Search results for "Optical"

showing 10 items of 7671 documents

Solubility and acid-base properties and activity coefficients of chitosan in different ionic media and at different ionic strengths, at T=25°C

2009

Studies on the acid-base properties and solubility of a polyammonium polyelectrolyte (chitosan) with different molecular weights (MW 310 and 50 kDa), were performed at T=25 °C, in the pH range 2.5–7. The protonation of chitosan was investigated by potentiometry ([H+]-glass electrode) in NaCl, NaNO3 and mixed NaNO3+Na2SO4 ionic media, at different ionic strengths. Protonation constants were calculated as a function of dissociation degree α by means of two different models, namely, a simple linear model and the modified Henderson–Hasselbalch equation. Experimental data were also fitted using a model independent of α (Diprotic-like model), according to which the acid-base properties can be sim…

Activity coefficientChemistryInorganic chemistryIonic bondingProtonationChitosan Acid-base properties Solubility Activity coefficients Ion pair formationCondensed Matter PhysicsSettore CHIM/12 - Chimica Dell'Ambiente E Dei Beni CulturaliAtomic and Molecular Physics and OpticsDissociation (chemistry)Electronic Optical and Magnetic MaterialsSpecific ion interaction theoryIonic strengthStability constants of complexesMaterials ChemistrySettore CHIM/01 - Chimica AnaliticaPhysical and Theoretical ChemistrySolubilitySpectroscopyJournal of Molecular Liquids
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Isobaric vapor-liquid equilibria and densities for the system methyl 1,1-dimethylethyl ether+2-propanol

2002

Vapor-liquid equilibrium data at 50, 75 and 94 kPa have been determined for the binary system methyl 1,1-dimethylethyl ether + 2-propanol, in the temperature range 308-344 K. The measurements were made in an equilibrium still with circulation of both the vapor and liquid phases. Excess volumes have been also determined from density measurements using a vibrating tube densimeter at 298.15 K. The system exhibits positive deviation from ideal behavior and does not present azeotropy within the range of pressures studied. The excess volume of the system is negative over the whole mole fraction range. The activity coefficients and boiling points of the solutions were well correlated with the mole…

Activity coefficientUNIQUACChemistryThermodynamicsCondensed Matter PhysicsMole fractionElectronic Optical and Magnetic MaterialsPropanolBoiling pointchemistry.chemical_compoundMolar volumeMaterials ChemistryNon-random two-liquid modelVapor–liquid equilibriumPhysical and Theoretical Chemistry
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Evapotranspiration from an Olive Orchard using Remote Sensing-Based Dual Crop Coefficient Approach

2013

A remote sensing-based approach to estimate actual evapotranspiration (ET) was tested in an area covered by olive trees and characterized by Mediterranean climate. The methodology is a modified version of the standard FAO-56 dual crop coefficient procedure, in which the crop potential transpiration, T p, is obtained by directly applying the Penman-Monteith (PM) equation with actual canopy characteristics (i.e., leaf area index, albedo and canopy height) derived from optical remote sensing data. Due to the minimum requirement of in-situ ancillary inputs, the methodology is suitable also for applications on large areas where the use of tabled crop coefficient values become problematic, due to…

Actual evapotranspirationCanopyEddy covarianceAlbedoPlant transpiration; Optical remote sensing; Dual crop coefficient; Actual evapotranspirationOlive treesSettore AGR/03 - Arboricoltura Generale E Coltivazioni ArboreeCrop coefficientDual crop coefficientEvapotranspirationOptical remote sensingPlant transpirationSettore AGR/08 - Idraulica Agraria E Sistemazioni Idraulico-ForestaliEnvironmental scienceLeaf area indexWater Science and TechnologyCivil and Structural EngineeringTranspirationRemote sensingWater Resources Management
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Development and validation of the SIMPLE endoscopic classification of diminutive and small colorectal polyps

2018

Abstract Background Prediction of histology of small polyps facilitates colonoscopic treatment. The aims of this study were: 1) to develop a simplified polyp classification, 2) to evaluate its performance in predicting polyp histology, and 3) to evaluate the reproducibility of the classification by trainees using multiplatform endoscopic systems. Methods In phase 1, a new simplified endoscopic classification for polyps – Simplified Identification Method for Polyp Labeling during Endoscopy (SIMPLE) – was created, using the new I-SCAN OE system (Pentax, Tokyo, Japan), by eight international experts. In phase 2, the accuracy, level of confidence, and interobserver agreement to predict polyp hi…

AdenomaMODULEValidation studymedicine.medical_specialtyConsensusDelphi TechniqueI-SCANColonoscopyColonic PolypsCOMMUNITY PRACTICE03 medical and health sciencesNarrow Band Imaging0302 clinical medicineEXPERTSPredictive Value of TestsOptical diagnosisADENOMASmedicineHumansHISTOLOGYObserver VariationReproducibilitymedicine.diagnostic_testbusiness.industryGastroenterologyReproducibility of ResultsColonoscopyCOLON POLYPSPredictive valueConfidence intervalEndoscopyTumor Burden030220 oncology & carcinogenesisPredictive value of testsAGREEMENTOPTICAL DIAGNOSIS030211 gastroenterology & hepatologyRadiologybusinessColorectal NeoplasmsEndoscopy
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Trap-limited mobility in space-charge limited current in organic layers

2009

Space-charge limited current transport in organic devices, relevant to the operation of a range of organic optoelectronic devices, is analyzed in the frequency domain. The classical multiple trapping picture with one transport state and one trap level is used as the basis for the descriptions. By varying the energetic and kinetic properties of the traps, we show that the admittance and the capacitance spectra are considerably modified depending on the interplay between the trap-limited mobility and the trap kinetics. We point out that capacitance steps at low-frequency, usually found in experiments, are observed only for slow traps. © 2008 Elsevier B.V. All rights reserved.

AdmittanceCapacitanceTrappingCapacitanceBiomaterialsTrap (computing)OpticsMaterials ChemistryOLEDPhysics::Atomic PhysicsElectrical and Electronic EngineeringElectrical impedanceMobilityCondensed Matter::Quantum GasesOrganic electronicsChemistrybusiness.industryImpedanceGeneral ChemistryCondensed Matter PhysicsSpace chargeTrapElectronic Optical and Magnetic MaterialsOLEDChemical physicsTransport in organic materialsbusinessOrganic Electronics
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Specific separation and recovery of phosphate anions by a novel NiFe-LDH/rGO hybrid film based on electroactivity-variable valence

2022

Phosphorus is a non-renewable resource. Supplies are limited and much phosphorus is currently wasted during the production and utilization process, causing concerns about future supplies and widespread environmental problems. To solve these problems, a new type of NiFe-LDH/rGO electrically switched ion-selective (ESIX) film is designed, based on the dominant mechanism of inner-sphere complexation. An ESIX process allows the NiFe-LDH/rGO hybrid film to achieve a controllably selective uptake and release of the phosphate anions. This route involves tuning potential steps to regulate the redox states of the composite film and the variable metal (e.g., Ni, Fe (II)/(III)) in coordination centers…

Adsorption capacityPhosphorusInner-sphere complexationSettore ING-IND/27 - Chimica Industriale E TecnologicaPhosphatesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsBiomaterialsColloid and Surface ChemistryValence state transitionSelective extractionMetalsLayered double hydroxideHydroxidesGraphitePhosphate anion
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Effect of contact lenses on ocular biometric measurements based on swept-source optical coherence tomography

2019

ABSTRACT Purpose: To determine the reliability of swept- source optical coherence tomography in cases in which soft contact lenses cannot be removed when acquiring biometric measurements. Methods: Eight subjects were included and only one eye per participant was analyzed. Each eye was measured six times by swept-source optical coherence tomography with the IOLMaster 700 instrument (Carl Zeiss Meditec, Jena, Germany). Axial length, central corneal thickness, anterior chamber depth, lens thickness, and keratometric measurements were evaluated for the naked eye and while wearing soft contact lenses of three different powers (-1.5, -3.0, and +2.0 D). Results: There were statistically significan…

AdultBiometryMaterials sciencegenetic structuresContact LensesTomography optical coherenceStatistics Nonparametriclaw.invention03 medical and health sciences0302 clinical medicineOpticslcsh:OphthalmologyOptical coherence tomographyLens thicknessAnterior Eye SegmentReference ValueslawmedicineHumansContact lensesAnalysis of VarianceCross-Over Studiesmedicine.diagnostic_testbusiness.industryReproducibility of ResultsGeneral MedicineAxial lengtheye diseasesContact lensLens (optics)Axial Length EyeOphthalmologylcsh:RE1-994Reference values030221 ophthalmology & optometrysense organsTomographybusinessTomography Optical CoherenceArquivos Brasileiros de Oftalmologia
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Evaluation of the practicality of optical biometry and applanation ultrasound in 253 eyes

2003

Abstract Purpose To evaluate the percentage of eyes that could not be measured using optical biometry and ultrasound applanation and the reasons. Setting Department of Ophthalmology, Johannes Gutenberg-University Hospital, Mainz, Germany. Methods Optical biometry (IOLMaster®, Carl Zeiss Meditec AG) and A-scan ultrasound biometry were performed consecutively in 253 eyes scheduled for cataract surgery the next day. Lens opacities were evaluated with the Opacity Lensmeter (Interzeag), and a slitlamp examination and measurement of visual acuity were performed. The 2 techniques were compared in terms of the rate of and reasons for primary measurement failure. Results Measurement with the IOLMast…

AdultBiometryVisual acuityAdolescentLightPseudophakiagenetic structuresmedicine.medical_treatmentEye diseaseVision DisordersVisual AcuityIntraocular lensDiagnostic Techniques OphthalmologicalEyeRefraction OcularCataractOptical biometryLens Implantation IntraocularHumansMedicineChildAgedUltrasonographyAged 80 and overLenses Intraocularbusiness.industryUltrasoundMiddle AgedCataract surgerymedicine.diseaseeye diseasesSensory SystemsOptical axisOphthalmologyInterferometryChild PreschoolOptometrySurgerysense organsmedicine.symptombusinessPseudophakiaJournal of Cataract and Refractive Surgery
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Noncontact monitoring of vascular lesion phototherapy efficiency by RGB multispectral imaging.

2013

A prototype low-cost RGB imaging system consisting of a commercial RGB CMOS sensor, RGB light-emitting diode ring light illuminator, and a set of polarizers was designed and tested for mapping the skin erythema index, in order to monitor skin recovery after phototherapy of vascular lesions, such as hemangiomas and telangiectasias. The contrast of erythema index (CEI) was proposed as a parameter for quantitative characterization of vascular lesions. Skin recovery was characterized as a decrease of the CEI value relative to the value before the treatment. This approach was clinically validated by examining 31 vascular lesions before and after phototherapy.

AdultDiagnostic ImagingSkin erythemaPathologymedicine.medical_specialtyErythemaMultispectral imageBiomedical EngineeringBiomaterialsYoung AdultMedicineHumansTelangiectasisSkinCMOS sensorintegumentary systembusiness.industrySpectrum AnalysisVascular lesionMiddle AgedPhototherapyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsTreatment OutcomeErythemaRGB color modelmedicine.symptombusinessHemangiomaBiomedical engineeringJournal of biomedical optics
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Changes in Accommodation and Ocular Aberration With Simultaneous Vision Multifocal Contact Lenses

2012

Objective: The aim of this study was to evaluate ocular aberration changes through different simultaneous vision multifocal contact lenses (CLs). Methods: Eighteen young-adult subjects with a mean age of 29.8 +/- 2.11 years took part. Changes in accommodative response, spherical aberration (C-4(0)), horizontal coma (C-3(1)), vertical coma (C-3(-1)), and root mean square (RMS) of higher-order aberrations (HOAs, third to sixth orders) were evaluated. Measurements were obtained with a distance-single vision CL and 2 aspheric multifocal CLs of simultaneous focus center-near design (PureVision Low Add and PureVision High Add) for 2 accommodative stimuli (-2.50 and -4.00 D). All measurements were…

AdultMaleAccommodative responseCross-Over StudiesOptical Phenomenagenetic structuresContact Lensesbusiness.industryVisual AcuityAccommodation OcularComa (optics)Mean ageRefraction Oculareye diseasesOphthalmologyOcular physiologySpherical aberrationCLs upper limitsHumansMedicineOptometryFemalebusinessAccommodationEye & Contact Lens: Science & Clinical Practice
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