Search results for "PFC-yhdisteet"

showing 2 items of 2 documents

Comparing the Ecotoxicological Effects of Perfluorooctanoic Acid (PFOA) and Perfluorohexanoic Acid (PFHxA) on Freshwater Microbial Community

2022

The ubiquitous presence of perfluorinated carboxylic acids (PFCAs) around the globe has attracted increasing attention, due to their persistency, bioaccumulation, and toxicity. Nevertheless, the ecotoxicological effects of the compounds on aquatic microorganisms has remained understudied. Hence, the present study focused on determining, and comparing, the effects of regulated long-chain PFCA, perfluorooctanoic acid (PFOA), and nonregulated short-chain PFCA, perfluorohexanoic acid (PFHxA), on the diversity, structure, microbial growth, and activity of a freshwater microbial community. In the experiment, lake water was incubated for a period of four weeks at three different concentrations of …

PFCAsekotoksikologiarRNA gene sequencingmikrobistokarboksyylihapotmicorbial communityNGSPFC-yhdisteetvesiekosysteemittoxicitymikrobit
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A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene

2020

A bis‐acridinium cyclophane incorporating switchable acridinium moieties linked by a 3,5‐dipyridylanisole spacer was studied as a multi‐responsive host for polycyclic aromatic hydrocarbon guests. Complexation of perylene was proven to be the most effective and was characterized in particular by a charge transfer band as signal output. Effective catch and release of the guest was triggered by both chemical (proton/hydroxide) and redox stimuli. Moreover, the dicationic host was also easily switched between organic and perfluorocarbon phases for application related to the enrichment of perylene from a mixture of polycyclic aromatic hydrocarbons. peerReviewed

Polycyclic aromatic hydrocarbon010402 general chemistryRedox01 natural sciencesCatalysischemistry.chemical_compoundTransfer agentPhase (matter)PFC-yhdisteetsupramolekulaarinen kemia[CHIM]Chemical Scienceshost-guest chemistryHost–guest chemistryComputingMilieux_MISCELLANEOUSmulti-responsive receptorchemistry.chemical_classificationacridinium[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryGeneral ChemistryGeneral MedicineperfluorocarbonsCombinatorial chemistry0104 chemical sciencesisäntä-vieras kemiachemistryHydroxidephase transferPeryleneCyclophane
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