMicrowave communication systemsSoil moistureSistemes de gestió mediambientalSòls -- Humitat
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