Search results for "PD"

The Calderón problem for the fractional Schrödinger equation

2020

We show global uniqueness in an inverse problem for the fractional Schr\"odinger equation: an unknown potential in a bounded domain is uniquely determined by exterior measurements of solutions. We also show global uniqueness in the partial data problem where the measurements are taken in arbitrary open, possibly disjoint, subsets of the exterior. The results apply in any dimension $\geq 2$ and are based on a strong approximation property of the fractional equation that extends earlier work. This special feature of the nonlocal equation renders the analysis of related inverse problems radically different from the traditional Calder\'on problem.

Structure Sensitivity of 2-Methyl-3-butyn-2-ol Hydrogenation on Pd: Computational and Experimental Modeling

2014

In the frame of DFT paradigms, the adsorption of 2-methyl-3-butyn-2-ol (MBY) and 2-methyl-3-buten-2-ol (MBE) on a Pd-30 cluster, including both {100} and {111} faces, was studied along with the pathways involved in the hydrogenation, taking place on plane and low coordination (corner/edge) sites of given MBY/Pd-30 and MBE/Pd-30 surface configurations. The calculated energetics, further validated by gas-phase and water-assisted gas-phase MBY and MBE hydrogenation, performed on well-defined size and shape-controlled Pd nanoparticles supported on SiO2, were able to explain the origin of the structure sensitivity and the high selectivity characterizing the title reaction when occurring in aqueo…

[2]Catenanes and inclusion complexes derived from self-assembled rectangular PdII and PtII metallocycles

2012

New inclusion complexes and [2]catenanes were self-assembled from a fluorescent diazapyrenium based ligand, a PdII or PtII complex, and cyclic or acyclic electron rich aromatic guests in aqueous and organic media. The molecular rectangles display a π-deficient cavity suitable to incorporate π-donor aromatic systems. The inclusion complexes between the metallocycles and phenylenic (2a,b) and naphthalenic (3a,b–5a,b) derivatives were studied by NMR, UV-vis and fluorescence spectroscopy. The crystal structure of (3b) ⊂ 1a·6PF(6) confirmed the insertion of the guest into the cavity of the metallocycle. Following the same self-assembly strategy, the use of polyethers 6,7 as π-donors resulted in …

The blue enamels in the baroque decorations of the churches of Palermo, Sicily: Fe2+-coloured glasses from lime kilns

2009

Deep blue glasses coloured by octahedral Fe 2+ cations are often reported as textbook examples of blue pigmentation. However, despite the possibility of laboratory synthesis under reducing conditions, to date there are no well-reported occurrences of their production and use in the past. A thorough historical, ethnographic, mineralogical, and chemico-physical investigation of the 'smaltini di calcara' from several baroque churches in Palermo, Sicily, has revealed that the blue enamels widely used for altar decorations in the 17th and 18th centuries are actually a unique case of ancient blue glasses pigmented by divalent iron cations in distorted octahedral coordination. This mixed-alkali gl…

Daylighting offices: A first step toward an analysis of photobiological effects for design practice purposes

2014

Abstract The research presented in this paper reports an analysis of daylight in three offices with different exposures and characteristics located in Naples (Italy). The goal was to fully investigate daylight characteristics, also considering the circadian impact of daylight entering these offices, with the hope to develop guidelines to better assess daylight quality in built environments. One of the main findings of this research is that the spectral distributions and CCTs of the light reaching the eye of a person seated at the desk in these offices are similar irrespective of the offices' different characteristics (dimensions, surfaces' spectral reflectances, external obstructions, etc.)…

Outcome and attitudes toward home tracheostomy ventilation of consecutive patients: a 10-year experience.

2008

Summary Objectives To describe survival, predictors of long-term outcome and attitudes in patients treated at home by tracheostomy-intermittent positive-pressure ventilation (TIPPV) for respiratory failure during a 10-year period (1995–2004). Methods Seventy-seven consecutive patients were treated by TIPPV at home. Patients were divided into three groups: neuromuscular, pulmonary, and non-pulmonary patients. Effects of TIPPV on survival, factors influencing outcome after TIPPV, and attitudes of patients and caregivers regarding mechanical ventilation were studied. Results Forty-one patients (53%) were neuromuscular, 19 (25%) were affected by pulmonary diseases, and 17 (22%) by non-pulmonary…

Asbestos: decontamination works and use of individual protection devices. Some remarks on the right use of IPD, considering the cost-benefit relation

2004

The FRAM robotic telescope for atmospheric monitoring at the Pierre Auger Observatory

2021

FRAM (F/Photometric Robotic Atmospheric Monitor) is a robotic telescope operated at the Pierre Auger Observatory in Argentina for the purposes of atmospheric monitoring using stellar photometry. As a passive system which does not produce any light that could interfere with the observations of the fluorescence telescopes of the observatory, it complements the active monitoring systems that use lasers. We discuss the applications of stellar photometry for atmospheric monitoring at optical observatories in general and the particular modes of operation employed by the Auger FRAM. We describe in detail the technical aspects of FRAM, the hardware and software requirements for a successful operati…

ASYMPTOTIC ANALYSIS OF THE LINEARIZED NAVIER–STOKES EQUATION ON AN EXTERIOR CIRCULAR DOMAIN: EXPLICIT SOLUTION AND THE ZERO VISCOSITY LIMIT

2001

In this paper we study and derive explicit formulas for the linearized Navier-Stokes equations on an exterior circular domain in space dimension two. Through an explicit construction, the solution is decomposed into an inviscid solution, a boundary layer solution and a corrector. Bounds on these solutions are given, in the appropriate Sobolev spaces, in terms of the norms of the initial and boundary data. The correction term is shown to be of the same order of magnitude as the square root of the viscosity. Copyright © 2001 by Marcel Dekker, Inc.

On vibrating thin membranes with mass concentrated near the boundary: an asymptotic analysis

2018

We consider the spectral problem \begin{equation*} \left\{\begin{array}{ll} -\Delta u_{\varepsilon}=\lambda(\varepsilon)\rho_{\varepsilon}u_{\varepsilon} & {\rm in}\ \Omega\\ \frac{\partial u_{\varepsilon}}{\partial\nu}=0 & {\rm on}\ \partial\Omega \end{array}\right. \end{equation*} in a smooth bounded domain $\Omega$ of $\mathbb R^2$. The factor $\rho_{\varepsilon}$ which appears in the first equation plays the role of a mass density and it is equal to a constant of order $\varepsilon^{-1}$ in an $\varepsilon$-neighborhood of the boundary and to a constant of order $\varepsilon$ in the rest of $\Omega$. We study the asymptotic behavior of the eigenvalues $\lambda(\varepsilon)$ and the eige…