Search results for "Periodic table"
showing 10 items of 262 documents
Two-Dimensional Melting Approached via Finite-Size Scaling of Bond-Orientational Order
1994
Relying on Monte Carlo simulations, we investigate the hard-disk melting transition. The finite-size scaled values of the bond-orientational order parameter moments are obtained with the block analysis technique. The behaviour of Binder's cumulant and the susceptibility favour an interpretation in terms of a first-order transition.
Structural study, thermal expansion and electrical conductivity of the composition NaSnZr(PO4)3
1993
Abstract The structure of the composition NaSnZr(PO4)3 and its evolution with temperature has been studied. The structure presents the space group R 3 c. The refinement of the structure shows that the Sn and Zr atoms are statistically distributed over the same crystallographic position. The unit cell expands in the c direction and contracts in the a direction, remaining the space group R 3 c at temperatures between 26 and 1000°C. The low value of the electrical conductivity at 400°C, 5.729×10−7S/cm and the low density of the pellets limited the use as electrical conductor.
Adsorption Active Diblock Copolymers as Universal Agents for Unusual Barrier-Free Transitions in Stimuli-Responsive Brushes
2021
We reconsider a recently proposed design for smart responsive brushes, which is based on a conformational transition in very dilutely embedded block copolymers with a surface active block (Qi et al., Macromolecules 53, 5326, 2020). Under certain conditions, the transition acquires an unusual character: it remains very sharp, but the barrier separating the adsorbed and desorbed states disappears completely. We show that these features are very robust with respect to changing almost all system parameters: the lengths of the inert and active blocks of the minority chain, the brush length, its density, and its polydispersity. The only relevant condition is that the inert block of the minority c…
Evaluation of the effect of three innovative recyling methods on the shear bond strength of stainless steel brackets-an in vitro study
2016
Background Orthodontists are commonly faced with the decision of what to do with debonded or inaccurately positioned brackets. An economical option to this dilemma is to recycle the brackets. Many recycling methods have been proposed, but the optimal bond strength of these recycled brackets needs further evaluation. Objectives: To evaluate and compare the effect of three recycling methods: (i) Sandblasting (ii) Sandblasting / direct flaming (iii) Sandblasting /direct flaming /acid bath solution on shear bond strength (SBS) of stainless steel brackets. Material and Methods Eighty human premolars were bonded with premolar stainless steel brackets as per manufacturer’s instructions. The teeth …
Are Metal-Free Monolithic Crowns the Present of Prosthesis? Study of Mechanical Behaviour
2019
Purpose: To analyze in vitro the mechanical behavior of five types of complete coverage crowns fabricated from different materials. Materials and methods: Seventy-five full coverage crowns were divided into five groups according to material: Group I, metal core with feldspathic ceramic covering (MC- control group)
Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations
2017
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775
Substitution Effects in Double Perovskites: How the Crystal Structure Influences the Electronic Properties
2013
We systematically studied substituted Sr2FeReO6 with respect to experimental characterization and theoretical band structure calculations. In the framework of the tight-binding approach, hole- or electron-doping of Sr2MM’O6 were performed at the M or M’ positions either by transition or main group metals. Hole-doping, rather than electron-doping, has a favorable effect to improve the half-metallicity (Curie temperature and saturation magnetization) of the parent compound. When M is substituted by another metal, the original M’ metal will serve as a redox buffer (and vice versa). Substituting M by another metal with a size similar to that of the metal at M’ position causes disorder, which ha…
CONCENTRATION MEASUREMENTS OF 7Be AT GROUND LEVEL AIR AT PALERMO, ITALY- COMPARISON WITH SOLAR ACTIVITY OVER A PERIOD OF 21 YEARS
2003
Air activity concentrations of (7)Be in Palermo determined for the period January 1995-December 2002 by gamma-ray spectrometric analysis of particulate samples collected on paper filter by a high-volume sampler (approximately 900 m(3) h(-1)) are reported. The temporal behaviour of (7)Be concentration presents the same characteristics already observed in the measurements carried out over the previous 13-year (1982-1994) investigated period. The mean value of 5.06 mBq m(-3) obtained from the analysis of the 4636 particulate samples collected from 1982 to 2002 can be considered a representative value of (7)Be air concentration at ground level in our geographical zone. The comparison of long-te…
Eukaryotes Are a Holophyletic Group of Polyphyletic Origin.
2020
Because of the polyphyletic origin of the eukaryotic monophylum, eukaryogenesis within prokaryotes is not comparable with mammal origin within paraphyletic reptiles. Both synapomorphies and plesiomorphies represent apomorphies and are indeed suitable for defining monophyletic (holophyletic and paraphyletic) groups. Alphaproteobacteria (Bacteria) and Asgard (Archaea) are the ancestors of LECA (the Last Eukaryotic Common Ancestor). The presence of ESPs in Asgard does not dispute the polyphyletic origin of eukaryotes ; it only further corroborates it. “Candidatus Prometheoarchaeum syntrophicum” is the closest relative to eukaryotes and the only Asgard with available microscopy data. This newly…
Solvates of Dasatinib: Diversity and Isostructurality
2015
A series of dasatinib crystalline forms were obtained, and a hierarchical cluster analysis of their powder X-ray diffraction patterns was performed. The resulting dendrogram implies 3 structural groups. The crystal structures of several solvates representing 2 of these groups were determined. The crystal structure analysis confirms the isostructurality of solvates within structural group I and suggests a correlation between solvent molecule size and trends in crystal structures within this group. In addition, the formation relationships in 2-solvent media between different dasatinib solvate groups were determined. The formation preference of solvates was found to follow the ranking group I …