Search results for "PEST"

El centro de producción de tapices de Tortosa (ca. 1425-1493/1513)

2007

[spa] Este artículo da noticia de la actividad del centro de producción de tapices de Tortosa entre 1425 y 1513; se documentan los maestros Pere Alfonso, Berenguer Baldrich, Joan Falsison, Jaume Sastre, Pere Marquès, Loor Batur, mestre Rubert y Joan Marroquí. Además, se proponen dos hipótesis principales: que en Tortosa se intentó poner en marcha una importante manufactura de tapices ("draps de Ras") hacia 1450, y que el citado Joan Falsison es el autor del tapiz de la Santa Cena de la catedral de Tortosa.

Latest Cretaceous storm-generated sea grass accumulations in the Maastrichtian type area, the Netherlands – preliminary observations

2019

Abstract Ever since the first description of fossil material during the mid-nineteenth century, sea grass has been shown to be quite commonly preserved in ‘pockets’ or ‘clumps’ at certain levels within the Gulpen, Maastricht and Kunrade formations in southern Limburg (the Netherlands) and contiguous areas in northeast Belgium. In those places where silicification occurred during early diagenesis, even completely silicified and three-dimensionally preserved stems and roots can be found, mostly of Thalassocharis bosquetii, in association with fully marine molluscs such as dentaliid scaphopods and a range of larger foraminifera, bivalves, gastropods and ammonites. Such occurrences are best kno…

Synthesis of new fluorinated Tebufenpyrad analogs with acaricidal activity through regioselective pyrazole formation.

2008

In previous studies, our group has shown that the use of fluorinated alcohols such as trifluoroethanol (TFE) and hexafluoroisopropanol (HFIP) as solvents dramatically increases the regioselectivity in the pyrazole formation from 1,3-diketone with methylhydrazine. We have now applied this synthetic method to the preparation of new fluorinated pyrazoles, which have then been used as synthetic intermediates in the preparation of fluorinated analogs of Tebufenpyrad, a commercial acaricide. These compounds display a strong acaricidal activity that is either comparable to or better than that of the commercial compound.

Multivariate Assessment of Procedures for Molecularly Imprinted Polymer Synthesis for Pesticides Determination in Environmental and Agricultural Samp…

2021

In the case of quantitative and qualitative analysis of pesticides in environmental and food samples, it is required to perform a sample pre-treatment process. It allows to minimalize the impact of interferences on the final results, as well as increase the recovery rate. Nowadays, apart from routinely employed sample preparation techniques such as solid-phase extraction (SPE) or solid-phase microextraction (SPME), the application of molecularly imprinted polymers (MIPs) is gaining greater popularity. It is mainly related to their physicochemical properties, sorption capacity and selectivity, thermo-mechanical resistance, as well as a wide range of polymerization techniques allowing to obta…

Relacion puntual de las horrososas tempestades que han sucedido en esta ciudad de Barcelona, en la de Pamplona, en la de Daroca, en la de Alcalà de H…

Precedeix al tít.: ✠ Vinyeta, filets Text a 1 col. - Reclams Sign.: [ ]2

Sulfuric acid cleanup and KOH-ethanol treatment for confirmation of organochlorine pesticides and polychlorinated biphenyls: application to wastewate…

1987

Abstract The efficacy of sulfuric acid cleanup and KOH-ethanol hydrolysis confirmation was studied for 22 organochlorine pesticides and 2 polychlorinated biphenyls (PCBs). Mean recoveries for different treatment times are given. The method was applied to analysis of several wastewater samples by gas chromatography with electron capture detection. Organochlorine compounds were extracted by using separatory funnels and 15% diethyl ether in hexane as extractant. All the compounds studied could be analyzed except trifluralin, dichloran, dieldrin, and endrin, which were destroyed after treatment with concentrated H2S04. The pesticides found most commonly in the samples analyzed were fenson, tetr…

Optimization of a matrix solid-phase dispersion method for the analysis of pesticide residues in vegetables

1996

A multiresidue method based on matrix solid-phase dispersion (MSPD) is studied to determine chlorfenvinfos, chlorpyrifos, fenarimol, iprodione, procimydone, propiconazole, tetradifon, triadimefon and vinclozolin in artichokes, green beans, lettuces and tomatoes. Alumina, silica and Florisil were assessed as extracting phases, and the extracts from Florisil were the cleanest. To facilitate manual extraction, sand was added to the sample together with the dispersing phase. Three eluting systems were then studied, and dichloromethane proved to be the best. Further purification can be performed using solid-phase cleanup after diluting extracts with aqueous solutions. Octyl- and octadecyl-silica…

Profiling of compounds and degradation products from the postharvest treatment of pears and apples by ultra-high pressure liquid chromatography quadr…

2010

This study deals with a simple strategy to pinpoint potential unknown compounds in full scan mass spectrometry (MS) experiments. Forty samples of apples and pears intended for human consumption were analyzed by ultra-high performance liquid chromatography quadrupole-time-of-flight (UPLC–QqTOF-MS), after extraction of the possible contaminants by rinsing the peel of the fruit with ethyl acetate. The peaks were visually recognized in the total ion chromatogram (TIC). Two major types of postharvest treatments were detected in this set of samples: imazalil (IMZ)/ethoxyquin (EQ) and thiabendazole (TBZ)/diphenylamine (DPA). The present work also describes the metabolites formed by degradation of …

Effects of propanil on the European eel Anguilla anguilla and post-exposure recovery using selected biomarkers as effect criteria

2008

Abstract The aim of this study was to assess the physiological response of Anguilla anguilla to propanil and the degree of recovery after being moved to clean water. Preliminary acute toxicity test was carried out in the laboratory and the median lethal concentration (LC50) at 96 h was calculated as 31.33 mg/L (29.60–33.59 mg/L). NOEC and LOEC values (at 96 h) were also calculated as 20 and 25 mg/L, respectively. The fish were exposed to 0.63 and 3.16 mg/L of propanil for 72 h and allowed to recover for 144 h. Total proteins (TPs), γ -glutamil transpeptidase ( γ -GT), alanin aminotransferase (AlAT), alkaline phosphatase (AP), lactate dehydrogenase (LDH) and water content (WC) were assayed i…

Use of semipermeable membrane devices for monitoring pesticides in indoor air.

2009

Abstract In this work, 40 pesticides from different categories were analyzed in the air of 20 indoor places that have an intensive use of pesticides. Passive sampling was carried out by using semipermeable membrane devices (SPMDs) deployed for 7 days. SPMDs were analyzed using microwave-assisted extraction and GC/MS. PCB-195 was used as an internal standard. Recoveries ranged between 81 and 108 for many compounds, with RSD values <11. Typical LOD values for 7 days of sampling were from 0.1 to 3.1 ng/m. Propamocarb, propoxur, carbosulfan, pirimicarb, metribuzin, metalaxyl, pendimethalin, oxadiazon, phenothrin, and permethrin were detected in 11 sampling sites, with air concentrations …