Search results for "PERYLENE"
showing 10 items of 70 documents
Stability improvement of PMMA and Lumogen® coatings for hybrid white LEDs
2014
Hybrid white LEDs employing perylene-based dyes for the frequency down-conversion of blue light, generated by a standard inorganic source, suffer from colour rendering variations due to the degradation of the organic molecule under prolonged irradiation. To avoid such inconvenient, proper encapsulation of the dyes in resins or other polymer matrices can prevent their accelerated ageing; nevertheless, embedding polymers can also exhibit significant bleaching caused by chemico-physical agents. Among all, polymethyl methacrilate (PMMA) is one of the most used materials for the fabrication of hybrid LEDs' colour conversion coatings, therefore its stability needs to be investigated.
Acceptor Concentration Dependence of Förster Resonance Energy Transfer Dynamics in Dye–Quantum Dot Complexes
2014
The dynamics of the photoinduced Forster resonance energy transfer (FRET) in a perylene diimide–quantum dot organic–inorganic hybrid system has been investigated by femtosecond time-resolved absorption spectroscopy. The bidentate binding of the dye acceptor molecules to the surface of CdSe/CdS/ZnS multishell quantum dots provides a well-defined dye-QD geometry for which the efficiency of the energy transfer reaction can be easily tuned by the acceptor concentration. In the experiments, the spectral characteristics of the chosen FRET pair facilitate a selective photoexcitation of the quantum dot donor. Moreover, the acceptor related transient absorption change that occurs solely after energy…
A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene
2020
A bis‐acridinium cyclophane incorporating switchable acridinium moieties linked by a 3,5‐dipyridylanisole spacer was studied as a multi‐responsive host for polycyclic aromatic hydrocarbon guests. Complexation of perylene was proven to be the most effective and was characterized in particular by a charge transfer band as signal output. Effective catch and release of the guest was triggered by both chemical (proton/hydroxide) and redox stimuli. Moreover, the dicationic host was also easily switched between organic and perfluorocarbon phases for application related to the enrichment of perylene from a mixture of polycyclic aromatic hydrocarbons. peerReviewed
Nickel(II) 3,4;9,10-perylenediimide bis-phosphonate pentahydrate: A metal-organic ferromagnetic dye
2012
The new metal organic compound nickel(II) 3,4;9,10-perylenediimide bis-phosphonate pentahydrate, i.e. Ni-2[(PDI-BP)-(H2O)(2)]center dot 3H(2)O (1), has been synthesized and its structural and magnetic properties have been studied. Reaction of 3,4;9,10-perylenediimide bisphosphonate (PDI-BP, hereafter) ligand and nickel chloride in water resulted in the precipitation of a red and poorly crystalline solid (1). As the solid shows a poor crystalline organization of aggregates, the energy dispersive X-ray diffraction analysis (EDXD) technique has been used to obtain short-range order structural information of the single nanoaggregates by radial distribution function analysis. The overall structu…
CCDC 1882074: Experimental Crystal Structure Determination
2019
Related Article: Sebastian B. Beil, Peter Franzmann, Timo Müller, Maximilian M. Hielscher, Tobias Prenzel, Dennis Pollok, Nicole Beiser, Dieter Schollmeyer, Siegfried R. Waldvogel|2018|Electrochimica Acta|302|310|doi:10.1016/j.electacta.2019.02.041
CCDC 161773: Experimental Crystal Structure Determination
2002
Related Article: M.Clemente-Leon, E.Coronado, C.Gimenez-Saiz, C.J.Gomez-Garcia, E.Martinez-Ferrero, M.Almeida, E.B.Lopes|2001|J.Mater.Chem.|11|2176|doi:10.1039/b103032a
CCDC 161774: Experimental Crystal Structure Determination
2002
Related Article: M.Clemente-Leon, E.Coronado, C.Gimenez-Saiz, C.J.Gomez-Garcia, E.Martinez-Ferrero, M.Almeida, E.B.Lopes|2001|J.Mater.Chem.|11|2176|doi:10.1039/b103032a
CCDC 232004: Experimental Crystal Structure Determination
2004
Related Article: E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, E.Martinez-Ferrero, M.Almeida, E.B.Lopes, S.C.Capelli, R.M.Llusar|2004|J.Mater.Chem.|14|1867|doi:10.1039/b402630f
CCDC 232006: Experimental Crystal Structure Determination
2004
Related Article: E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, E.Martinez-Ferrero, M.Almeida, E.B.Lopes, S.C.Capelli, R.M.Llusar|2004|J.Mater.Chem.|14|1867|doi:10.1039/b402630f
Superexchange-mediated electronic energy transfer in a model dyad
2010
On the basis of time-dependent density functional theory (TD-DFT) calculations coupled to the polarizable continuum model (PCM) and single molecule spectroscopic studies, we provide a detailed investigation of excitation energy transfer within a model bi-chromophoric system where a perylene monoimide (PMI) donor is bridged to a terrylene diimide (TDI) acceptor through a ladder-type pentaphenylene (pPh) spacer. We find that the electronic excitation on the PMI donor significantly extends over the bridge giving rise to a partial charge transfer character and inducing a approximately 3-fold increase in the electronic interaction between the chromophores, which explains the failure of the Först…