Search results for "Pentafluoride"
showing 2 items of 2 documents
Feasibility of photodetachment isobar suppression of WF with respect to HfF
2014
Abstract The feasibility of using laser photodetachment as a means for isobar suppression in accelerator mass spectrometry has been investigated for the special case of HfF 5 − /WF 5 − . A method for absolute photodetachment cross section measurements was applied and the cross sections of tungsten pentafluoride and hafnium pentafluoride negative ions were measured. The measurements indicate that the photodetachment cross section for WF 5 − is at least 100 times larger than for HfF 5 − at the wavelength of the fourth harmonic of the Nd:YAG laser at 266 nm. The absolute cross section for WF 5 − at this photon energy was found to be (2.8 ± 0.3) × 10 −18 cm 2 , while an upper limit of 2 × 10 −…
Deformation of sulfur hexafluoride and floppiness of trifluoromethyl sulfur pentafluoride
2006
International audience; With recent advances in space exploration and atmospheric chemistry there is an increased need for more spectroscopic tools to allow the of study complex species. One such tool is the theory of frame transformation of coupled rotor systems. In this article, the theory of frame transformation along with the concept of rotational energy surface is used to study the symmetry that occurs in trifluoromethyl sulfur pentafluoride due to the internal rotation of the CF3 radical and, more generally, to the extent of floppiness of SF5CF3. Other lower symmetries when a CF4 molecule is stuck on the various symmetry axes of an SF6 molecule are also discussed.