Search results for "Partial"

TiO2 based Inorganic-Organic Hybrid Photocatalysts for Highly Selective Alcohol Partial Oxidation

2015

An integrated approach to develop a composite hybrid material made of titanium dioxide functionalized with an organic conjugated phenol (DIOL) and silver NPs suitable for the selective oxidation of water soluble aromatic alcohols to aldehydes in water under UV irradiation and very mild conditions was used. The 86% selectivity observed for the Rutile/DIOL/Ag composite is, to the best of our knowledge, the highest thus far reported for partial oxidation of aromatic alcohols to aldehydes in water suspensions of titanium dioxide. The method is general as it relies on the concomitant easier adsorption of the aromatic alcohol and more facile release of the aldehyde, coupled to fast interfacial el…

Photocatalytic and photoelectrocatalytic H2 evolution combined with valuable furfural production

2023

In this work the photocatalytic (PC) and photoelectrocatalytic (PEC) reforming of furfuryl alcohol (FA) under environmental friendly conditions was investigated. Both H2 evolution and partial oxidation to furfuraldehyde were followed. For the first time TiO2 based photocatalysts were studied and the photocatalytic activity of home prepared photocatalysts was compared with that of commercial ones under both UVA and simulated solar irradiation. PEC tests were performed by using home prepared TiO2 nanotubes (TiO2 NTs) as photoanode and Pt free Ni foam as cathode to improve the Hydrogen Evolution Reaction (HER). Both the partial FA oxidation reaction rate and H2 evolution rate were normalized f…

A facile way to synthesize noble metal free TiO2 based catalysts for glycerol photoreforming

2023

In this work anaerobic heterogeneous photocatalytic solar/UV light reforming of glycerol in aqueous media was performed with Pt-photodeposition and noble metal free modified TiO2 photocatalysts prepared through ball milling, a very simple and cheap coupled catalyst preparation method. Different amounts of Cu2O or 3% CuO were loaded on TiO2 using ball milling and during each run glycerol conversion, hydrogen and CO2 formed in the gas phase and 1,3-dihydroxyacetone (DHA) and glyceraldehyde (GA) in the liquid phase were determined. The results were compared with the aim to verify the effectiveness of Cu2O in replacing Pt. Using noble metal free photocatalysts, 33% glycerol conversion, 10.3% an…

Test procedures for use of wireless partial discharges instrumentation in HV networks

2014

On-field diagnostic methods based on Partial Discharge (PD) measurements for asset assessment in High Voltage (HV) sectors are experiencing a constant growth in recent years. This rise of interest motivated the research toward faster, reliable and less expensive methods and technologies to perform PD measurements. Recently, a portable instrument based on a wideband antenna sensor, intended for accurate partial discharge measurements, has been developed by the authors. This sensor allows to capture electromagnetic waves in a bandwidth ranging from 0.1-100 MHz as well as the electric field of the AC supply voltage to be used as a phase reference. This approach completely avoid the need of a d…

Performances of a PCB-based Loop Antenna Inductive Sensor for Partial Discharges Detection

2022

This paper presents the test results of an electrically small loop antenna sensor towards detecting the radiated magnetic field due to partial discharge (PD) activities. The loop antenna prototype was printed on an FR-4 substrate with a thickness of 1.6 mm, featuring a compact size of 20 mm times20 mm times1.7 mm. The proposed sensor, initially simulated with Ansys HFSS software, has a resonant frequency of about 100 MHz. Its detection capability for three types of partial discharges (i.e., corona, surface and internal PDs) has been evaluated. Laboratory experiments showed that the evaluated loop spiral antenna is appropriate for the detection of the three types of PDs. Indeed, the results …

Partial discharges characteristics during load transients in an HVDC model cable

2021

The occurrence of Partial Discharges (PD) in HVAC cables is widespread considered as one of the most important concerns for the stability of the insulation. To date, the role of PD in the ageing and definitive fault of HVDC cables has been poorly investigated. This is mainly due to some practical difficulties in the performing of the measurements. Compared to the PDs occurring under AC stress, the higher inception voltages and the lower repetition rates, obtainable under DC voltage, make the exclusion of the measurement noise more difficult. This paper is focused on the study of the characteristics of the PDs occurring in an artificial defect located in proximity of the outer dielectric' su…

Characteristics of partial discharges in an experimental setup reproducing HVDC cable insulation operating conditions

2021

The occurrence of Partial Discharge (PD) inside a cavity subjected to HVDC voltage can be considered as one of the most likely sources of insulation ageing and failure. In practical applications, the recognition of PD under HVDC is more difficult than under AC stress because of the lower repetition rates and the impossibility to obtain a PD pattern synchronized with the waveform of the applied voltage. In this paper, the relationship between conduction phenomena in dielectrics and the occurrence of PD is investigated by means of a novel experimental setup. A couple of dielectric cells connected in series is subjected to various HVDC stress levels. The applied voltage is divided between the …

Investigation of PCB-based Inductive Sensors Orientation for Corona Partial Discharge Detection

2022

This paper presents an experimental investigation of two different printed circuit board (PCB) inductive sensors, with meander and non-spiral shapes, to assess their capabilities and best orientation for corona partial discharge (PD) detection. First, simulations with the Ansys HFSS software are performed in order to evaluate the equivalent electrical circuit of the two sensors and their 2d radiation patterns. The meander sensors presented a resonant frequency of 600 MHz, while it was around 1.1 GHz for the non-spiral. The 2d radiation pattern showed that better sensitivity is achieved when the inductive sensor is oriented 90 degrees with respect to the PD source. Experimental tests showed …

CARATTERIZZAZIONE ELETTROMAGNETICA DI IGBT IN PRESENZA DI SCARICHE PARZIALI

2014

Use of Time-Frequency map combined with DBSCAN algorithm for separation of partial discharge pulses under DC voltage

2022

The Phase-Resolved-Partial-Discharge pattern (PRPD) is a conventional technique used for the evaluation of partial discharges (PD) phenomena in High-Voltage-Alternating-Current (HVAC) systems. This map is constructed by plotting the peak of each detected pulses as a function of the phase angle of the supply voltage. Therefore it is obvious that this technique cannot be used for the analysis of data from PD mesaurement under different supply voltage condition (DC). The aim of this paper is to evaluate the application of the Time-Frequency map (TF map) for the analysis of a dataset obtained from PD measurement under DC voltage. A density-based clustering algorithm was also used to gain more i…