Search results for "Percolation threshold"
showing 10 items of 34 documents
Rheological Percolation Threshold in High-Viscosity Polymer/CNTs Nanocomposites
2017
AbstractPolystyrene (PS)/multi-walled carbon nanotubes (CNT) nanocomposites have been prepared through melt mixing processing aiming at obtaining a uniform and homogeneous dispersion of the used nanoparticles within the polymeric matrix. Optical and scanning electron microscopy has been employed to determine the dispersion and distribution of CNTs at different length scales. Furthermore, the linear viscoelastic behavior of formulated nanocomposites has been deeply investigated. As a result of CNTs added, the nanocomposites experience a transition from liquid-like to solid-like rheological behavior, and a disappearance of relaxation processes at low frequency can be noticed. By plotting G’ v…
Pore structural characteristics, size exclusion properties and column performance of two mesoporous amorphous silicas and their pseudomorphically tra…
2007
Highly ordered mesoporous silicas such as, mobile composition of matter, MCM-41, MCM-48, and the SBA-types of materials have helped to a large extent to understand the formation mechanisms of the pore structure of adsorbents and to improve the methods of pore structural characterization. It still remains an open question whether the high order, the regularity of the pore system, and the narrow pore size distribution of the materials will lead to a substantial benefit when these materials are employed in liquid phase separation processes. MCM-41 type 10 microm beads are synthesized following the route of pseudomorphic transformation of highly porous amorphous silicas. Highly porous silicas a…
Effect of the Content and Ordering of the sp2 Free Carbon Phase on the Charge Carrier Transport in Polymer-Derived Silicon Oxycarbides
2020
The present work elaborates on the correlation between the amount and ordering of the free carbon phase in silicon oxycarbides and their charge carrier transport behavior. Thus, silicon oxycarbides possessing free carbon contents from 0 to ca. 58 vol.% (SiOC/C) were synthesized and exposed to temperatures from 1100 to 1800 °
Depletion-induced percolation in networks of nanorods.
2006
Above a certain density threshold, suspensions of rod-like colloidal particles form system-spanning networks. Using Monte Carlo simulations, we investigate how the depletion forces caused by spherical particles affect these networks in isotropic suspensions of rods. Although the depletion forces are strongly anisotropic and favor alignment of the rods, the percolation threshold of the rods decreases significantly. The relative size of the effect increases with the aspect ratio of the rods. The structural changes induced in the suspension by the depletant are characterized in detail and the system is compared to an ideal fluid of freely interpenetrable rods.
Spontaneous symmetry-breaking pathways: time-resolved study of agarose gelation
1996
Abstract Extensive time-resolved studies of self-assembly of agarose gels, performed with the use of a variety of techniques allowed identification of the initial break of symmetry and the actual path leading to self-assembly at concentrations well below the random percolation threshold. The overall process is seen to occur through the following sequence: (i) break of symmetry in the sol, causing the spontaneous generation of mesoscopic polymer-rich and solvent-rich regions; (ii) percolation, or nearly percolation [see (iv) below], of polymer-rich regions through the sample, still in the sol state; (iii) start of polymer cross-linking within polymer-rich regions; (iv) progress of cross-link…
Controlling electrical percolation in multicomponent carbon nanotube dispersions
2011
Carbon nanotube reinforced polymeric composites can have favourable electrical properties, which make them useful for applications such as flat-panel displays and photovoltaic devices. However, using aqueous dispersions to fabricate composites with specific physical properties requires that the processing of the nanotube dispersion be understood and controlled while in the liquid phase. Here, using a combination of experiment and theory, we study the electrical percolation of carbon nanotubes introduced into a polymer matrix, and show that the percolation threshold can be substantially lowered by adding small quantities of a conductive polymer latex. Mixing colloidal particles of different …
Percolation and Schramm–Loewner evolution in the 2D random-field Ising model
2011
Abstract The presence of random fields is well known to destroy ferromagnetic order in Ising systems in two dimensions. When the system is placed in a sufficiently strong external field, however, the size of clusters of like spins diverges. There is evidence that this percolation transition is in the universality class of standard site percolation. It has been claimed that, for small disorder, a similar percolation phenomenon also occurs in zero external field. Using exact algorithms, we study ground states of large samples and find little evidence for a transition at zero external field. Nevertheless, for sufficiently small random-field strengths, there is an extended region of the phase d…
Electrical transport in carbon black-epoxy resin composites at different temperatures
2013
Citation: J. Appl. Phys. 114, 033707 (2013); doi: 10.1063/1.4815870 (Received 3 May 2013; accepted 27 June 2013; published online 17 July 2013) Results of broadband electric/dielectric properties of different surface area—carbon black/epoxy resin composites above the percolation threshold are reported in a wide temperature range (25–500 K). At higher temperatures (above 400 K), the electrical conductivity of composites is governed by electrical transport in polymer matrix and current carriers tunneling from carbon black clusters to polymer matrix. The activation energy of such processes decreases when the carrier concentration increases, i.e., with the increase of carbon black concentration…
Dynamic percolation transition induced by phase separation: A Monte Carlo analysis
1987
The percolation transition of geometric clusters in the three-dimensional, simple cubic, nearest neighbor Ising lattice gas model is investigated in the temperature and concentration region inside the coexistence curve. We consider “quenching experiments,” where the system starts from an initially completely random configuration (corresponding to equilibrium at infinite temperature), letting the system evolve at the considered temperature according to the Kawasaki “spinexchange” dynamics. Analyzing the distributionnl(t) of clusters of sizel at timet, we find that after a time of the order of about 100 Monte Carlo steps per site a percolation transition occurs at a concentration distinctly l…
Permeability and effective porosity of porous media
1997
The concept of permeability of porous media is discussed, and a modification of Kozeny’s permeability equation to include the effect of effective porosity is introduced. An analytical expression for the specific surface area of a system constructed of randomly placed identical obstacles with unrestricted overlap is derived, and a lattice-gas cellular automaton method is then used to simulate the dependence on porosity of permeability, tortuosity, and effective porosity for a flow of Newtonian uncompressible fluid in this two-dimensional porous substance. The simulated permeabilities can well be explained by the concept of effective porosity, and the exact form of the specific surface area. …