Search results for "PEDOT"
showing 10 items of 101 documents
INFLUENCE OF PARTICLE-SIZE DISTRIBUTION MEASUREMENT METHOD ON THE PREDICTION OF SOIL WATER RETENTION CURVE
2013
Application of the Arya and Paris (AP) model to estimate the soil water retention curve requires detailed particle-size distributions (PSD) that can be obtained by fitting a continuous model to traditional sieve-hydrometer (SH) data or using the laser diffraction (LD) method. The AP model was applied to 40 Sicilian soils for which PSD was measured by both SH and LD methods. The scale factor was set equal to 1.38 (procedure AP1) or estimated by a logistic model with parameters gathered from literature (procedure AP2). To simplify application of the AP model, a relationship for estimating a soil-specific value from clay content was developed (procedure OPT). For both SH and LD data, proce…
PV effect of fullerene/poly(3-hexylthiophene) blend sensitized by phthalocyanine having infrared absorption CT band
2008
An attempt was made to extend the photosensitivity spectral range of fullerene/poly(3-hexylthiophene) blend to NIR region by adding extra electron donor — hydroxygallium phthalocyanine (GaOHPc) with a strong and wide intermolecular charge transfer (CT) band around 830 nm. Multilayer cells of ITO/PEDOT: PSS/6 GaOHPc/P3HT: C61(CO2Et)2 have been prepared by spin coating with vacuum evaporated Al or In top electrodes. Significant photosensitivity of the cells was in 370–900 nm spectral range. However charge carrier photogeneration efficiency was 3 times higher for illumination in P3HT absorption band as compared with the GaOHPc CT band at 830 nm. But when GaOHPc was mixed in the blend forming P…
Characterization of thermoelectric and thermogravimetric properties of conductive PEDOT:PSS films blended with SWCNTs and PVA
2019
Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was blended with polyvinyl alcohol (PVA) and single-walled carbon nanotube (SWCNT) filler to form composites with thermoelectric properties. Studied samples were obtained by drop coating and solution casting methods. Thermoelectric measurements of PEDOT:PSS demonstrated that the addition of 5 wt. % SWCNTs increased the Seebeck coefficient value from 8.0 μV/K to 23.6 μV/K, while in the case of PEDOT:PSS/PVA blended with 5 wt. % SWCNT Seebeck coefficient value of 20.3 μV/K was achieved. Thermogravimetric analysis showed slight SWCNT effect on thermal stability of the investigated systems.
Push‐Pull Design of Bis(tridentate) Ruthenium(II) Polypyridine Chromophores as Deep Red Light Emitters in Light‐Emitting Electrochemical Cells
2013
Light-emitting electrochemical cells (LECs) with a simple device structure were prepared by using heteroleptic bis(tridentate) ruthenium(II) complexes [1](PF6)(2)-[3](PF6)(2) as emitters. The push-pull substitution shifts the emission energy to low energy, into the NIR region. The devices emit deep red light up to a maximum emission wavelength of 755 nm [CIE (International Commission on Illumination) coordinates: x = 0.731, y = 0.269 for [3](PF6)(2)], which, to the best of our knowledge, is the lowest emission energy for LECs containing bis(tridentate) ruthenium(II) complexes. A device structure of ITO/PEDOT:PSS/ruthenium(II) complex/Ag was used, and the thickness of the emitting layer was …
UHF RFID humidity sensor tag based on hygroscopic polymeric load
2012
Passive UHF RFID tags, beside item labelling, are also able to exploit capability of sensing the physical state of the tagged object as well as of the surrounding environment. Here a family of polymer-doped tags are proposed and fully characterized for the detection of ambient humidity. A sensitive chemical species based on PEDOT: PSS is used to dope a properly shaped slot carved into a folded-like patch tag. The sensing capabilities of the radio-sensor are investigated by means of measurements for different quantities of sensitive material and in cyclic exposures. The device could have interesting application in the assessment of the air quality in living and controlled rooms, in the monit…
Taxonomic and environmental implication of pedotechnique in large scale farming
2016
Abstract Human activities that involve deep modifications of the soils and a substantial deterioration of their features are numerous and very diverse. Such activities are considered as pedotechniques and, in large-scale farming, are used only under the boost of significant economic returns. In these last decades, the pedotechniques used to tailor soils suitable for table vine cultivation in the Acate valley (Sicily, Italy), not only led to objective difficulties in the classification of these deeply transformed soils but also, to several environmental hazards. In this work after considering the pedotechniques used in tailoring suitable soil for table vine cultivation, we propose to introdu…
Soil interpretation in the context of anthropedogenic transformations and pedotechniques application
2018
Abstract Following a long and vigorous study carried out by the International Committee on Anthropogenic Soils (ICOMANTH), the Soil Taxonomy (ST) classification system recently incorporated a number of changes to include Human-Altered and Human-Transported soils, generally called anthropogenic soils. These changes underwent careful scrutiny as they affect the current classification of existing soil series, and as the proposals and logics are as yet untested against existing data and descriptions. Particular attention was given to the diagnostic characteristics of the anthropogenic soils and to the Subgroups for Human-Altered and Human-Transported soils. In this study, we consider a frequent…
Efficient Monolithic Perovskite/Perovskite Tandem Solar Cells
2016
Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead iodide perovskite solar cells by replacing the commonly used hole transport layer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) with a better hole-selective polyarylamine. As a result, these cells exhibit superior operation under reduced light conditions, which we demonstrate for the extreme case of moonlight irradiance, at which open-circuit voltages of 530 mV can still be obtained. By the shunt removal we also observe the VOC to dro…
Polymer-doped UHF RFID tag for wireless-sensing of humidity
2012
Passive UHF RFID tags, beside item labelling, are also able to exploit capability of sensing the physical state of the tagged object as well as of the surrounding environment. Here a family of polymer-doped tags are proposed and fully characterized for the detection of ambient humidity. A sensitive chemical species based on PEDOT:PSS is used to dope a properly shaped slot carved into a folded-like patch tag. The communication and sensing capabilities of the radio-sensor are investigated by means of simulation and measurements showing how to control and balance above opposite requirements by dosing the quantity of sensitive material. The device could have interesting application in the asses…
Hybrid LEDs based on ZnO nanowire structures
2017
Abstract This paper summarized the research, development, and state of the art of hybrid ZnO nanowire LEDs, in which electroluminescence is generated at the junction between n-type doped ZnO nanowire structures and specific p-type doped polymers (in particular PEDOT, PEDOT:PSS, or PFO). Different device architectures will be reviewed and discussed with a particular emphasis on the electronic transport through the hybrid structures and the microscopic processes of light emission. Finally, a gas-phase deposition technique for conductive polymers will be presented which might help improve the performance of hybrid ZnO nanowire LEDs in the future.