Search results for "POLYCATIONS"

showing 5 items of 5 documents

BIOCOMPATIBLE POLYAMINOACID-BASED POLYCATIONS AS NON-VIRAL VECTORS FOR GENE THERAPY OF CYSTIC FIBROSIS.

2009

Settore CHIM/09 - Farmaceutico Tecnologico ApplicativoPOLYCATIONS NON-VIRAL VECTORS GENE THERAPY CYSTIC FIBROSIS.
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Kinetic studies of the interaction between DNA and polycations based on polyasparthylhydrazide

2008

Abstract In the present paper, a systematic kinetic study on the interaction between interpolyelectrolytes such as positive-charged polymers and DNA was carried out. In particular, a qualitative–quantitative kinetic investigation on the interaction between copolymers of the α,β-poly(aspartylhydrazide) and DNA calf thymus filaments was performed. This study gives a new model starting from a well known “pseudo-phase model”, and permits to give a qualitative explanation about the trends of experimentally observed kinetic constants by varying the concentration of one of the two poly-electrolytes. Moreover, this study permits to verify the dependence of the binding constants KPAHy–CPTA and KDNA …

chemistry.chemical_classificationAqueous solutionKineticsCationic polymerizationThermodynamicsElectrolytePolymerKinetic energychemistry.chemical_compoundColloid and Surface ChemistrychemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoCopolymerOrganic chemistryDNA polycationsDNA
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Reversibly stable thiopolyplexes for intracellular delivery of genes.

2006

Novel polyaspartamide non-viral carriers for gene therapy were synthesized by introducing, on the same polymer backbone, positively charged groups, for electrostatic interactions with DNA, and thiol groups for the formation of disulfide bridges between polymer chains. The introduction of thiols was aimed to have a vector with low redox potential sensitivity: disulfide crosslinking in fact, being stable in extracellular environment, allowed either to have stable complexes in plasma, that can protect DNA from metabolism, or to be reduced inside the cell, where the excess of glutathion in reduced form maintains a low redox potential. The consequent destabilization of the complex after disulfid…

Magnetic Resonance SpectroscopyLightStereochemistryCell SurvivalPolymersPharmaceutical ScienceElectrophoretic Mobility Shift AssayGene deliveryTransfectionchemistry.chemical_compoundGene DeliveryMiceDynamic light scatteringGenes ReporterCell Line TumorAnimalsScattering RadiationElectrophoretic mobility shift assayDisulfidesSulfhydryl CompoundsLuciferaseschemistry.chemical_classificationthiopolycationsEndodeoxyribonucleasesLuminescent AgentsGenetic transferCationic polymerizationProteinsDNAChromatography Ion ExchangeCombinatorial chemistrychemistrypolyaspartammideAgarose gel electrophoresisThiolPeptidesOxidation-ReductionDNAJournal of controlled release : official journal of the Controlled Release Society
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Non viral colloidal vectors based on polyaminoacids for gene therapy

2008

Settore CHIM/09 - Farmaceutico Tecnologico Applicativonon viral vectors polycations gene therapy
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Improvements in Rational Design Strategies of Inulin Derivative Polycation for siRNA Delivery.

2016

The advances of short interfering RNA (siRNA)-mediated therapy provide a powerful option for the treatment of many diseases, including cancer, by silencing the expression of targeted genes involved in the progression of the pathology. On this regard, a new pH-responsive polycation derived from inulin, Inulin-g-imidazole-g-diethylenetriamine (INU-IMI-DETA), was designed and employed to produce INU-IMI-DETA/siRNA "Inulin COmplex Nanoaggregates" (ICONs). The experimental results showed that INU-IMI-DETA exhibited strong cationic characteristics and high solubility in the pH range 3-5 and self-aggregation triggered by pH increase and physiological salt concentration. INU-IMI-DETA showed as well…

polycationssiRNA deliverySmall interfering RNAPolymers and PlasticsInulinBioengineering02 engineering and technology010402 general chemistry01 natural sciencesBiomaterialschemistry.chemical_compoundDrug Delivery SystemsMaterials ChemistryPolyaminesGene silencingHumansGene SilencingRNA Small Interferingpolycations siRNA delivery inulinRational designInulinBafilomycinRNATransfectionHydrogen-Ion Concentration021001 nanoscience & nanotechnologyEndolysosomePolyelectrolytesEndocytosis0104 chemical scienceschemistryBiochemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoDrug DesignMCF-7 Cellspolycations; siRNA delivery; inulin0210 nano-technologyBiomacromolecules
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