Search results for "PLASMA"
showing 10 items of 4043 documents
Assessment of Five Monazite Reference Materials for U-Th/Pb Dating Using Laser-Ablation ICP-MS
2019
Monazite is a common accessory phosphate mineral that occurs under a wide range of pressure and temperature conditions in sedimentary, metamorphic and igneous rocks. Monazite contains high amounts of Th and U, rendering single monazite grains suitable for in-situ U-Th/Pb dating using laser ablation inductively-coupled mass spectrometry (LA-ICP-MS). Two key aspects of monazite dating that are critical for accurate age data with maximum precision are (i) optimized instrumental conditions to minimize analytical scatter and (ii) a well characterized reference material to ensure the accuracy of the obtained aged. Here, we analyzed five monazite reference materials (USGS 44069, 94-222, MAdel, Moa…
Comparative LA-ICP-IDMS determinations of trace elements in powdered samples using laser ablation systems with low and high ablation rates
2004
The results of laser ablation inductively coupled plasma isotope dilution mass spectrometry (LA-ICP-IDMS) with a special laser ablation system with high ablation rates (LINA-Spark-Atomiser), which was constructed for bulk analyses of solid samples, are compared with those obtained by one of the commonly used LA systems (UP213). Using different reference materials for validation it was demonstrated that the accuracy of LA-ICP-IDMS determinations of elements like Fe, Cu, Pb, and Zn by both systems is comparable in the concentration range of 10−2–10−6 g g−1, but the LINA-Spark-Atomiser also provides accurate results in the sub-μg g−1 range. IDMS enables accurate calibration of LA-ICP-MS determ…
Characterization of laser ablation of copper in the irradiance regime of laser-induced breakdown spectroscopy analysis
2014
Abstract The LIBS signal depends both on the ablated mass and on the plasma excitation temperature. These fundamental parameters depend in a complex manner on laser ablation and on laser–plasma coupling. As several works in the literature suggest that laser ablation processes play a predominant role compared to plasma heating phenomena in the LIBS signal variations, this paper focuses on the study of laser ablation. The objective was to determine an interaction regime enabling to maximally control the laser ablation. Nanosecond laser ablation of copper at 266 nm was characterized by scanning electron microscopy and optical profilometry analysis, in air at 1 bar and in the vacuum. The laser …
Simultaneous laser generation and laser ultrasonic detection of the mechanical breakdown of a coating–substrate interface
2001
Abstract The present study deals with information that could be obtained by real-time contactless monitoring of the normal displacement, due to the propagation of the longitudinal waves generated by nanosecond pulsed laser irradiation, through a transparent and porous ceramic coating deposited on a metallic substrate. These displacements were recorded in real-time at the rear surface of the specimens using a laser heterodyne interferometer and were correlated with the different steps of laser/material interaction (thermoelastic interactions, fracture of the coating–substrate interface and coating expulsion). An analytical model was developed to establish a relation between the longitudinal …
Effects of Onshore and Offshore Environmental Parameters on the Leading Edge Erosion of Wind Turbine Blades: A Comparative Study
2021
Abstract The presence of rain-induced leading edge erosion of wind turbine blades (WTBs) necessitates the development of erosion models. One of the essential parameters for erosion modeling is the relative impact velocity between rain droplets and the rotating blade. Based on this parameter, the erosion damage rate of a WTB is calculated to estimate the expected leading edge lifetime. The environmental conditions that govern this parameter have site-specific variations, and thus, rain and wind loading on a turbine differ for onshore and offshore locations. In addition, there are wave loads present in the offshore environment. The present paper tries to provide guidelines for erosion modelin…
(Table 1) Geochemistry of ODP Site 160-963 sediments
2010
The Mediterranean Sea acts as a miniature ocean with the development of its own conveyor belt. It constitutes an ideal location to study and forecast how the marine environment responds to rapid climatic change. Here we present a palaeoenvironmental study carried out on the sediments of ODP Site 963, recovered in the Sicily Channel, the sill which divides the western from the eastern Mediterranean basin. We focused on the transition between the penultimate glacial (MIS 6) and the last interglacial (MIS 5), between approximately 130 and 115 kyr BP. A novel approach is proposed, taking into account centennial-scale geochemical data on major elements, selected trace elements, and yttrium and R…
(Table 1) Trace element/Ca ratios of Orbulina universa shells from late Neogene Mediterranean samples
2008
A Mediterranean composite sedimentary record was analyzed for Ba/Ca ratios on carbonate shells of Orbulina universa planktonic foraminifer (Ba/Ca)carb providing the opportunity to study and assess the extent of freshwater inputs on the basin and possible impacts on its dynamics during the Tortonian to Recent period. A number of scanning electron microscope analyses and auxiliary trace element measurements (Mn, Sr, and Mg), obtained from the same samples, exclude important diagenetic effects on the studied biogenic carbonates and corroborate the reliability of (Ba/Ca)carb ratios in foraminifera calcite as indicators of seawater source components during the studied interval. A long-term trend…
Modeling Atmospheric Turbulence via Rapid Distortion Theory: Spectral Tensor of Velocity and Buoyancy
2017
Abstract A spectral tensor model is presented for turbulent fluctuations of wind velocity components and temperature, assuming uniform vertical gradients in mean temperature and mean wind speed. The model is built upon rapid distortion theory (RDT) following studies by Mann and by Hanazaki and Hunt, using the eddy lifetime parameterization of Mann to make the model stationary. The buoyant spectral tensor model is driven via five parameters: the viscous dissipation rate ε, length scale of energy-containing eddies L, a turbulence anisotropy parameter , gradient Richardson number (Ri) representing the local atmospheric stability, and the rate of destruction of temperature variance . Model outp…
Spatial correlations of mobility and immobility in a glass-forming Lennard-Jones liquid
1998
Using extensive molecular dynamics simulations of an equilibrium, glass-forming Lennard-Jones mixture, we characterize in detail the local atomic motions. We show that spatial correlations exist among particles undergoing extremely large (``mobile'') or extremely small (``immobile'') displacements over a suitably chosen time interval. The immobile particles form the cores of relatively compact clusters, while the mobile particles move cooperatively and form quasi-one-dimensional, stringlike clusters. The strength and length scale of the correlations between mobile particles are found to grow strongly with decreasing temperature, and the mean cluster size appears to diverge near the mode-cou…
Non-London electrodynamics in a multiband London model : anisotropy-induced nonlocalities and multiple magnetic field penetration lengths
2018
The London model describes strongly type-2 superconductors as massive vector field theories, where the magnetic field decays exponentially at the length scale of the London penetration length. This also holds for isotropic multi-band extensions, where the presence of multiple bands merely renormalises the London penetration length. We show that, by contrast, the magnetic properties of anisotropic multi-band London models are not this simple, and the anisotropy leads to the inter-band phase differences becoming coupled to the magnetic field. This results in the magnetic field in such systems having N+1 penetration lengths, where N is the number of field components or bands. That is, in a giv…