Search results for "Orphism."
showing 10 items of 2645 documents
Dual attachment pairs in categorically-algebraic topology
2011
[EN] The paper is a continuation of our study on developing a new approach to (lattice-valued) topological structures, which relies on category theory and universal algebra, and which is called categorically-algebraic (catalg) topology. The new framework is used to build a topological setting, based in a catalg extension of the set-theoretic membership relation "e" called dual attachment, thereby dualizing the notion of attachment introduced by the authors earlier. Following the recent interest of the fuzzy community in topological systems of S. Vickers, we clarify completely relationships between these structures and (dual) attachment, showing that unlike the former, the latter have no inh…
Harmonic morphisms in nonlinear potential theory
1992
This article concerns the following problem: given a family of partial differential operators with similar structure and given a continuous mapping f from an open set Ω in Rn into Rn, then when does f pull back the solutions of one equation in the family to solutions of another equation in that family? This problem is typical in the theory of differential equations when one wants to use a coordinate change to study solutions in a different environment.
Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds
2017
[EN] Understanding the origin of cooperativity and the equilibrium temperature of transition (T1/2) displayed by the spin-crossover (SCO) compounds as well as controlling these parameters are of paramount importance for future applications. For this task, the occurrence of polymorphism, presented by a number of SCO complexes, may provide deep insight into the influence of the supramolecular organization on the SCO behavior. In this context, herein we present a novel family of mononuclear octahedral FeII complexes with formula cis- [Fe(bqen)(NCX)2], where bqen is the chelating tetradentate ligand N,N¿-bis(8-quinolyl)ethane-1,2-diamine and X = S, Se. Depending on the preparation method, these…
High-Pressure Behavior of Nickel Sulfate Monohydrate: Isothermal Compressibility, Structural Polymorphism, and Transition Pathway
2020
Single crystals of synthetic nickel sulfate monohydrate, α-NiSO4·H2O (space-group symmetry C2/c at ambient conditions), were subject to high-pressure behavior investigations in a diamond-anvil cell up to 10.8 GPa. By means of subtle spectral changes in Raman spectra recorded at 298 K on isothermal compression, two discontinuities were identified at 2.47(1) and 6.5(5) GPa. Both transitions turn out to be apparently second order in character, as deduced from the continuous evolution of unit-cell volumes determined from single-crystal X-ray diffraction. The first structural transition from α- to β-NiSO4·H2O is an obvious ferroelastic C2/c–P1̅ transition. It is purely displacive from a structur…
Insights into the crystal packing of phosphorylporphyrins based on the topology of their intermolecular interaction energies
2014
Four metal complexes of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin 1M (M = Cd(II), Ni(II), Pd(II), and Pt(II)) were synthesized and crystallographically characterized. The crystal organization patterns were analyzed using DFT (B97-D3/def2-SVP) calculations of the intermolecular interaction energies between complexes in the crystals. For the systematic analysis of crystal packing, the calculations were extended to previously reported compounds 1M (M = H2, Cu(II), and Zn(II)). Quantitative analysis of the interaction energies shows the essential role of weak intermolecular interactions, such as C-H⋯O, C-H⋯π and M⋯π, in the formation of basic structural motifs and their organization …
Non‐subduction origin for 3.2 Ga high‐pressure metamorphic rocks in the Barberton granitoid‐greenstone terrane, South Africa
2019
The occurrence of high-pressure (HP) garnet-bearing metamorphic rocks in the southern Barberton granitoid-greenstone terrane (BGGT), South Africa, has been proposed as a key indicator of the onset of modern plate tectonics at ca. 3.2 Ga. Here, we report new zircon/titanite U-Pb ages of garnet-bearing HP metamorphic rocks and associated granitoids in the BGGT that argue against such an interpretation. The results show that HP metamorphism occurred synchronously with granitoid magmatism in the Stolzburg domain, the supposed subducted plate, during two episodes at 3.4 and 3.2 Ga, and that these two episodes of magmatism occurred on both sides of the assumed suture zone, a feature that cannot e…
Subduction or sagduction? Ambiguity in constraining the origin of ultramafic–mafic bodies in the Archean crust of NW Scotland
2016
Abstract The Lewisian Complex of NW Scotland is a fragment of the North Atlantic Craton. It comprises mostly Archean tonalite–trondhjemite–granodiorite (TTG) orthogneisses that were variably metamorphosed and reworked in the late Neoarchean to Paleoproterozoic. Within the granulite facies central region of the mainland Lewisian Complex, discontinuous belts composed of ultramafic–mafic rocks and structurally overlying garnet–biotite gneiss (brown gneiss) are spatially associated with steeply-inclined amphibolite facies shear zones that have been interpreted as terrane boundaries. Interpretation of the primary chemical composition of these rocks is complicated by partial melting and melt loss…
Early Neoproterozoic crustal growth and microcontinent formation of the north–central Central Asian Orogenic Belt: New geological, geochronological, …
2021
Abstract In this study, new geological, geochronological, geochemical, and Nd–Hf isotopic data are presented for the Melange Zone within the Zavkhan terrane, Mongolia, and the terrane structure, early Neoproterozoic continental crust growth, and microcontinent formation in the north–central part of the Central Asian Orogenic Belt (CAOB) are discussed. The Melange Zone separates high-grade complexes of the northwestern part of the Zavkhan terrane and unmetamorphosed Neoproterozoic Zavkhan Formation covered by Cryogenian–Cambrian shelf deposits of the southwestern part. Zone consist of a lower-grade association of basalts, basaltic andesites, rarely felsic volcanic rocks, trondhjemites of the…
Zircon and muscovite ages, geochemistry, and Nd-Hf isotopes for the Aktyuz metamorphic terrane: Evidence for an Early Ordovician collisional belt in …
2011
International audience; The Aktyuz metamorphic terrane in the Kyrgyz northern Tianshan consists of granitoid gneisses and migmatites with subordinate paragneisses, greenschists, presumed meta-ophiolites, and garnet amphibolite dykes that contain HP eclogite relicts. The gneisses and migmatites were previously considered to be Archaean and Palaeoproterozoic in age on the basis of α-Pb and U-Pb multigrain zircon dating. Zircons from a post-tectonic granite were previously dated at 692 ± 15 Ma, constraining the time of main deformation and metamorphism in the Aktyuz terrane to the Precambrian. The chemical characteristics of most granitoid samples are consistent with melting of chemically evol…
Kinematics, deformation partitioning and late Variscan magmatism in the Agly massif, Eastern Pyrenees, France
2020
International audience; In order to constrain the finite deformation pattern of the Variscan basement of the Agly massif, a detailed structural analysis over the whole Agly massif was performed. Our investigation combined geological mapping, reappraisal of published and unpublished data completed with our own structural work. Results are provided in the form of new tectonic maps and series of regional cross-sections through the Agly massif. At variance from previous studies, we identified three deformation fabrics named D1, D2 and D3. The D1 deformation is only relictual and characterized by a broadly northwest-southeast striking and eastward dipping foliation without any clear mineral and …