Search results for "Orbital"
showing 10 items of 679 documents
Regio(ir)regular naphthalenediimide- and perylenediimide-bithiophene copolymers: How MO localization controls the bandgap
2016
Absorption spectra of regio(ir)regular naphthalenediimide (NDI)- and perylenediimide (PDI)-bithiophene (2T) donor/acceptor (D/A) copolymers are surprisingly similar despite cross-conjugation in the regioirregular structures. This result is traced back to largely localized frontier molecular orbitals (FMOs) as revealed by (time-dependent) DFT calculations. Interestingly, while the FMOs of the P(PDI-2T) copolymer are localized solely in the PDI units, they are predominantly localized in the respective D/A units of the P(NDI-2T) copolymer. The pronounced CT character of the lowest singlet state in P(NDI-2T) should give rise to a close lying CT triplet state, generating small singlet–triplet ga…
Spectral and timing properties of IGR J00291+5934 during its 2015 outburst
2016
We report on the spectral and timing properties of the accreting millisecond X-ray pulsar IGR J00291+5934 observed by XMM-Newton and NuSTAR during its 2015 outburst. The source is in a hard state dominated at high energies by a comptonization of soft photons ($\sim0.9$ keV) by an electron population with kT$_e\sim30$ keV, and at lower energies by a blackbody component with kT$\sim0.5$ keV. A moderately broad, neutral Fe emission line and four narrow absorption lines are also found. By investigating the pulse phase evolution, we derived the best-fitting orbital solution for the 2015 outburst. Comparing the updated ephemeris with those of the previous outbursts, we set a $3��$ confidence leve…
NuSTAR and NICER reveal IGR J17591-2342 as a new accreting millisecond X-ray pulsar
2018
We report the discovery by the Nuclear Spectroscopic Telescope Array (NuSTAR) and the Neutron Star Interior Composition Explorer (NICER) of the accreting millisecond X-ray pulsar IGR J17591-2342. Coherent X-ray pulsations around 527.4 Hz (1.9 ms) with a clear Doppler modulation were detected. This implies an orbital period of ∼8.8 h and a projected semi-major axis of ∼1.23 lt-s. With the binary mass function, we estimate a minimum companion mass of 0.42 M, obtained assuming a neutron star mass of 1.4[subscript ⊙] and an inclination angle lower than 60°, as suggested by the absence of eclipses or dips in the light curve of the source. The broad-band energy spectrum, obtained by combining NuS…
The identification of vicinally substituted cyclohexane isomers in their mixtures by 1H and 13C NMR spectroscopy.
2000
The radical addition reactions of organobromine compounds, XBr (X = CH2COOMe, PhCH2, CHBr2 and CCl3) with cyclohexene afforded mixtures of cis/trans isomer pairs of 1-X-2-Br-cyclohexanes. In addition to benzyl benzoyloxy derivatives are formed also, when benzoyl peroxide is used as an initiator. Owing to the great difficulties in separating these cis/trans isomer pairs, they are identified directly in their mixtures by NMR spectroscopy. In addition to one-dimensional (ID) 1H, proton decoupled 13C and DEPT-135, also two-dimensional (2D) 13C-13C INADEQUATE as well as 1H-13C HMQC experiments have been used in assigning the signals of each compound in their mixtures. The identification of each …
Pseudo-Jahn–Teller Origin of the Metastable States in Sodium Nitroprusside
2003
Abstract A new model for the photochromic effect in sodium nitroprusside Na 2 [Fe(CN) 5 (NO)]·2H 2 O based on the concept of the pseudo-Jahn–Teller effect is proposed. The model takes into account the electron transfer from the Fe 2+ ion to the π ∗ orbitals of the NO-ligand as well as the vibronic mixing of three electronic states of the Fe–NO fragment through the non-symmetric and full symmetric modes. The problem is solved within the adiabatic approximation. Under certain conditions, the lower sheet of the adiabatic potential is shown to possess three minima with the increasing energies that correspond to the N-bound, sideways bound, and O-bound NO group. The barriers between the minima a…
Ophthalmic manifestations in IgG4-related disease
2017
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Survival in rhino-orbito-cerebral mucormycosis: An international, multicenter ID-IRI study
2022
International audience; BACKGROUND: Mucormycosis is an emerging aggressive mold infection. This study aimed to assess the outcome of hospitalized adults with rhino-orbito-cerebral mucormycosis (ROCM). The secondary objective was to identify prognostic factors in this setting. METHODS: This study was an international, retrospective, multicenter study. Patients’ data were collected from 29 referral centers in 6 countries. All qualified as "proven cases" according to the EORTC/MSGERC criteria. RESULTS: We included 74 consecutive adult patients hospitalized with ROCM. Rhino-orbito-cerebral type infection was the most common presentation (n = 43; 58.1%) followed by rhino-orbital type (…
Primary Orbital Liposarcoma in Li-Fraumeni Cancer Family Syndrome: A Case Report
2005
Aims and background The aim of this study was to describe a case of primary orbital liposarcoma in Li-Fraumeni syndrome. Methods and study design In July 1998 a 20-year-old woman with a histological diagnosis of orbital myxoid liposarcoma underwent surgical treatment in our department. Since the patient's family pedigree met the clinical criteria for the diagnosis of LFS, molecular analysis was performed, which resulted in a molecular profile consistent with Li-Fraumeni syndrome. Results The patient underwent orbital exenteration extended to the upper eyelid; surgical reconstructive steps were performed to permit placement of an orbital prosthesis. Two years after primary surgery the patien…
Cognitive priming in sung and instrumental music: Activation of inferior frontal cortex
2006
Neural correlates of the processing of musical syntax-like structures have been investigated via expectancy violation due to musically unrelated (i.e., unexpected) events in musical contexts. Previous studies reported the implication of inferior frontal cortex in musical structure processing. However - due to the strong musical manipulations - activations might be explained by sensory deviance detection or repetition priming. Our present study investigated neural correlates of musical structure processing with subtle musical violations in a musical priming paradigm. Instrumental and sung sequences ended on related and less-related musical targets. The material controlled sensory priming com…
Quality of Life in a German Graves Orbitopathy Population
2010
To evaluate the validity and responsiveness of a German-language version of the disease-specific Graves orbitopathy quality-of-life questionnaire (GO-QOL).Prospective cross-sectional study.At a multidisciplinary university orbital center, 310 consecutive unselected Graves orbitopathy outpatients answered the GO-QOL before undergoing complete ophthalmic and endocrine assessment. The main outcome measures were the GO-QOL and its 2 subscales, Visual Functioning and Appearance.The QOL scores for the subscales Visual Functioning and Appearance were (mean ± SE) 72.5 ± 1.4 and 71.3 ± 1.5, respectively. Visual Functioning and Appearance were higher in mild (82.2 ± 2.2 and 86.0 ± 17.6) than in moder…