Search results for "Palladium"
showing 10 items of 956 documents
Palladium local structure of La1-xSrxCo1-yFey-0.03Pd0.03O3-δperovskites synthesized using a one pot citrate method
2014
Nanostructured La1-xSrxCo1-yFey-0.03Pd0.03O3-δ(LSCF-Pd) perovskites with fixed La-Sr composition (x = 0.4) and two different Fe contents (y = 0.2 and 0.8) were successfully synthesized using a one pot citrate method starting from nitrates of the metal cations. Pd-free La1-xSrxCo1-yFeyO3-δ(LSCF) systems were prepared for comparison. LSCF powders were calcined at 1300 °C and characterized by XRD and Rietveld refinement, EXAFS, XPS, TPR analyses. Promotion of La0.6Sr0.4Co0.8Fe0.2O3-δand of La0.6Sr0.4Co0.2Fe0.8O3-δby incorporation of palladium was evidenced by solving the local environment of Pd using EXAFS spectroscopy. XPS analyses, in agreement with TPR measurements, demonstrated an inc…
Isomers inPd128andPd126: Evidence for a Robust Shell Closure at the Neutron Magic Number 82 in Exotic Palladium Isotopes
2013
The level structures of the very neutron-rich nuclei $^{128}\mathrm{Pd}$ and $^{126}\mathrm{Pd}$ have been investigated for the first time. In the $r$-process waiting-point nucleus $^{128}\mathrm{Pd}$, a new isomer with a half-life of $5.8(8)\text{ }\text{ }\ensuremath{\mu}\mathrm{s}$ is proposed to have a spin and parity of ${8}^{+}$ and is associated with a maximally aligned configuration arising from the ${g}_{9/2}$ proton subshell with seniority $\ensuremath{\upsilon}=2$. For $^{126}\mathrm{Pd}$, two new isomers have been identified with half-lives of 0.33(4) and $0.44(3)\text{ }\text{ }\ensuremath{\mu}\mathrm{s}$. The yrast ${2}^{+}$ energy is much higher in $^{128}\mathrm{Pd}$ than in…
Excited states inPd115populated in theβ−decay ofRh115
2010
Excited states in $^{115}\mathrm{Pd}$, populated following the ${\ensuremath{\beta}}^{\ensuremath{-}}$ decay of $^{115}\mathrm{Rh}$ have been studied by means of $\ensuremath{\gamma}$ spectroscopy after the Penning-trap station at the IGISOL facility, University of Jyv\"askyl\"a. The $1$$/$$2$${}^{+}$ spin and parity assignment of the ground state of $^{115}\mathrm{Pd}$, confirmed in this work, may indicate a transition to an oblate shape in Pd isotopes at high neutron number.
Beta Decay of68–74Niand Level Structure of Neutron-Rich Cu Isotopes
1998
The isotopes ${}^{68--74}\mathrm{Ni}$, of interest both for nuclear physics and astrophysics, have been produced in proton-induced fission of ${}^{238}\mathrm{U}$ and ionized in a laser ion guide coupled to an on-line mass separator. Their $\ensuremath{\beta}$ decay was studied by means of $\ensuremath{\beta}$- $\ensuremath{\gamma}$ and $\ensuremath{\gamma}$- $\ensuremath{\gamma}$ spectroscopy. Half-lives have been determined and production cross sections extracted. A partial level scheme is presented for ${}^{73}\mathrm{Cu}$ and additional levels for ${}^{71}\mathrm{Cu}$, providing evidence for a sharply lowered position of the $\ensuremath{\pi}{1f}_{5/2}$ orbital as occupancy of the $\ens…
Direct mass measurements of cadmium and palladium isotopes and their double-βtransitionQvalues
2012
The Q-value of the double-electron capture in Cd-108 has been determined to be (272.04 +/- 0.55) keV in a direct measurement with the double-Penning trap mass spectrometer TRIGA-TRAP. Based on this result a resonant enhancement of the decay rate of Cd-108 is excluded. We have confirmed the double-beta transition Q-values of Cd-106 and Pd-110 recently measured with the Penning-trap mass spectrometers SHIPTRAP and ISOLTRAP, respectively. Furthermore, the atomic masses of the involved nuclides Cd-106, Cd-108, Cd-110, Pd-106, Pd-108 and Pd-110 have been directly linked to the atomic mass standard.
β-decay of 113Rh and the observation of 113mPd : Isomer systematics in odd-A palladium isotopes
1993
Abstract Decay of 113Rh to the levels of 113Pd was studied at the IGISOL-facility by means of β-, γ- and conversion-electron spectroscopy. The level scheme of 113Pd was constructed using 33 gamma transitions on the basis of observed γγ-coincidence relations and half-life analysis. A β-decay half-life of (2.80±0.12) s was measured for 113Rh. A new 9 − 2 isomeric state with (0.3 ± 0.1) s half-life and excitation energy 81.3 keV was discovered in 113Pd. This state and the other recently observed low-lying 9 − 2 or 11 − 2 isomeric states in 115,117Pd isotopes are directly populated in proton-induced fission. The decay of these isomers is unusually strongly hindered compared with Weisskopf estim…
Gamow-Teller decay of 118Pd and of the new isotope 120Pd
1993
Abstract With the use of the proton-induced fission of 238 U and the ion guide-fed on-line mass separation, even- A isotopes of palladium with high neutron excess were studied by means of γ-ray and conversion-electron spectroscopy. The decay of 118 Pd was reinvestigated in detail, and evidence for the new isotope 120 Pd, with a half-life T 1 2 = 0.5 ± 0.1 s , was found. As established for 118 Pd and tentatively shown for 120 Pd, the β-decay of these two isotopes proceeds mainly through 0 + → 1 + Gamow-Teller transitions with log ft values between 4.2 and 4.7. The strength of individual transitions has been compared with the predictions of the shell-correction model with a deformed Woods-Sax…
β-Decay Studies Close to the N=82 r-process Path
2005
New half-lives for neutron-rich ruthenium, rhodium and palladium isotopes close to the r-process path along the N=82 closed shell have been measured at the National Superconducting Cyclotron Laboratory at Michigan State University. The studied isotopes are close to the critical A=118-126 mass region in the astrophysical r-process, where incorrect nuclear structure development towards the shell closure may have the most pronounced effect on the abundances of elements produced. Neutron-rich nuclei were produced by fragmentation of a 120-MeV per nucleon 136 Xe beam on Be and were separated by the A1900 fragment separator. The nuclei of interest were implanted into a double-sided Si strip detec…
New isomers in $^{125}$Pd$_{79}$ and $^{127}$Pd$_{81}$: Competing proton and neutron excitations in neutron-rich palladium nuclides towards the $N = …
2019
The neutron-rich isotopes of palladium have attracted considerable interest in terms of the evolution of the N=82 neutron shell closure and its influence on the r-process nucleosynthesis. In this Letter, we present the first spectroscopic information on the excited states in Pd and Pd studied using the EURICA γ-ray spectrometer, following production via in-flight fission of a high-intensity U beam at the RIBF facility. New isomeric states with half-lives of 144(4) ns and 39(6) μs have been assigned spins and parities of (23/2 ) and (19/2 ) in Pd and Pd, respectively. The observed level properties are compared to a shell-model calculation, suggesting the competition between proton excitation…
Microscopic anharmonic vibrator approach for beta decays
2007
Abstract We formulate a microscopic description of charge-changing excitations, including dynamical mixture of one- and two-phonon states. The present formalism generalizes our previous microscopic anharmonic vibrator approach (MAVA), designed to treat charge-conserving two- and four-quasiparticle degrees of freedom and their mixing. In the present formalism, the proton–neutron MAVA, pnMAVA, the main building blocks are the quasiparticle random-phase approximation (QRPA) phonons in the charge-conserving channels, and the proton–neutron QRPA (pnQRPA) phonons in the charge-changing channels. The QRPA and pnQRPA equations are directly used in deriving the equations of motion for two-phonon sta…