Search results for "PAHS"
showing 10 items of 40 documents
Wood pellets for home heating can be considered environmentally friendly fuels? Polycyclic aromatic hydrocarbons (PAHs) in their ashes
2016
This paper reports the results of the first quantitative investigations of PAHs in wood pellet ashes. Investigations were carried out into the fifteen PAHs identified by the US-Environment Protection Agency (US-EPA) as requiring priority monitoring; other non-US-EPA listed PAHs and perylene were also investigated. The total concentrations for the 17 investigated compounds, expressed as the sum of the concentrations (∑PAHs), in the ashes produced by the wood pellet combustion, ranged from 0.064mg kg-1 to 0.90mg kg-1 of dry weight with a means of 0.31mg kg-1. The lowest concentrations (<0.1mg kg-1) were measured in the conifer ash samples. Concentrations of PAHs found in this paper will al…
Polycyclic aromatic hydrocarbons (PAHs) in coffee brew samples: analytical method by GC-MS, profile, levels and sources.
2009
Roasting is a crucial step for the production of coffee, as it enables the development of color, aroma, and flavor, which are essential for the characterization of the coffee quality. At the same time, roasting may lead to the formation of not desirable compounds, such as polycyclic aromatic hydrocarbons (PAHs). In this paper, we report a method for PAHs determination in coffee brew, based on saponification and liquid-liquid extraction with small volumes of hexane, with exclusion of further processes of purification since we analyze the extract by gas chromatography with mass spectrometric detectors in the single ion monitoring mode (SIM). The total concentration of the 28 compounds investi…
Comparison of different methods for extraction of polycyclic aromatic hydrocarbons (PAHs) from Sicilian (Italy) coastal area sediments.
2012
This paper describes a work aimed at improving the conditions of an extraction method, coupling GC-MS determination, for the analysis without cleanup phase, of polycyclic aromatic hydrocarbons (PAHs) from sediment samples. The automatic Soxhlet extraction in warm mode (using Extraction System B-811 Standard, Buchi) has demonstrated advantages for automation, reduced extraction time, and lower solvent use than for conventional Soxhlet extraction. Under these conditions, the recoveries are very good as they resulted greater than 85 % and, in most of the cases, near 100 %. The repeatability is also satisfactory (relative standard deviation less than 15 %). The detection limits are also accepta…
The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)
2006
Abstract This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percent…
A preliminary study on the ecotoxic potency of wastewater treatment plant sludge combining passive sampling and bioassays.
2021
Highlights • The passive samplers collected bioavail able and bioaccessible chemicals from the WWTP sludge samples. • The sampler extracts were acutely and chronically toxic to water flea. • The sampler extracts were cytotoxic and genotoxic. • The sludge treatment such as composting and digesting diminished the toxicity. • Effect-based methods should be part of the risk assessment of sludge recycling. Sewage sludge is an inevitable byproduct produced in wastewater treatment. Reusing nutrient-rich sludge will diminish the amount of waste ending in soil dumping areas and will promote circular economy. However, during sewage treatment process, several potentially harmful organic chemicals are …
The use of lightweight expanded clay aggregate (LECA) as sorbent for PAHs removal from water.
2012
Author's version of an article in the journal: Journal of Hazardous Materials. Also available from the publisher at: http://dx.doi.org/10.1016/j.jhazmat.2012.03.038 Lightweight expanded clay aggregate (LECA) has been explored as a sorbent for the removal of PAHs (phenanthrene, fluoranthene and pyrene) from water. The efficacy of LECA as a sorbent for PAHs was assessed using contact time, mass of sorbent and sorption isotherms in a series of batch experiments. Maximum (optimum) sorption was reached at 21 h after which the amount of PAHs sorbed remained almost constant. Batch experiments were conducted by shaking a 100 ml solution mixture of individual PAHs (containing 0.02 mg/L) with LECA. T…
How building an underwater pipeline connecting Libya to Sicilian coast is affecting environment: polycyclic aromatic hydrocarbons (PAHs) in sediments…
2009
The purpose of this study was to determine the variation of concentrations and distribution of PAHs in the sediments of the Gela coastal area (Italy) caused by the construction of an underwater pipeline connecting Libya to Sicilian coast. The receiving terminal of offshore pipeline, crossing the Mediterranean Sea, 516 Km long, up to 1127 meters deep, is located in Gela (Sicily, Italy). No bibliographic data regarding hydrocarbons are available for this area. In this paper we report the results of analysis on the water and organic along PAHs.The total concentrations of 16 PAHs in the sediments, analyzed during five surveys, ranged from 2.4 to 434 microg/kg of dry weight. The highest concentr…
Isomer effects in fragmentation of Polycyclic Aromatic Hydrocarbons
2015
We have observed significant differences in the fragmentation patterns of isomeric Polycyclic Aromatic Hydrocarbon (PAH) cations following collisions with helium atoms at center-of-mass energies around 100 eV. This is in contrast to the situation at other collision energies or in photo-absorption experiments where isomeric effects are very weak and where the lowest-energy dissociation channels (H- and C2H2-loss) domihate in statistical fragmentation processes. In the 100 eV range, non-statistical fragmentation also competes and is uniquely linked to losses of single carbon atoms (CHx-losses). We find that such CHx-losses are correlated with the ionic ground state energy within a given group…
Response of soil phosphatase activities to contamination with two types of tar oil.
2018
Tar oil is a complex mixture of hydrocarbon compounds obtained from high-temperature distillation of coal tar. It has been used for over 100 years from now to protect wood and has been applied to wood products, primary utility poles, and railroad ties by pressure methods. Composition of the tar oil depends on the source and typically consists of 85% polycyclic aromatic hydrocarbons (PAHs), 10% phenolic compounds, and 5% heterocyclic compounds. In this research, we performed the laboratory experiment to compare two types of tar oil: C and GX-Plus, and their effects on P-cycling enzymes (phosphatases) in sandy loam and loamy sand. Tar oil was applied to soil samples at the following doses: 2,…
Emerging contaminants related to the occurrence of forest fires in the Spanish Mediterranean
2017
Forest fires can be a source of contamination because, among others, of the use of chemicals to their extinction (flame retardants, FRs), or by the production of Polycyclic Aromatic Hydrocarbons (PAHs) derived from high temperature alteration of organic matter. Up to our knowledge, this study is the first to assess the direct (PAHs 16 on the USA EPA's priority list), and indirect [tri- to hepta- brominated diphenyl ethers (PBDEs), organophosphorus flame retardants (PFRs) and perfluoroalkyl substances (PFASs)] contamination related to forest fires. The abundance and distribution of these contaminants were monitored on two Mediterranean hillslopes, one burned and one unburned, near Azuébar (S…