Search results for "Perchlorate"
showing 10 items of 643 documents
CCDC 723683: Experimental Crystal Structure Determination
2010
Related Article: H.Arora, F.Lloret, R.Mukherjee|2009|Eur.J.Inorg.Chem.||3317|doi:10.1002/ejic.200900326
CCDC 1944600: Experimental Crystal Structure Determination
2019
Related Article: Víctor García-López, Mario Palacios-Corella, Salvador Cardona-Serra, Miguel Clemente-León, Eugenio Coronado|2019|Chem.Commun.|55|12227|doi:10.1039/C9CC05988A
CCDC 1478367: Experimental Crystal Structure Determination
2017
Related Article: Saikat Banerjee, Sattwick Halder, Paula Brandão, Carlos J. Gómez García, Samia Benmansour, Amrita Saha|2017|Inorg.Chim.Acta|464|65|doi:10.1016/j.ica.2017.04.056
CCDC 987580: Experimental Crystal Structure Determination
2014
Related Article: Isabel Castro, M. Luisa Calatayud, Wdeson P. Barros, José Carranza, Miguel Julve, Francesc Lloret, Nadia Marino, and Giovanni De Munno|2014|Inorg.Chem.|53|5759|doi:10.1021/ic500544n
CCDC 978950: Experimental Crystal Structure Determination
2014
Related Article: Ravindra Singh, Francesc Lloret and Rabindranath Mukherjee|2014|Z.Anorg.Allg.Chem.|640|1086|doi:10.1002/zaac.201400005
CCDC 1935981: Experimental Crystal Structure Determination
2019
Related Article: Sacramento Ferrer, Javier Hernández-Gil, Francisco Javier Valverde-Muñoz, Francisco Lloret, Alfonso Castiñeiras|2019|RSC Advances|9|29357|doi:10.1039/C9RA05922A
On Demand One-Pot Mild Preparation of Layered Double Hydroxides and Their Hybrid Forms: Advances through the Epoxide Route.
2019
Epoxide ring opening driven alkalinization process was explored with the aim of preparing layered double hydroxide (LDH) phases on demand, at room temperature. Employing iodide as nucleophilic agent, the precipitation reaction can be driven under much lower halide concentrations. This scenario favors the selective intercalation of concomitant bulky oxo anions as nitrate or perchlorate in the LDH products, allowing for the one-pot synthesis of an LDH able to delaminate in formamide. Even large dicarboxylic acids, - O2 C-(CH2 )n -CO2 - , with n up to 8, can be quantitively intercalated within the growing LDH phase, providing a versatile one-pot route for hybrid LDHs as well. Under the mild co…
Spin Transition of 1D, 2D and 3D Iron(II) Complex Polymers The Tug-of-War between Elastic Interaction and a Shock-Absorber Effect
2003
The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.
Alkyl- and aryl-substituted corroles. 4. Solvent effects on the electrochemical and spectral properties of cobalt corroles.
2003
Solvent effects on the electrochemistry and spectroscopic properties of alkyl- and aryl-substituted corroles in nonaqueous media are reported. The oxidation and reduction of six compounds containing zero to seven phenyl or substituted phenyl groups on the macrocycle were studied in four different nonaqueous solvents (CH(2)Cl(2), PhCN, THF, and pyridine) containing 0.1 M tetra-n-butylammonium perchlorate. Dimers were formed upon oxidation of all corroles in CH(2)Cl(2), but this was not the case in the other three solvents, where either monomers or dimers were formed upon oxidation depending upon the solvent Gutmann donor number and the number or location of aryl substituents on the macrocycl…
Complexation of planar, organic, five-membered cations with crown ethers
2000
Complexation of six aromatic, nitrogen-containing cations with various crown ethers has been studied using 1H NMR, mass spectrometric and crystallographic methods. Hydrogen bonding appears to be the most important interaction in complexation, but minor effects such as π-stacking or cation–π interactions have also been observed. The stability constants of five different imidazolium perchlorate ·crown ether complexes and five other similar cation·DB18C6 complexes were determined by 1H NMR titration in acetonitrile solution. The stability of these complexes in solution and in the gas phase is discussed. The crystal structures of seven complexes were determined in order to study complexation in…