Search results for "POLLUTANTs"
showing 10 items of 1125 documents
Characterization of the Etna volcanic emissions through an active biomonitoring technique (moss-bags): Part 1 – Major and trace element composition
2013
Active biomonitoring using moss-bags was applied to an active volcanic environment for the first time. Bioaccumulation originating from atmospheric deposition was evaluated by exposing mixtures of washed and air-dried mosses (Sphagnum species) at 24 sites on Mt. Etna volcano (Italy). Concentrations of major and a large suite of trace elements were analysed by inductively coupled mass and optical spectrometry (ICP-MS and ICP-OES) after total acid digestion. Of the 49 elements analysed those which closely reflect summit volcanic emissions were S, Tl, Bi, Se, Cd, As, Cu, B, Na, Fe, Al. Enrichment factors and cluster analysis allowed clear distinction between volcanogenic, geogenic and anthropo…
A new foam-based method for the (bio)degradation of hydrocarbons in contaminated vadose zone
2020
International audience; An innovative foam-based method for Fenton reagents (FR) and bacteria delivery was assessed for the in situ remediation of a petroleum hydrocarbon-contaminated unsaturated zone. The surfactant foam was first injected, then reagent solutions were delivered and propagated through the network of foam lamellae with a piston-like effect. Bench-scale experiments demonstrated the feasibility of the various treatments with hydrocarbon (HC) removal efficiencies as high as 96 %. Compared to the direct injection of FR solutions, the foam-based method led to larger radii of influence and more isotropic reagents delivery, whereas it did not show any detrimental effect regarding H…
Hydrogen sulfide and odor removal by field-scale biotrickling filters: Influence of seasonal variations of load and temperature
2012
Two biotrickling filters were set up at two wastewater treatment plants (WWTP) in The Netherlands to investigate their effectiveness for treatment of odorous waste gases from different sources. One biotrickling filter was installed at Nieuwe Waterweg WWTP in Hook of Holland to study the hydrogen sulfide removal from headworks waste air. The other reactor was installed at Harnaschpolder WWTP (treating wastewater of the city of The Hague) to remove mercaptans and other organic compounds (odor) coming from the emissions of the anaerobic tanks of the biological nutrient removal (BNR) activated sludge. The performance of both units showed a stable and highly efficient operation under seasonal va…
Photo-induced fluorescence of magnesium derivatives of tetracycline antibiotics in wastewater samples
2009
Abstract An analytical strategy, for the determination of tetracyclines (TCs), based on a HPLC system coupled with a photo-reactor followed by post-column derivatization was developed. Higher fluorescence emission after coupling the resulting photo-fragments with magnesium ions was observed for the determination of minocycline (MC), epitetracycline (ETC), tetracycline (TC) and doxycycline (DC). The manifold included a HPLC system with a photo-reactor (PTFE tubing helically coiled around a low-pressure mercury lamp), a mixing T-piece and a fluorescence detector. The derivatization reagent was delivered at 0.5 mL min −1 by a pump. After HPLC separation using a gradient system with a mobile ph…
Protecting emergency workers and armed forces from volatile toxic compounds: Applicability of reversible conductive polymer-based sensors in barrier …
2019
International audience; Barrier materials have wide applicability in both professional (military, medical, industrial) and non-professional(leisure and sports) fields. This paper focuses on the preparation of real conductive polymer (CP) sensors, for thestudy of the permeation of volatile toxic compounds through barrier materials. Use of such a CP sensor can helpimprove the quality of barrier materials used in protective clothing. Several types of platforms have beenmanufactured or purchased for use as comb sensors with different electrode dimensions, and a suitable methodof applying the detection layer of conductive polymers (polyaniline and poly-pyrrole) has been developed. Prepared senso…
Enhanced remedial reagents delivery in unsaturated anisotropic soils using surfactant foam
2018
Abstract Homogeneous delivery of solution of oxidant in unsaturated soils is limited by soil anisotropy and gravity. An innovative injection strategy using foam was developed to improve in situ delivery. Primary foam injection before oxidant solution enhanced both the lateral and uniform delivery of reactant in isotropic and anisotropic (permeability, contamination) soils. The oxidant spread isotropically through the foam water network. This sequential injection heavily improved the delivery radius of influence (ROI), while limiting contact between surfactant and solution of oxidant in order to preserve the selective oxidation of petroleum hydrocarbons contaminant (TPH). Prior foam injectio…
Electrochemical treatment of aqueous solutions of organic pollutants by electro-Fenton with natural heterogeneous catalysts under pressure using Ti/I…
2018
The treatment of toxic organic pollutants by electro-Fenton (EF) presents some drawbacks such as the necessity to work at low pH and the low solubility of oxygen in water contacted with air or oxygen at room pressure that results often in slow and relatively low abatements. Here, the coupled adoption of natural heterogeneous catalysts and of relatively high pressure was proposed in order to improve the performances of EF for the treatment of organic pollutants. Caffeic acid (CA) and 3-chlorophenol were used as model resistant organic pollutants. EF process was performed using both conventional homogeneous FeSO4 and natural heterogeneous catalysts (pyrite, chalcopyrite, Fe2O3 and Fe3O4) as i…
Performances of a granular sequencing batch reactor (GSBR).
2007
Aerobic granulation in sequencing batch reactors is widely reported in literature and in particular in SBAR (Sequencing batch airlift reactor) configuration, due to the high localised hydrodynamic shear forces that occur in this type of configuration. The aim of this work was to observe the phenomenon of the aerobic granulation and to confirm the excellent removal efficiencies that can be achieved with this technology. In order to do that, a laboratory-scale plant, inoculated with activated sludge collected from a conventional WWTP, was operated for 64 days: 42 days as a SBAR and 22 days as a SBBC (sequencing batch bubble column). The performances of the pilot plant showed excellent organic…
Features and application of coupled cold plasma and photocatalysis processes for decontamination of water
2020
Dielectric barrier discharge plasma and photocatalysis have been proposed as tools for decontamination of process water, especially in food industry. The present investigation aims to redefine and identify the features of coupling the two technologies in terms of degradation efficiency of a model compound. Results show that, when the process is carried out in plasma activated water in the presence of irradiated TiO2, the efficiency of the integrated process is lower than the sum of the two processes acting separately. It is proposed that afterglow species, e.g. hydrogen peroxide and/or peroxynitrites could be activated by UVA light irradiation producing hydroxyl radicals in the liquid phase…
Deep oxidation of pollutants using gold deposited on a high surface area cobalt oxide prepared by a nanocasting route.
2011
Gold deposited on a cobalt oxide with high surface area (138 m2 g−1), obtained through a nanocasting route using a siliceous KIT-6 mesoporous material as a hard template, has demonstrated high activity for the total oxidation of propane and toluene, and ambient temperature CO oxidation. The addition of gold promotes the activity when compared to a gold-free Co3O4 catalyst prepared using the same nanocasting technique. The enhanced catalytic activity when gold is present has been explained for the deep oxidation of propane and toluene in terms of the improved reducibility of cobalt oxide when gold is added, rather than to the intrinsic activity of metallic gold particles. The improved behavi…