Search results for "Papers"
showing 10 items of 345 documents
4-[5-Amino-4-(4-fluorophenyl)-3-(pyridin-4-yl)-1H-pyrazol-1-yl]benzonitrile
2012
In the crystal structure of the title compound, C21H14FN5, the pyrazole ring forms dihedral angles of 38.0 (1), 40.0 (1) and 28.5 (1)° with the directly attached 4-fluorophenyl, pyridine and benzonitrile rings, respectively. The crystal packing is characterized by N—H...N hydrogen bonds, which result in a two-dimensional network parallel to theac-plane.
2,2-Diphenylbenzo[c]quinoline-1-oxyl
2009
In the title compound, C25H18NO, a stable phenanthridinic nitroxide, the ring containing the nitroxide function assumes a twist-boat conformation and the dihedral angle formed by adjacent benzene rings is 21.78 (5)°. The phenyl substituents at position 2 are approximately orthogonal to each other, forming a dihedral angle of 81.04 (4)°. The crystal structure is stabilized by an intramolecular C—H...O hydrogen bond and by C—H...π interactions.
Time-of-flight photoelectron momentum microscopy with 80–500 MHz photon sources: electron-optical pulse picker or bandpass pre-filter
2021
Journal of synchrotron radiation 28(6), 1891 - 1908 (2021). doi:10.1107/S1600577521010511
Potential impact of a nonavalent HPV vaccine on HPV related low-and high-grade cervical intraepithelial lesions: A referral hospital-based study in S…
2017
ABSTRACT While bivalent and quadrivalent HPV vaccines have been used for about 10 years, a nonavalent vaccine against HPV types 6/11/16/18/31/33/45/52 and 58 has been recently approved by FDA and EMA and is now commercially available. The objective of our study was to evaluate the potential impact of the nonavalent vaccine on HPV infection and related low- and high-grade squamous intraepithelial lesions (LSIL, HSIL), compared to the impact of the quadrivalent vaccine, in a female population living in Sicily (Italy). Low estimates of HPV vaccine impact were calculated as prevalence of HPV 6/11/16/18/31/33/45/52 and 58 genotypes, alone or in association, but excluding presence of other HPV ty…
The association between Mediterranean Diet Score and glucokinase regulatory protein gene variation on the markers of cardiometabolic risk: an analysi…
2014
Consumption of a Mediterranean diet (MD) and genetic variation in the glucokinase regulatory protein (GCKR) gene have been reported to be associated with TAG and glucose metabolism. It is uncertain whether there is any interaction between these factors. Therefore, the aims of the present study were to test the association of adherence to a MD and rs780094 (G>A) SNP in theGCKRgene with the markers of cardiometabolic risk, and to investigate the interaction between genetic variation and MD adherence. We studied 20 986 individuals from the European Prospective Investigation into Cancer (EPIC)-Norfolk study. The relative Mediterranean Diet Score (rMED: range 0–18) was used to assess MD adher…
Evolution of the opinion of newspapers on the Catalan conflict from 2010 to 2017
2020
Comunicació presentada al VII Congreso Internacional de la Asociación Española de Investigación de la Comunicación (AE-IC), celebrat del 28 al 30 d'octubre de 2020 a València, Espanya. Si hubiera que precisar el origen de lo que actualmente se conoce como “el Procés” de independencia de Catalunya probablemente coincidiríamos en localizarlo en julio de 2010, cuando se hizo pública la sentencia del Tribunal Constitucional en contra del Estatut. El 10 de julio de 2010 tuvo lugar en Barcelona una manifestación multitudinaria en contra de esa sentencia que significaba unos recortes importantes sobre el texto inicial que el pueblo catalán había refrendado. A partir de ese momento, la desafección …
9-Eth-oxy-1,5,13-trimethyl-8,10-dioxa-tetra-cyclo-[7.7.1.0.0]hepta-deca-2,4,6,11,13,15-hexa-ene.
2009
The reaction of ethyl acetoacetate with meta-cresol in an acidic ionic liquid yielded a complex mixture of condensation products. 4,7-Dimethyl-coumarin and the title compound, C(20)H(22)O(3), were isolated. The title compound shows chemical but not crystallographic mirror symmetry. The two aromatic rings are inclined at an angle of 73.55 (6)°.
A Comparative Study of Cyclic Fatigue of 10 Different Types of Endodontic Instruments: an in Vitro Study
2019
Objective This study was designed to test the null hypothesis that there were no significant differences between size 25 files F360, F6 SkyTaper, Hyflex EDM, iRace, Neoniti, One Shape Protaper Next, Reciproc, Revo-S and Wave One Gold in terms of resistance to cyclic fatigue and length of broken fragments. Material and methods 300 new size 25 files of the systems studied were selected (n=30). The instruments were mechanized with a X-Smart Plus endo motor at the speed and torque recommended by the manufacturer, holding the instruments steady with a clamping mechanism, with passive adjustment and without pressure in a stainless-steel block. The time was calculated in seconds until fracture. Th…
Comparison of Shaping Ability of 10 Rotary and Reciprocating Systems: an In Vitro Study with AutoCAD
2017
Cilj: Usporediti reznu površinu, očuvanje anatomije korijenskog kanala i neinstrumentiranu površinu nakon instrumentacije sustavima F360®, F6SkyTaper®, HyflexEDM®, iRace®, Neoniti®, O.Shape®, P.Next®, Reciproc®, Revo-S® i WaveOneGold® s veličinom instrumenta 25. Materijali i metode: Tristo zubi s jednim ravnim korijenom i okruglim ili eliptičnim presjekom korijenskog kanala podijeljeno je u 10 skupina (1-F360®, 2-F6SkyTaper®, 3-HyflexEDM®, 4-iRace®, 5-Neoniti®, 6-O Shape®, 7-P.Next®, 8-Reciproc®, 9-Revo-S® i 10-WaveOneGold®) i poprečno prerezano na trećine ultrafinim reznim diskovima. Uzorci su fotografirani pod stereomikroskopom i provedena je predinstrumentacijska analiza prije ponovnog s…
Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals
2020
Abstract The substitution of catalytic metals by p‐block main elements has a tremendous impact not only in the fundamentals but also in the economic and ecological fingerprint of organic reactions. Here we show that few‐layer black phosphorous (FL‐BP), a recently discovered and now readily available 2D material, catalyzes different radical additions to alkenes with an initial turnover frequency (TOF0) up to two orders of magnitude higher than representative state‐of‐the‐art metal complex catalysts at room temperature. The corresponding electron‐rich BP intercalation compound (BPIC) KP6 shows a nearly twice TOF0 increase with respect to FL‐BP. This increase in catalytic activity respect to t…