Search results for "PERT"

showing 10 items of 7689 documents

Mossbauer spectroscopic study of the thermal spin crossover in [Fe(II)(isoxazole)(6)](ClO(4))(2)

2008

The (57)Fe Mossbauer spectroscopy of mononuclear [Fe(II)(isoxazole)(6)](ClO(4))(2) has been studied to reveal the thermal spin crossover of Fe(II) between low-spin (S = 0) and high-spin (S = 2) states.Temperature-dependent spin transition curves have been constructed with the least-square fitted data obtained from the Mossbauer spectra measured at various temperatures between 84 and 270 K during a cooling and heating cycle. This compound exhibits an unusual temperature-dependent spin transition behaviour with T(C)(down arrow) = 223 and T(C)(up arrow) = 213 K occurring in the reverse order in comparison to those observed in SQUID observation and many other spin transition compounds. The comp…

5-BIS(PYRIDIN-2-YL)-1Phase transitionMossbauer spectroscopySpin transition2Inorganic compoundsABPT=4-AMINO-3chemistry.chemical_compoundMOLECULESNuclear magnetic resonanceSpin crossoverMössbauer spectroscopyMagnetic propertiesPERCHLORATEGeneral Materials Science4-TRIAZOLEIsoxazoleSpin (physics)Mössbauer effectORDER-DISORDER PHENOMENABIS(3-AMINOPROPYL)(2-PYRIDYLMETHYL)AMINECOMPOUNDGeneral ChemistryAtmospheric temperature rangeCondensed Matter PhysicsSTATECrystallographychemistryPhase transitionsPHASE-TRANSITIONCondensed Matter::Strongly Correlated ElectronsCOMPLEXESLIGANDSABPT=4-AMINO-35-BIS(PYRIDIN-2-YL)-124-TRIAZOLEJournal of Physics and Chemistry of Solids
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What do we mean by diversity? : the path towards quantification

2018

The concept of biological diversity has evolved from a simple count of species to more sophisticated measures that are sensitive to relative abundances and even to evolutionary divergence times between species. In the course of this evolution, diversity measures have often been borrowed from other disciplines. Biological reasoning about diversity often implicitly assumed that measures of diversity had certain mathematical properties, but most of biologys traditional diversity measures did not actually possess these properties, a situation which often led to mathematically and biologically invalid inferences. Biologists now usually transform the traditional measures to the «effective number …

51MultidisciplinaryHistory and Philosophy of SciencePath (graph theory)Mathematical propertiesBiodiversityEvolutionary divergenceRule of inferenceData scienceDiversity (business)Global biodiversitySimple (philosophy)
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Adaptive Number Knowledge in Secondary School Students: Profiles and Antecedents

2019

Cited By :1 Export Date: 10 February 2021 Correspondence Address: McMullen, J.; Department of Teacher EducationFinland; email: jake.mcmullen@utu.fi The present study aims to examine inter-individual differences in adaptive number knowledge in secondary school students. Adaptive number knowledge is defined as a well-connected network of knowledge of numerical characteristics and arithmetic relations. Substantial and relevant qualitative differences in the strategies and expression of adaptive number knowledge have been found in primary school students still in the process of learning arithmetic. We present a study involving 879 seventh-grade students that examines the structure of individual…

515 PsychologyProcess (engineering)yläkoululaisetlcsh:BF1-990Experimental and Cognitive Psychology050105 experimental psychologyFluencylatent profile analysisMathematics educationComputingMilieux_COMPUTERSANDEDUCATIONmatemaattiset taidot0501 psychology and cognitive sciencesAlgebra over a fieldAdaptive expertiseindividual differencesStructure (mathematical logic)Numerical Analysis4. EducationApplied Mathematicslcsh:Mathematics05 social sciences050301 educationMixture modeladaptive number knowledgelcsh:QA1-939Expression (mathematics)lcsh:PsychologyFormal instructionadaptive expertisenumeerinen lukutaitoarithmetic developmentPsychology0503 educationJournal of Numerical Cognition
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Tunable Superstructures of Dendronized Graphene Nanoribbons in Liquid Phase

2019

In this Communication, we report the first synthesis of structurally well-defined graphene nanoribbons (GNRs) functionalized with dendritic polymers. The resultant GNRs possess grafting ratios of 0.59-0.68 for the dendrons of different generations. Remarkably, the precise 3D branched conformation of the grafted dendrons affords the GNRs unprecedented 1D supramolecular self-assembly behavior in tetrahydrofuran (THF), yielding nanowires, helices and nanofibers depending on the dimension of the dendrons. The GNR superstructures in THF exhibit near-infrared absorption with maxima between 650 and 700 nm, yielding an optical bandgap of 1.2-1.3 eV. Ultrafast photoconductivity analyses unveil that …

530 PhysicsBand gapChemistry MultidisciplinaryExcitonSupramolecular chemistryNanowireNanotechnology010402 general chemistry01 natural sciencesBiochemistryCatalysisColloid and Surface ChemistryPHOTOCONDUCTIVITYDENDRIMERSSuperstructureScience & TechnologyChemistryBOTTOM-UP SYNTHESISPhotoconductivityGeneral Chemistry530 Physik0104 chemical sciencesELECTRONIC-PROPERTIESChemistryEDGENanofiberPhysical SciencesGraphene nanoribbonsJournal of the American Chemical Society
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Rational Design of Thermoresponsive Microgel Templates with Polydopamine Surface Coating for Microtissue Applications.

2021

Functional microgels provide a versatile basis for synthetic in vitro platforms as alternatives to animal experiments. The tuning of the physical, chemical, and biological properties of synthetic microgels can be achieved by blending suitable polymers and formulating them such to reflect the heterogenous and complex nature of biological tissues. Based on this premise, this paper introduces the development of volume-switchable core-shell microgels as 3D templates to enable cell growth for microtissue applications, using a systematic approach to tune the microgel properties based on a deep conceptual and practical understanding. Microscopic microgel design, such as the tailoring of the microg…

540 Chemistry and allied sciencesMaterials scienceIndolesPolymers and PlasticsPolymersMicrofluidicsBioengineeringNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesBiomaterialsBiological propertyddc:570Materials ChemistryAnimalsNanoscopic scalechemistry.chemical_classificationMicrogelsRational designPolymer021001 nanoscience & nanotechnology0104 chemical sciencesSurface coatingTemplatechemistry540 ChemieSurface modification0210 nano-technologyGelsBiotechnologyMacromolecular bioscience
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Variations of selective separability II: Discrete sets and the influence of convergence and maximality

2012

A space $X$ is called selectively separable(R-separable) if for every sequence of dense subspaces $(D_n : n\in\omega)$ one can pick finite (respectively, one-point) subsets $F_n\subset D_n$ such that $\bigcup_{n\in\omega}F_n$ is dense in $X$. These properties are much stronger than separability, but are equivalent to it in the presence of certain convergence properties. For example, we show that every Hausdorff separable radial space is R-separable and note that neither separable sequential nor separable Whyburn spaces have to be selectively separable. A space is called \emph{d-separable} if it has a dense $\sigma$-discrete subspace. We call a space $X$ D-separable if for every sequence of …

54D65 54A25 54D55 54A20H-separable spaceSubmaximalD+-separable spaceSequential spaceFUNCTION-SPACESSeparable spaceSpace (mathematics)INVARIANTSSeparable spaceCombinatoricsGN-separable spaceStrong fan tightnessM-separable spaceMaximal spaceConvergence (routing)Radial spaceFOS: MathematicsFréchet spaceCountable setStratifiable spaceWhyburn propertyTOPOLOGIESDH+-separable spaceTightnessMathematics - General TopologyMathematicsDH-separable spaceD-separable spaceSequenceExtra-resolvable spaceGeneral Topology (math.GN)Hausdorff spaceResolvableR-separable spaceLinear subspaceResolvable spaceSequentialDiscretely generated spaceSubmaximal spaceGeometry and TopologyTOPOLOGIES; FUNCTION-SPACES; INVARIANTSSS+ spaceFan tightnessCrowded spaceSubspace topologyTopology and its Applications
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Polyester microplastic fibers affect soil physical properties and erosion as a function of soil type

2021

Microplastics are recognized as a factor of global change contaminating many environmental compartments. Agricultural soils are very likely to receive microplastic contamination and are of particular concern due to their role in food production. Microplastic fibers have already been shown to be able to affect soil properties, but their effect on different soil types is poorly understood. Moreover, limited information is available on how the presence of this pollutant can affect soil water erosion processes, which are extremely important issues in many environments. In the light of this, we performed two experiments (carried out on a microscale) to investigate how the presence of polyester m…

570soil erosion600 Technik Medizin angewandte Wissenschaften::630 Landwirtschaft::630 Landwirtschaft und verwandte Bereiche550Microplastic in soil500 Naturwissenschaften und Mathematik::570 Biowissenschaften; Biologie::570 Biowissenschaften; Biologieerosioncomplex mixtures630Settore AGR/02 - Agronomia E Coltivazioni ErbaceePolyester microplasticsoil typesoil propertiessoil physical properties500 Naturwissenschaften und Mathematik::550 Geowissenschaften Geologie::550 GeowissenschaftenSettore AGR/08 - Idraulica Agraria E Sistemazioni Idraulico-Forestali
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Isomeric state of $^{80}$Y and its role in the astrophysical rp-process

2001

5 pages, 7 figures.-- PACS nrs: 21.10.Tg; 23.20.Nx; 27.50.+e.

59 ≤ A ≤ 89 [[PACS] Properties of specific nuclei listed by mass ranges]PhysicsNuclear and High Energy Physics[PACS] Properties of specific nuclei listed by mass ranges: 59 ≤ A ≤ 89Proton[PHYS.NEXP] Physics [physics]/Nuclear Experiment [nucl-ex]010308 nuclear & particles physicsHadronElectron[PACS] Internal conversion and extranuclear effects (including Auger electrons and internal bremsstrahlung)rp-processNuclear isomer[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]01 natural sciences7. Clean energyNuclear physicsExcited state0103 physical sciences[PACS] Lifetimes widthsAtomic physics010306 general physicsInternal conversion coefficientExcitation
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Thermomineral waters of Greece: geochemical characterization

2020

75 °C). In terms of pH most results vary from 5.5 to 823 °C) ii) warm (23 40 °C) iii) thermal (40 75 °C) and iv) hyperthermal (&gtfew springs show either very low pH (&lt10) proposing serpentinization processes. Regarding TDS concentrations collected waters can be subdivided into low salinity (up to 1.5 g/L) brackish (up to 20 g/L) and saline (up to 43 g/L). The medium high salinities can be justified by mixing with sea water and/or strong waterrock interaction processes. Isotope composition of O and H ranges from 12.7 to +2.7 ‰ SMOW and from 91 to +12 ‰ SMOW respectively and is generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Only few water samples show a positive shift for δ18O possibly related to high temperature waterrock interaction processes. Carbon dioxide (18 997000 μmol/mol) or N2 (1100 989000 μmol/mol) or CH4 (&ltMany geothermal areas of Greece are located in regions affected by Miocene or Quaternary volcanism and in continental basins characterised by elevated heat flow. Moreover the majority of them is found along the coast as well as in islands of the Aegean Sea and thus thermal water is often brackish to saline due to marine intrusion into costal aquifer. In the present study almost 300 thermal and cold mineral water samples were collected along the Hellenic territory with their physicochemical parameters (temperature pH electrical conductivity and Eh) and the amount of bicarbonates (titration with 0.1N HCl) being determined in situ. Additionally gases found either in free or dissolved phase were sampled. Both water and gas samples were analysed at the INGVPa laboratories for major ions (Ion Chromatography) silica (Inductively Coupled Plasma Optical Emission Spectrometry) chemical composition of free and dissolved gases (Gas Chromatography) water isotopes (O and H) and carbon and helium isotopes of free and dissolved gases (Mass Spectrometry). The temperature of the investigated waters ranges from 6.5 to 98°C pH from 1.96 to 11.98 whilst Total Dissolved Solids (TDS) from 0.06 to 43 g/L. Based on the temperature parameter waters can be divided into four groups: i) cold (&lt0.5 913000 μmol/mol) are the prevailing gas species found in the studied sites. The δ13CCO2 values ranged from 20.1 to +8.5 ‰ whilst the isotope ratio of He from 0.21 to 6.71 R/RA.4) suggesting interaction with H2Srich gases or very high pH values (&gtSettore GEO/08 - Geochimica E Vulcanologia
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Azido and thiocyanato bridged dinuclear Ni(II) complexes involving 8-aminoquinoline based Schiff base as blocking ligands: Crystal structures, ferrom…

2020

Abstract The use of two 8-aminoquinoline-based tridentate N3-donor rigid Schiff base ligands (L1 and L2) with Ni(II) in the presence of the pseudohalides, NaN3 and NaSCN results in the crystallization of the two novel Ni(II) dimers: [Ni2(L1)2(µ1,1′-N3)2(N3)2] (1) and [Ni2(L2)2(µ1,3-NCS)2(NCS)2] (2). Both complexes are centrosymmetric Ni(II) dimers where the Schiff base ligands coordinate the octahedral Ni(II) centres in a mer configuration with one terminal and two bridging pseudohalide ligands in the remaining positions. Complex 1 shows Ni(II) ions connected by a double µ1,1′-N3− bridge whereas in complex 2 the Ni(II) ions are connected by a double µ1,3-NCS− bridge. The magnetic properties…

8-AminoquinolineSchiff baseFerromagnetic material properties010405 organic chemistryCrystal structureAzido/ThiocyanatoNi(II)Crystal structure010402 general chemistry01 natural sciences0104 chemical scienceslaw.inventionIonInorganic ChemistrySchiff baseCrystallographychemistry.chemical_compoundFerromagnetismOctahedronchemistrylawFerromagnetismMaterials ChemistryPhysical and Theoretical ChemistryCrystallizationPolyhedron
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