Search results for "PEDOT"
showing 10 items of 101 documents
Application and evaluation of the SWAP model for simulating water and solute transport in a cracking clay soil
2005
In Sicily, the increasing scarcity of quality water is leading to irriga- from salinization (Crescimanno et al., 2004). tion with saline water in soils having a considerable susceptibility to In Sicily, the increasing scarcity of good quality water cracking. Irrigation systems involving high application rates are used coupled with intensive use of soil under semiarid to arid in these irrigated areas, and bypass flow during irrigation is thus climatic conditions, is leading to irrigation with saline prevalent. Adoption of management practices accounting for cracking water on soils having a high shrink-swell potential and is therefore necessary to prevent salinization and land degradation. su…
Assessing soil moisture regimes with traditional and new methods
2002
Soil moisture regime classes are required by U.S. soil taxonomy and other classification systems. Soil moisture regimes are based on long-term daily data of soil water content, which are as a rule estimated by means of models. International Commitee on Soil Moisture and Temperature Regimes (ICOMMOTR) has proposed classifying pedoclimate on the basis of biweekly water potential. This study was conducted to validate the use of the Erosion-Productivity Impact Calculator (EPIC) model in assessing soil water content of experimental fields placed in different European pedoclimatic conditions, to compare the pedoclimatic classification obtained with EPIC with those produced by the traditional Bill…
Testing different approaches to characterize Burundian soils by the best procedure
2011
Abstract The Beerkan Estimation of Soil Transfer parameters (BEST) procedure seems attractive for soil hydraulic characterization but it has received little testing so far. The objective of this investigation was to test BEST with different application approaches for some soils in Burundi, where there is the need of using simple methods to characterize soils. Most (14) of the 19 sampled sites had a clay soil texture whereas texture ranged from silty clay to loam in the other cases. On average, the fitting ability of both the particle size distribution (PSD) model (mean relative error, Me ( E r ) = 2.0%) and the cumulative infiltration model ( Me ( E r ) = 2.3%) was good according to recomme…
Removing Leakage and Surface Recombination in Planar Perovskite Solar Cells
2019
Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead iodide perovskite solar cells by replacing the commonly used hole transport layer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) with a better hole-selective polyarylamine. As a result, these cells exhibit superior operation under reduced light conditions, which we demonstrate for the extreme case of moonlight irradiance, at which open-circuit voltages of 530 mV can still be obtained. By the shunt removal we also observe the VOC to dro…
A method for soil moisture probes calibration and validation of satellite estimates
2017
Graphical abstract
Preparation of conductive PDDA/(PEDOT:PSS) multilayer thin film: influence of polyelectrolyte solution composition.
2014
Abstract Self-assembled multilayer films made of PEDOT:PSS poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) and PDDA poly(diallyldimethylammonium chloride) were prepared using layer-by-layer method. In order to modify the growth regime of the multilayer, to fabricate an electrical conductive film and to control its thickness, the effects of pH, type of electrolyte, ionic strength and polyelectrolyte concentration were investigated. Optical reflectometry measurements show that the pH of the solutions has no effect on the film growth while the adsorbed amount increases more rapidly when BaCl2 is used instead of NaCl as electrolyte. An increase in the ionic strength (with NaCl) induces…
PEDOT thin films with n-type thermopower
2019
peer-reviewed Synthesis of n-type organic semiconductors is challenging as reduced states are difficult to obtain due to their instability in air. Here, we report tailoring of semiconducting behavior through control of surfactant concentration during synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticles. Nanoparticles were synthesized by mini-emulsion polymerization, where stable suspensions were used to produce polymer films by a simple casting technique on polyethylene terephthalate (PET) substrates. Electrical conductivity and Seebeck coefficients were measured as a function of surfactant concentration. It was found that conductivity decreases three orders of magnitude as s…
Electrochemical Fabrication and Physicochemical Characterization of Metal/High-k Insulating Oxide/Polymer/Electrolyte Junctions
2014
Photoelectrochemical polymerization of poly(3,4-ethylenedioxythiophene), PEDOT, was successfully realized on anodic film grown to 50 V on magnetron sputtered Ti-6 atom % Si alloys. Scanning electron microscopy allowed us to evidence formation of compact and uniform polymer layers on the oxide surface. Photoelectrochemical and impedance measurements showed that photopolymerization allows one to grow PEDOT in its conducting state, while a strong cathodic polarization is necessary to bring the polymer in its p-type semiconducting state. Information on the optical and electrical properties of metal/oxide/polymer/electrolyte junctions proves that PEDOT has promising performance as an electrolyte…
Electrochemically induced free solvent transfer in thin poly(3,4-ethylenedioxythiophene) films
2015
International audience; In dynamic intrinsically conducting films, counterions transfer and conformational movements stimulated by the electrochemical reactions affect the free water molecules transfer. Poly(3,4-ethylenedioxythiophene) or PEDOT is included in this category. Here, p-doping of PEDOT immersed in LiClO4 aqueous solution was explored by ac-electrogravimetry. Electrochemical impedance spectroscopy combined with mass impedance spectroscopy proves useful for species identification and kinetics. For PEDOT, new equations have been developed to analyze the ac -electrogravimetry response. Quantitatively, faster free water transfer and slower coupled View the MathML sourceClO4−/free wat…
Fabrication of a biocompatible and continuous glucose biosensor with the poly(3,4-ethylenedioxythiophene) modified electrode
2019
Abstract In this study, we have explored the potentiality of using GOx/AuNP/PEDOT(BSA)/Pt electrode as an implantable, long-lasting, and sensitive glucose biosensor. We have examined the performance of the electrode for glucose calibration with three electrochemical measurements, such as cyclic voltammetry, linear sweep voltammetry, as well as chronoamperometry, which all exhibited strong linear correlation between resulting signal and glucose concentration. In comparison, linear sweep voltammetry gave the best linear sensitivity, whose average was about 3.124 µA/mM/cm2 within a wide glucose concentration range from 0.416 to 50 mM. Meanwhile, the stability of the electrode was confirmed by …