Search results for "Particle-Size"
showing 10 items of 97 documents
One dimensional consolidation of Opalinus Clay from shallow depth
2017
First experimental results on Opalinus Clay from shallow depth (< 30 m depth) are presented and compared to results on cores from Mont Terri Underground Rock Laboratory (~ 300 m depth). Samples were tested in one dimensional condition using an advanced experimental technique. The samples from the two sites show similar properties in terms of geotechnical characterization and one dimensional compressibility/swelling indexes, despite the different source depths.
Small changes in particle-size distribution dramatically delay and enhance nucleation in hard sphere colloidal suspensions.
2006
We present hard-sphere crystallization kinetics for three samples with small differences in polydispersity. We show that an increase in polydispersity of 1% is sufficient to cause dramatic changes in the crystallization kinetics: Crystallization is delayed by almost one decade in time and quantitative and qualitative changes in the crystallization scenario are observed. Surprisingly the nucleation rate density is enhanced by almost a factor of 10. We interpret these results in terms of polydispersity limited growth, where local fractionation processes lead to a delayed but faster nucleation.
Effect of particle size distribution in laser-induced breakdown spectroscopy analysis of mesoporous V–SiO2 catalysts
2011
In this paper, the effect of particle size on Laser-Induced Breakdown Spectroscopy (LIBS) analysis of mesoporous V–SiO2 catalyst samples was investigated. The measurements were realized on three LIBS devices with different parameters. Concentrations of V in samples used for LIBS experiments previously determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES) varied from 1.2 to 4.7 w/w%. Granulometry of silica samples was modified by two grinding methods (conventional vibration mill and cryogenic mill) and three sets of samples with different particle size distributions were obtained. Ground samples were then deposited in the form of a thin layer on the adhesive tape a…
COMPARING PARTICLE SIZE DISTRIBUTION ANALYSIS BY SEDIMENTATION AND LASER DIFFRACTION METHOD
2009
In this paper a brief review of the laser diffraction method is firstly carried out. Then, for 30 soil samples having a different texture classification sampled in Sicilian basin, a comparison between the two techniques is developed. The analysis demonstrated that the sand content measured by Sieve-Hydrometer method can be assumed equal to the one determinated by laser diffraction technique while an overestimation of the clay fraction measured by Sieve-Hydrometer method respect to laser diffraction technique was obtained. Finally a set of equations useful to refer LD measurements to SH method was proposed.
Assessing the particle size of a broadly dispersed powder by complementary techniques
1998
The experimental determination of reliable particle size distribution curves and statistical parameters of broad distributions is known to be a difficult task. This problem is addressed here in an attempt to characterize the granularity of three distinct batches of a pharmaceutical powder (fenofibrate from Fournier Laboratories). The methodology consists in comparing the results, expressed in terms of surface based mean diameter, as obtained by three complementary techniques, namely optical microscopy image analysis, laser light low angle diffraction and surface area measurement by krypton physisorption. These techniques are applied in parallel to the material of interest and to a certified…
RAPID CONDENSATIONAL GROWTH OF PARTICLES IN THE INLET OF PARTICLE SIZING INSTRUMENTS
2000
Abstract Rapid particle growth by the condensation of water vapour resulting from expansion in the inlet of particle sizing instruments such as optical particle counters and impactors was modelled. The corrected Mason diffusion growth equation extended to the application for particles beyond the continuum region has been found suitable. The influence of particle acceleration in the nozzle air flow, modelled with the CFX-FLOW3D program, on the condensation process was considered. The study was focused on a typical inlet nozzle of an optical particle counter with an inner diameter of 0.5 mm and a length of 20 mm, connected by an additional 20 mm long conical nozzle at a flow rate of 28.5 ml s…
Physics of agarose fluid gels: Rheological properties and microstructure
2021
Agarose, a strongly gelling polysaccharide, is a common ingredient used to optimize the viscoelastic properties of a multitude of food products. Through aggregation of double helices via hydrogen bonds while cooling under quiescent conditions it forms firm and brittle gels. However, this behavior can be altered by manipulating the processing conditions viz shear. For example, gelation under shear leads to microgel particles with large surface area, which in turn leads to completely different rheological properties and texture. Such fluid gels are shown to play an important role in texture modification of foods and beverages for dysphagia patients. In this study, different concentration of a…
Occurrence of coal and coal-derived particle-bound polycyclic aromatic hydrocarbons (PAHs) in a river floodplain soil.
2006
A PAH contaminated river floodplain soil was separated according to grain size and density. Coal and coal-derived particles from coal mining, coal industry and coal transportation activities were identified by organic petrographic analysis in our samples. Distinct concentrations of PAHs were found in different grain size and density fractions, however, similar distribution patterns of PAHs indicated similar sources. In addition, although light fractions had the mass fraction by weight of less than 5%, they contributed almost 75% of the total PAHs in the soil. PAH concentrations of all sub fractions showed positive correlation with their TOC contents. Altogether, coal and coal-derived partic…
Testing the BEST procedure to estimate the soil water retention curve
2012
The BEST (Beerkan Estimation of Soil Transfer parameters) procedure is attractive for simple soil hydraulic characterization but there is the need to test the reliability of the predictions. In this investigation, the BEST procedure to predict water retention of 199 Sicilian soils was evaluated. The BEST water retention model performed well (relative error, Er≤0.05) for approximately 80% of the soil samples. Low errors were obtained in soils with a high clay, cl, content (≥44%), whereas both high and low Er values were obtained in soils with a lower cl content. The BEST particle size distribution (PSD) model was accurate for 50% of the samples and the fitting accuracy increased with cl, wit…
Calculations of the variability of ice cloud radiative properties at selected solar wavelengths
2010
This study shows that there is surprising little difference in values of reflectance, absorptance, and transmittance for many of the intermediate-size particle spectra. Parrticle size distributions with mode radii ranging from approximately 50 to 300 microAm, irrespective of particle shape and nearly independent of the choice of size distribution representation, give relatively similar flux values. The very small particle sizes, however, have significantly larger values of reflectance and transmittance with corresponding smaller values of absorptance than do the larger particle sizes. The very large particle modes produce very small values of reflectance and transmittance along with very la…