Search results for "PESTICIDE"
showing 10 items of 588 documents
Photostability assessment of natural pyrethrins using halloysite nanotube carrier system
2022
Natural pyrethrins are one of the most used pesticides and insect repellents employed for domestic or agronomic use. However, they are highly hydrophobic and suffer from insolubility in water media and ready decomposition by photochemical, and oxidative actions. These aspects hamper their long-term storage and applicability. Herein, we report the synthesis and characterization of a nanomaterial based on the loading of pyrethrum extract (PE) into natural, low-cost, and eco-compatible halloysite nanotubes (Hal). The Hal/PE nanomaterial was thoroughly characterized, and the morphology was imaged by TEM and SEM investigations. Release experiments showed a slow release of pyrethrins from the car…
Assessment of two extraction methods to determine pesticides in soils, sediments and sludges. Application to the Túria River Basin.
2014
Pressurized liquid extraction (PLE) and Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) extraction methods were optimized for the simultaneous determination of 50 pesticides in sediment, soils and sewage sludge. For QuEChERS development, several buffers and dispersive solid-phase extraction clean-up (dSPE) sorbents were tested. In the PLE method, several parameters affecting the extraction efficiency, such as organic solvent, amount of sample, cell size, temperature, pressure, static time, number of cycles and % of flush, as well as sorbent used for the on-line clean up, were also evaluated. PLE and QuEChERS were assessed and compared in obtained recoveries (33-89% versus 25-120%)…
Contaminants of emerging concern in freshwater fish from four Spanish Rivers.
2019
This study investigated the occurrence of 135 contaminants of emerging concern (CECs) – pharmaceuticals, pesticides, a set of endocrine disrupting compounds (EDCs) (parabens, bisphenols, hormones, triazoles, organophosphorus flame retardants and triclosan), UV-filters, perfluoroalkyl substances (PFASs) and halogenated flame retardants (HFRs) – in 59 fish samples, collected in 2010 in 4 Spanish Rivers (Guadalquivir, Júcar, Ebro and Llobregat). Of the 135 CECs, 76 including 8 pharmaceuticals, 25 pesticides, 10 EDCs, 5 UV-filters, 15 PFASs and 13 HFRs were detected. Pharmaceuticals were the less frequently found and at lower concentrations. Pesticides, EDCs, UV-filters, PFASs and HFRs were det…
Pesticide monitoring in the basin of Llobregat River (Catalonia, Spain) and comparison with historical data.
2014
Through an extensive sampling in the Llobregat River basin, the presence of 50 currently used pesticides in water, sediment, and biota was assessed. Pesticides were detected primarily in water (up to 56% of the analytes), whereas their presence in sediments was more intermittent, and in biota was scarce. Those at high concentrations in water were the benzimidazoles (carbendazim in 22% of the samples up to 697ngL-1), the organophosphorus (malathion in 54% of the samples up to 320ngL-1), and the ureas (diuron in 54% of the samples up to 159ngL-1). However, this pattern differed in sediments and biota, which were contaminated primarily with organophosphorus (higher Kow) (chlorpyrifos 93% of se…
Screening of currently used pesticides in water, sediments and biota of the Guadalquivir River Basin (Spain)
2013
The occurrence of 50 currently used pesticides and their transformation products in surface and waste waters, sediment and fish in the Guadalquivir River Basin was determined in 2010 and 2011. After selective sample extraction, pesticides were identified and quantified by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS). The contamination profile in water and sediments is marked by the presence of organophosphorus and triazines. Transformation products were even at higher concentrations than parent pesticides. A wider range of pesticides was present in water than in sediments but none of them were detected in fish. The mean concentrations ranged from 0.2 to 13.0 ng/L in …
Pesticide exposure and women's health
2003
Background Research on pesticide-related health effects has been mostly focused in industrialized countries and in men. This paper discusses critical issues related to women's pesticide exposure and its effects on women's health. Methods The literature on pesticides was reviewed with emphasis on data related to women. Attention was focused on research suggesting different conditions of exposure or different response to pesticides by sex. Studies on cancer and reproductive effects were used as illustrative examples. Results Women are increasingly exposed to pesticides in developing countries, where women's poisoning and other pesticide-related injuries seem to be greatly underestimated. Many…
Acute toxicity and oxygen consumption in the gills of Procambarus clarkii in relation to chlorpyrifos exposure.
1992
Fenitrothion uptake and bioconcentration in the European eel(Anguilla anguilla)
1994
Eels (Anguilla anguilla) were exposed to 0.02 mg/L of the organophosphorus pesticide fenitrothion during 144 hours in semi‐static conditions. BCF, intBCF, uptake rate constants (Ku) and elimination rate constants (Kd) of fenitrothion were determined in brain, gills, blood and muscle tissues of the eel. A simple one‐compartment model fitted the uptake and elimination characteristics. Plateau were reached at different times in the different tissues: at 24 hr in gills, 72 hr in brain and blood and 120 hr in muscle tissue. BCF were ranged from 117 for blood to 658 for muscle. Muscle tissue showed the highest BCF, intBCF, Ku and the lowest Kd .
An approach to the diazinon toxicity in the European eel: bioaccumulation studies
1993
Abstract The acute toxicity effects of diazinon on European eel ( Anguilla anguilla ) were examined using short-term exposures in static conditions. In these conditions the 96-h median lethal concentration (LC 50 ) was 0.086 mg/1. In addition, the eels were exposed to two sublethal diazinon concentrations, 0.042 and 0.056 mg/1 (1/2 and 2/3 LC 50 96-h, respectively) for different exposure times, till a maximum of 96 h, and bioaccumulation and clearance of this insecticide in liver, muscle, gill and blood tissues were studied. BCF values of diazinon after 96 h exposure to 0.042 mg/l were 1850 in liver, 875 in gill and 775 in eel muscle. BCF values of diazinon over a 48-h exposure period to 0.…