Search results for "Oxide"
showing 10 items of 6424 documents
First combined flux chamber survey of mercury and CO2 emissions from soil diffuse degassing at Solfatara of Pozzuoli crater, Campi Flegrei (Italy): M…
2014
Abstract There have been limited studies to date targeting gaseous elemental mercury (GEM) flux from soil emission in enriched volcanic substrates and its relation with CO 2 release and tectonic structures. In order to evaluate and understand the processes of soil–air exchanges involved at Solfatara of Pozzuoli volcano, the most active zone of Campi Flegrei caldera (Italy), an intensive field measurement survey has been achieved in September 2013 by using high-time resolution techniques. Soil–air exchange fluxes of GEM and CO 2 have been measured simultaneously at 116 points, widely distributed within the crater. Quantification of gas flux has been assessed by using field accumulation chamb…
From 1D coordination polymers to Metal Organic Frameworks by the use of 2-pyridyl oximes.
2020
The synthesis and characterization of coordination polymers and metal&ndash
Fundamental limits for transmission modulation in VO2 metasurfaces
2022
The interest in dynamic modulation of light by ultra-thin materials exhibiting insulator–metal phase transition, such as VO 2 , has rapidly grown due to the myriad industrial applications, including smart windows and optical limiters. However, for applications in the telecommunication spectral band, the light modulation through a thin VO 2 film is low due to the presence of strong material loss. Here, we demonstrate tailored nanostructuring of VO 2 to dramatically enhance its transmission modulation, reaching a value as high as 0.73, which is 2 times larger than the previous modulation achieved. The resulting designs, including free-topology optimization, demonstrate the fundamental limit i…
Catalytic Conversion of Glucose and Chlorella sp. into Furans in the Presence of Niobium Oxide
2023
A series of Nb2O5 solid catalysts have been prepared to be used for the catalytic dehydration of glucose and sugars from algae Chlorella sp. into added value furans. The glucose transformation gave rise to 5-hydroxymethylfurfural (5-HMF). Chlorella sp. was used in the same catalytic conditions to be valorised to furans. By preliminary studies we concluded that the algae aqueous suspension needed a previous treatment in the presence of SiO2 pellets to liberate the carbohydrates that in the catalytic reaction in the presence of Nb2O5 materials gave rise 5-HMF and furfural. The best operative conditions and Nb2O5 catalysts were individuated. The most performant Nb2O5 catalyst also showed an ex…
Fractal-like Hierarchical CuO Nano/Microstructures for Large-Surface-to-Volume-Ratio Dip Catalysts
2022
Dip catalysts are attracting interest in both academia and industry for catalyzing important chemical reactions. These provide excellent stability, better recoverability, recyclability, and easy scale-up. Using the unique microstructures of leaf skeletons, we present a fractal-like hierarchical surface that can be used as a versatile and efficient dip catalyst. Copper oxide microcactuses with nanoscalar features were fabricated onto the Bauhinia racemosa leaf skeletons via a combination of physical vapor deposition, electroplating, and chemical oxidation methods. The coated leaf skeletons have a very high surface area, and the three-dimensional (3D) morphology allows the reactants to encoun…
Theoretical and experimental study of novel types of solid oxide fuel cell electrodes
2016
Master's thesis Renewable Energy ENE500 - University of Agder 2016 Solid oxide fuel cells (SOFCs) have the potential to become one of the efficient and costeffective system for direct conversion of a wide variety of fuels to electricity. The performance, stability and durability of SOFCs depend strongly on the materials used for the fabrication of electrodes as well as the fabrication process. For anode supported SOFCs, the tape casting method has been the de facto standard for constructing cell components. Furthermore, organic solvents such as ethanol, propanol, terpineol and poly-ethers are generally used in industrial tape casting as the solvent medium to make the chemical slurries out o…
Non-stationary nature of SO2 degassing at Etna’s North-east crater (Italy).
2012
Investigating Etna’s long-term SO2 flux behaviour has led to important conclusions on the structure of the volcano’s magma feeding system, magma production (and degassing) rates, and causes for the excess degassing behaviour. Nonetheless, our knowledge of the short-term (timescales of seconds to a few hours) behaviour of magmatic volatiles (e.g., bubble coalescence, separate ascent and surface bursting of gas-rich bubbles) in the volcano’s upper feeding conduit system is still fragmentary, and based on indirect evidences (petrologic-textural data, observation of geophysical signals , physical modelling and laboratory experiments). In the past, direct gas flux measurements at Etna have been ta…
Excitation Transfer Engineering in Ce-Doped Oxide Crystalline Scintillators by Codoping with Alkali-Earth Ions
2018
This work has been supported by the European Social Fund Measure No. 09.3.3-LMT-K-712 activity Improvement of Researchers Qualification by Implementing the World-Class R&D Projects, and by grant #14.W03.31.0004 of the Russian Federation Government. Authors are grateful to CERN Crystal Clear Collaboration and COST Action TD1401 "Fast Advanced Scintillator Timing (FAST)" for support of collaboration.
Tolerance, Adaptation, and Cell Response Elicited by Micromonospora sp. Facing Tellurite Toxicity: A Biological and Physical-Chemical Characterization
2022
The intense use of tellurium (Te) in industrial applications, along with the improper disposal of Te-derivatives, is causing their accumulation in the environment, where oxyanion tellurite (TeO32−) is the most soluble, bioavailable, and toxic Te-species. On the other hand, tellurium is a rare metalloid element whose natural supply will end shortly with possible economic and technological effects. Thus, Te-containing waste represents the source from which Te should be recycled and recovered. Among the explored strategies, the microbial TeO32− biotransformation into less toxic Te-species is the most appropriate concerning the circular economy. Actinomycetes are ideal candidates in…
Deficiency of Nrf2 accelerates the effector phase of arthritis and aggravates joint disease
2011
14 páginas, 8 figuras, 1 tabla.-- et al.