Search results for "Optical"

Mechanisms of covalent dimerization on a bulk insulating surface

2017

Combining density functional theory and high resolution NC-AFM experiments, we have studied the on surface reaction mechanisms' responsible for the covalent dimerization of 4-iodobenzoic acid (IBA) organic molecules on the calcite (10.4), insulating surface. When annealed at 580 K, the Molecules assemble in one-dimensional chains of covalently bound dimers: The chains have a unique orientation and result from a complex set of processes, including a nominally rather. costly double dehalogenation reaction followed by dimerization. First, focusing on the latter two processes and using the nudged elastic band method, we analyze a number of possible mechanisms involving one and two molecules, an…

Limitation of carrier fringe methods in digital photoelasticity

2007

The carrier fringes method has been proposed in digital photoelasticity in combination with techniques such as Fourier transform and phase shifting method, without considering the influence of the isoclinics on the isochromatic patterns analysis. Unlike other optical methods as moire and holographic interferometry, in photoelasticity the light intensity emerging from a circular polariscope is related to both the isochromatic retardation and the isoclinic parameter. As it is shown by the theoretical analysis, owing to the misalignment between the principal stresses in the model and in the carrier, the computed retardation is affected by an error which is the same for all photoelastic methods…

High pressure EXAFS on GaTe single crystal including polarization

1999

Determination of Geometry Arrangement of Copper Ions in HKUST-1 by XAFS During a Prolonged Exposure to Air

2017

We present an experimental investigation focused on the local structural changes taking place around Cu2+ions in metal− organic framework (MOF) HKUST-1 for different times of exposure to air by XAFS (X-ray absorption fine structure). The analysis involves both XANES (X-ray absorption near edge structure) and EXAFS (extended X-ray absorption fine structure) regions around the Cu K-edge. Starting from the paddle-wheel structures proposed in literature, a more detailed description of the geometrical environment of Cu2+ions has been found. In particular, the paddle-wheel structure of a fresh sample, which means a pristine HKUST-1 material with a single water molecule weakly adsorbed on each C…

Airborne Measurements of Contrail Ice Properties—Dependence on Temperature and Humidity

2021

The largest share in the climate impact of aviation results from cirrus clouds. Here, the dependence of microphysical contrail ice properties and extinction on temperature and humidity is investigated. Contrail measurements were performed at various altitudes during the 2018 ECLIF II/NDMAX campaign with the NASA DC-8 chasing the DLR A320. Ice number concentrations and contrail extinction coefficients are largest at altitudes near 9.5 km, typical for short- and medium-range air traffic. At higher altitudes near 11.5 km, low ambient water vapor concentrations lead to smaller contrail particle sizes and lower extinction coefficients. In addition, contrails were detected below 8.2 km near the S…

Gain, detuning, and radiation patterns of nanoparticle optical antennas

2008

International audience; For their capability to localize and redirect electromagnetic field, metal nanoparticles have been recently viewed as efficient nanoantenna operating in the optical regime. In this article, we experimentally investigated the optical responses of coupled gold antenna pairs and measured the critical parameters defining antenna characteristics: resonant frequencies and bandwidths, detuning and gains, and radiation patterns.

Macroscopic and Molecular Insights from CO Adsorption on NaY Zeolite: A Combined FTIR and Manometric Study

2012

International audience; This survey combines both quantitative and IR molecular descriptions and aims to provide new insights for the description of CO adsorption on NaY zeolite at 77 K. Quantitative measurements of the number of CO molecules trapped in the microporous super cage are compared to the corresponding IR spectra of CO as adsorbed species. We demonstrate that polycarbonyls formed during the completion of the accessible S-II Na+ coordinative vacancies result in the formation of mono-, di- and tricarbonyls but not consecutively. Quantitative analysis and measurements of the CO molecules that are adsorbed prove that polycarbonyls coexist with different proportions over the adsorptio…

Perceptually Optimized Image Rendering

2017

We develop a framework for rendering photographic images by directly optimizing their perceptual similarity to the original visual scene. Specifically, over the set of all images that can be rendered on a given display, we minimize the normalized Laplacian pyramid distance (NLPD), a measure of perceptual dissimilarity that is derived from a simple model of the early stages of the human visual system. When rendering images acquired with a higher dynamic range than that of the display, we find that the optimization boosts the contrast of low-contrast features without introducing significant artifacts, yielding results of comparable visual quality to current state-of-the-art methods, but witho…

Upperbounds on the probability of finding marked connected components using quantum walks

2019

Quantum walk search may exhibit phenomena beyond the intuition from a conventional random walk theory. One of such examples is exceptional configuration phenomenon -- it appears that it may be much harder to find any of two or more marked vertices, that if only one of them is marked. In this paper, we analyze the probability of finding any of marked vertices in such scenarios and prove upper bounds for various sets of marked vertices. We apply the upper bounds to large collection of graphs and show that the quantum search may be slow even when taking real-world networks.

Transient dynamics of pulse-driven memristors in the presence of a stable fixed point

2019

Abstract Some memristors are quite interesting from the point of view of dynamical systems. When driven by narrow pulses of alternating polarities, their dynamics has a stable fixed point, which may be useful for future applications. We study the transient dynamics of two types of memristors characterized by a stable fixed point using a time-averaged evolution equation. Time-averaged trajectories of the Biolek window function memristor and resistor-threshold type memristor circuit (an effective memristor) are determined analytically, and the times of relaxation to the stable fixed point are found. Our analytical results are in perfect agreement with the results of numerical simulations.