Search results for "PALLADIUM"
showing 10 items of 956 documents
Phenylation of cationic allylpalladium(II) complexes by tetraphenylborate anion. A mechanistic study
1990
Abstract The mechanism of the reaction of allyl complexes [Pd(η3-2-R′C3H4)(NN′)]+ (NN′ = α-diimine ligand) wiht BPh4− in the presence of activated olefins (ol), yielding the products [Pd(η2-ol)(NN′)] and PhCH2C(R′)CH2, has been investigated. The results are interpreted in terms of extensive association between the cationic substrate and the BPh4− anion in a tight ion-pair, followed by rate-determining phenyl transfer to the palladium center and fast reductive elimination of allylbenzene.
ChemInform Abstract: ortho-Functionalized Aryltetrazines by Direct Palladium-Catalyzed C-H Halogenation: Application to Fast Electrophilic Fluorinati…
2016
A general catalyzed direct C-H functionalization of s-tetrazines is reported. Under mild reaction conditions, N-directed ortho-C-H activation of tetrazines allows the introduction of various functional groups, thus forming carbon-heteroatom bonds: C-X (X=I, Br, Cl) and C-O. Based on this methodology, we developed electrophilic mono- and poly-ortho-fluorination of tetrazines. Microwave irradiation was optimized to afford fluorinated s-aryltetrazines, with satisfactory selectivity, within only ten minutes. This work provides an efficient and practical entry for further accessing highly substituted tetrazine derivatives (iodo, bromo, chloro, fluoro, and acetate precursors). It gives access to …
Hydrogen Adsorption in Zeolite Studied with Sievert and Thermogravimetric Methods
2012
Natural clinoptilolite (mixture from clinoptilolite, quartz and muscovite) is activated with palladium and tested for hydrogen adsorption capability at temperatures RT - 200 o C. Thermogravimetric and volumetric methods showed that zeolite activated with palladium (1.25%wt) shows markedly high hydrogen adsorption capacity - up to 3 wt%. Lower amount of adsorbed hydrogen (~1.5 wt%) was found for raw zeolite and activated with higher amount of palladium sample. Hypothesis is proposed that the heating of zeolite in argon atmosphere forms and activates the pore structure in zeolite material, where hydrogen encapsulation (trapping) is believed to occur when cooling down to room temperature. An e…
Synthesis and Characterization of Palladium Nanoparticle/Polypyrrole Composites
2008
In this work, a simple non-template one-step method for the synthesis of 2.0−2.5 nm palladium nanoparticles encapsulated into a polypyrrole shell via direct redox reaction between palladium(II) acetate and pyrrole in acetonitrile medium is described. Palladium nanoparticles are found to be able to self-organize into spherical Pd/PPy composites. The size of the Pd/PPy composite particles and Pd content in the composite depend strongly on the concentration of the palladium salt component. The combination of elemental CHNS and thermogravimetric (TGA) analysis was used to determine a high (∼40 wt %) content of palladium, which is in a good agreement with EDX data. The process of Pd/PPy composit…
Palladium supported on Halloysite-triazolium salts as catalyst for ligand free Suzuki cross-coupling in water under microwave irradiation
2015
Abstract Environmental friendly halloysite-dicationic triazolium salts (second generation) obtained by subsequent click reactions of a diyne derivative in the presence of 2-azidopropyl-modified halloysite nanotubes, were used as supports for palladium catalyst. Thanks to the high triazolium loading (25%) these materials were able to support higher amount of the metal than that on the monocationic derivative (first generation). Such materials were characterized by thermogravimetric analysis, FT-IR spectroscopy and SEM investigations. The new catalytic system was employed in the ligand free Suzuki cross-coupling under microwave irradiation. A set of solvent, time and% loading of palladium was…
Catalytic CO oxidation over pumice supported Pd–Ag catalysts
2001
Abstract Results on the catalytic oxidation of CO at 523 K over bimetallic Pd–Ag catalysts supported on pumice are reported and compared with those obtained from the monometallic Pd and Ag catalysts. The catalysts were prepared by organometallic precursors and were characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) after different treatments with air and with hydrogen. The activity of the catalysts decreases with increasing Ag/Pd atomic ratio, the monometallic palladium exhibiting the highest activity. Furthermore, the treatment with air and with hydrogen always results in a better catalytic performance. On the basis of the structural characterization by XRD…
Synthesis of the Glycopeptide Partial Sequence A80-A84 of Human Fibroblast Interferon
1985
The glycopentapeptide H-(GlcNAcβ1-)Asn-Glu-Thr-Ile-Val-OH (10) representing the partial sequence A80–A84 of human fibroblast interferon was synthesized using the newly developed allyl-ester protection of carboxy functions. The allyl esters, which are stable to acids and to bases, can be cleaved under very mild, neutral conditions using tris(triphenylphosphine)rhodium(I) chloride or tetrakis(triphenylphosphine)palladium(0) as a catalyst. This synthetic method opens up a preparative route to glycopeptide model structures of glycoproteins of high biological interest.
ChemInform Abstract: SYNTHESIS OF THE GLYCOPEPTIDE PARTIAL SEQUENCE A80-A84 OF HUMAN FIBROBLAST INTERFERON
1985
The glycopentapeptide H-(GlcNAcβ1-)Asn-Glu-Thr-Ile-Val-OH (10) representing the partial sequence A80–A84 of human fibroblast interferon was synthesized using the newly developed allyl-ester protection of carboxy functions. The allyl esters, which are stable to acids and to bases, can be cleaved under very mild, neutral conditions using tris(triphenylphosphine)rhodium(I) chloride or tetrakis(triphenylphosphine)palladium(0) as a catalyst. This synthetic method opens up a preparative route to glycopeptide model structures of glycoproteins of high biological interest.
A new efficient, highly dispersed, Pd nanoparticulate silica supported catalyst synthesized from an organometallic precursor. Study of the homogeneou…
2018
[EN] A new Pd(0) catalyst supported on silica UVM-7 has been synthesized from the organometallic [Pd-2(mu-(C6H4) Pp(2))(2)(CH3CN)(4)](BF4)(2) precursor, characterized by the high dispersion, activity, and small size of the palladium nanoclusters fixed on the silica surface. The catalyst was tested for the Suzuki-Miyaura (SM) reaction of different 4-substitutedphenyl halides with phenylboronic acid. The kinetic study concurs with most of the catalytic action was carried out by Pd species originated by the partial solubilization of Pd immobilized on mesoporous silica. The Schmidt's analysis of differential selectivity (SADS) in several competitive SM reactions, together the STEM-HAADF and HRT…
Investigation of diffusion and electromigration of hydrogen in palladium and PdAg alloy
1999
Abstract Diffusion and electromigration of hydrogen in PdH 0.1 , Pd 77 Ag 23 H 0.1 and Pd 50 Ag 50 H 0.1 alloy were measured by means of resistivity method. It is known that hydrogen migrates towards the cathode within the temperature range of 300–473 K in the PdH 0.1 and Pd 77 Ag 23 H 0.1 system. In Pd 50 Ag 50 H 0.1 , hydrogen migrates towards the cathode below 400 K, but towards the anode at higher temperatures. Its effective valency increases together with temperature. At the same time it satisfies the linear dependence on inverse specific resistance ρ : Z eff = Z i +( k / ρ ). The constants Z i and k have the following values: (1.05±0.01) and −(3.81±0.04)×10 −8 Ω m for hydrogen in PdH …