Search results for "PEDOT"

Enhanced thermoelectric performance of PEDOT with different counter-ions optimized by chemical reduction

2014

This work reports on the synthesis of the intrinsically conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) doped with several counter-ions, ClO4, PF6 and bis(trifluoromethylsulfonyl)imide (BTFMSI), by electro-polymerization and its thermoelectric properties. We show that, depending on the counter-ion size, the thermoelectric efficiency of PEDOT can be increased up to two orders of magnitude. A further chemical reduction with hydrazine optimizes the power factor (PF). By changing the counter-ions, we were able to increase the electrical conductivity (σ) of PEDOT by a factor of three, while the Seebeck coefficient remains at the same order of magnitude in the three polymers. The best…

2016

The organic electrochemical transistor (OECT), capable of transducing small ionic fluxes into electronic signals in an aqueous environment, is an ideal device to utilize in bioelectronic applications. Currently, most OECTs are fabricated with commercially available conducting poly(3,4-ethylenedioxythiophene) (PEDOT)-based suspensions and are therefore operated in depletion mode. Here, we present a series of semiconducting polymers designed to elucidate important structure–property guidelines required for accumulation mode OECT operation. We discuss key aspects relating to OECT performance such as ion and hole transport, electrochromic properties, operational voltage, and stability. The demo…

Light emitting and electrical properties of pure amorphous thin films of organic compounds containing 2-tert-butyl-6-methyl-4H-pyran-4-ylidene

2013

Abstract Low molecular weight organic compounds which make thin films from organic solutions would be a great benefit in future organic light emitting systems. Two most important advantages should be mentioned. First – repeatability of synthesis of small molecules is better than of polymers. Second – wet casting methods can be applied. In this paper we present optical and opto-electrical properties of three glassy forming compounds containing 2-tert-butyl-6-methyl-4H-pyran-4-ylidene fragment as a backbone. They have the same N,N-dialkylamino electron donating group with attached bulky trityloxyethyl groups. The difference between these compounds is in an electron acceptor group. One has ind…

Quantifying the inverse spin-Hall effect in highly doped PEDOT:PSS

2020

The authors provide experimental results that show the onset of the Nernst effect, thermovoltages and an inverse spin-Hall effect in the polymer PEDOT:PSS. Specifically, the observed inverse spin-Hall effect appears to be smaller than other measurements, but in better agreement with theoretical calculations.

Effect of conductivity of hole injection layer on the performance of a blue light emitting solution processable OLED

2005

The performance of blue emitting OLED devices, using a polyspiro as blue light emitting polymer, were studied as a function of the conductivity of a novel hybrid hole injection material. The hole injection material is based on a polyarylamine using a molecular magnet as oxidant. The charge density and the luminance of the devices changed considerably with increasing conductivity of the hole injection layer. The change in device performance can be attributed to a change from a hole limited device to a balanced charge carrier device and eventually to an electron limited device. The performance of the optimized device configuration is significantly improved with respect to a device making use …

Spatial and short-term temporal variations in runoff, soil aggregation and other soil properties along a Mediterranean Climatological Gradient.

1998

Abstract Physical and chemical soil properties were measured along a mountainous climatological gradient in the province of Alicante (Spain). The objective was to evaluate how the climate affects certain soil properties at different temporal and spatial scales. These properties include infiltration, runoff and sediment concentrations resulting from rainfall simulation experiments performed in winter and in summer. Chemical soil properties like carbonate content, organic matter content and CEC were analysed in reference soil profiles along the gradient. Physical soil properties like soil moisture content, macroaggregation and waterstable microaggregation were measured at monthly intervals du…

Light-emitting thin films of glassy forming organic compounds containing 2-tert-butyl-6-methyl-4H-pyran-4-ylidene

2012

Low molecular mass organic compounds which make thin films from volatile organic solutions would be great benefit in future organic light emitting systems. Two most important advantages could be mentioned. First - the repetition of synthesis of small molecules is better than for polymers. Second - wet casting methods could be used. In this work we are presenting optical, electroluminescence and amplified spontaneous emission properties of four original glassy forming compounds containing 2-tert-butyl-6-methyl-4H-pyran-4-ylidene fragment as backbone of the molecule. They has the same N,N-dialkylamino electron donating group with incorporated bulky trityloxy ethyl groups. The difference of th…

Electrochemical Synthesis of an Organic Thermoelectric Power Generator.

2020

[EN] Energy harvesting through residual heat is considered one of the most promising ways to power wearable devices. In this work, thermoelectric textiles were prepared by coating the fabrics, first with multiple-wall carbon nanotubes (MWCNTs) by using the layer-by-layer technique and second with poly(3,4-ethylenedioxythiophene) (PEDOT) deposited by electrochemical polymerization. Sodium deoxycholate and poly(diallyldimethylammonium chloride) were used as stabilizers to prepare the aqueous dispersions of MWCNTs. The electrochemical deposition of PEDOT on the MWCNT-coated fabric was carried out in a three-electrode electrochemical cell. The polymerization of PEDOT on the fabric increased the…

Economic aspects of pedotechnique applications in large scale farming: a case study

2016

Conference of the World Association of Soil and Water Conservation

Repercussion of anthropogenic landscape changes on pedodiversity and preservation of the pedological heritage

2013

Over a period of time people have lived in and with their surrounding landscapes and for several thousand years transformed the soilscapes and the vegetation into cultural landscape types important for their economy and to meet their needs (Richter 2007, Ellis 2011, Hjelle 2012). The sustainable provision of goods and services depends critically on managing soils without damaging the natural soilscapes and the related natural resources. To support the transition towards sustainable development, science needs to understand how land-use change affects the environment and how this, in turn, feeds back into human livelihood strategies or infl uences the vulnerability of the environment (Rounsev…