Search results for "PMC"
showing 10 items of 42 documents
A novel approach to prevent graphene oxide re-aggregation during the melt compounding with polymers
2015
Abstract The technology for the preparation of polymer-GO nanocomposites was investigated by studying the structure-properties relationships of two different systems, based on PA6 and EVA, fabricated by using different preparation methods, i.e. melt mixing, wet phase inversion, and the combination of the two. The morphology of nanocomposites resulted dramatically influenced by the technique adopted and showed to be the critical variable affecting the physical properties of the materials. Finally, the mechanical and dynamic-mechanical of the nanocomposites were improved by using the hybrid technique combining the two procedures.
Toward Mechanistic Design of Surrogate Buffers for Dissolution Testing of pH-Dependent Drug Delivery Systems
2020
The in vivo dissolution of enteric-coated (EC) products is often overestimated by compendial in vitro dissolution experiments. It is of great interest to mimic the in vivo conditions as closely as possible in vitro in order to predict the in vivo behavior of EC dosage forms. The reason behind this is the overly high buffering capacity of the common compendial buffers compared to the intestinal bicarbonate buffer. However, a bicarbonate-based buffer is technically difficult to handle due to the need for continuous sparging of the media with CO2 to maintain the desired buffer pH. Therefore, bicarbonate buffers are not commonly used in routine practice and a non-volatile alternative is of inte…
An hsf2-like factor is present in the invertebrates: Characterization and purification in sea urchin embryos and its localization in primary mesenchi…
2015
Effects of aging in salt spray conditions on flax and flax/basalt reinforced composites: Wettability and dynamic mechanical properties
2016
Abstract In the last years, the industrial policies are more attentive to issues concerning sustainability, recycling and environmental care. Therefore, the use of natural fibres in composite materials has spread more and more. This paper deals with flax and basalt fibres within an epoxy matrix by investigating the wettability and the dynamic mechanical properties of the resulting composites, subjected to long-term aging tests in critical environmental conditions. The first laminate was constituted by stacking ten layers of bidirectional flax fabrics. The second one was produced by replacing two external flax layers with two layers of basalt mat, for each side of the laminate. Both laminate…
A comparative study of fatigue behaviour of flax/epoxy and glass/epoxy composites
2012
Experimental investigations on flax and glass fabrics reinforced epoxy specimens, i.e. FFRE and GFRE, submitted to fatigue tests are presented in this paper. Samples having [0/90]3S and [±45]3S stacking sequences, with similar fibre volume fractions have been tested under tension–tension fatigue loading. The specific stress-number of cycles to failure (S–N) curves, show that for the [0/90]3S specimens, FFRE have lower fatigue endurance than GFRE, but the [±45]3S FFRE specimens offer better specific fatigue endurance than similar GFRE, in the studied life range (<2 × 10^6). Overall, the three-stage stiffness degradation is observed in all cases except for [0/90]3S FFRE specimens, which prese…
Effect of hydrothermal ageing on the thermal and delamination fracture behaviour of CFRP composites
2014
Abstract This work investigates the hydrothermal ageing behaviour of a carbon fibre reinforced laminate and its epoxy matrix in bulk conditions. A model DGEBA epoxy is employed, and water uptake and dynamic mechanical thermal (DMTA) analyses have been performed on both the composites and bulk resin. Fracture toughness of the bulk resin has been measured, evidencing a substantially unmodified critical stress intensity factor KIC, although the evidence of plasticisation effects given by DMTA. Interlaminar Mode I fracture toughness of the composite showed a variable trend towards slight decreases or slight increases, according to the prevailing toughening or embrittling mechanisms activated by…
CuO nanoparticle filled vinyl-ester resin nanocomposites: Fabrication, characterization and property analysis
2007
Abstract Both unmodified cupric oxide (CuO) nanoparticles and those functionalized with a bi-functional coupling agent methacryloxypropyl-trimethoxysilane (MPS) were used to fabricate vinyl-ester resin polymeric nanocomposites. The nanoparticle functionalization was observed to have a significant effect on the physical properties of the cupric oxide filled vinyl-ester resin nanocomposite. Thermal degradation study by thermo-gravimetric analysis (TGA) showed the increased thermo-stability in the functionalized-nanoparticle-filled vinyl-ester resin nanocomposites as compared with the unmodified-nanoparticle-filled counterparts. The more uniform particle dispersion and the chemical bond betwee…
Effects of Nylon 6,6 Nanofibrous Mats on Thermal Properties and Delamination Behavior of High Performance CFRP Laminates
2014
none 8 no Nylon 6,6 electrospun nanofibrous membranes interleaved in Carbon Fibre Reinforced Plastic (CFRP) laminates have been proposed as a means to provide a higher threshold value to delamination on structural sites where composites are more prone to develop such failure. A model, highly crosslinked thus inherently brittle, epoxy matrix was selected for its high Young’s modulus and glass transition temperature exceeding 250 °C. The influence of the Nylon 6,6 nanofibres on the curing behaviour of the matrix and on the thermal and dynamic mechanical properties of the cured resin was investigated. These properties were related to the features of the epoxy resin and of the resin impregnated…
X-ray micro-computed tomography investigation of fibre length degradation during the processing steps of short-fibre composites
2014
The mechanical properties of composites in the fibre direction are mainly attributed to the fibre slenderness, or aspect ratio. A trade-off between performance and processability is usually required, and dependent on the intended application. If the fibre length could be retained or not severely degraded during various processing steps towards the injection-moulded component, a stiffer and stronger composite product could be obtained. The processing steps for injection moulded wood-fibre composites here include: Pulping, commingling, extrusion, pelletizing, and injection moulding. To tune the processing parameters systematically for retained fibre length, it would be useful to investigate t…
The effect of silica nanoparticles on the morphology, mechanical properties and thermal degradation kinetics of polycarbonate
2012
Abstract Polycarbonate/silica nanocomposites with different silica quantities were prepared by a melt compounding method. The effect of silica amount, in the range 1–5 wt.%, on the morphology, mechanical properties and thermal degradation kinetics of polycarbonate (PC) was investigated. Clusters of silica nanoparticles were well dispersed in the polycarbonate whose structure remained amorphous. NMR results showed intermolecular interactions involving the carbonyl groups of different polymeric chains which did not affect the intramolecular rotational motions. The presence of the lowest silica content showed a decrease in the storage and loss moduli below the glass transition temperature, pro…