Search results for "Phase Transition"

Understanding complex phase transition mechanism by crystal structure analysis

2014

Xylazine hydrochloride (2-(2,6-xylidino)-5,6-dihydro-4H-1,3-thiazine hydrochloride) is an adrenergic α-agonist used as a sedative, analgesic, and muscle relaxant in veterinary medicine. It has four polymorphous forms (A, Z, M and X), monohydrate (H), hemihydrate and solvates with dichloromethane and 2-propanol. It has been reported that the polymorph X is thermodynamically the least stable of these polymorphs, while the A is the most stable form at temperatures above 500C. The X forms only in H dehydration process, and at elevated temperature X transforms to polymorph A [1]. The crystal structures of the polymorphs A and X as well as hydrate H have been reported. Crystal structure of A and …

Study of the chemically activated sublimation of ZnSe

1999

Abstract The reactions and processes involved in the growth of ZnSe by chemically activated sublimation in a H 2 atmosphere are studied. The rate of transport as a function of source and substrate temperatures and the difference between them are determined from close spacing vapour transport experiments. According to this process, ZnSe layers are deposited on sapphire substrates by short distance chemically assisted sublimation. The experimental results are analysed and the thermodynamic constants of the transport are determined using a theoretical model for kinetically controlled processes, assuming water to act as sublimation catalyst. A preliminary optical and structural characterisation…

Soft Nanoonions: A Dynamic Overview onto Catanionic Vesicles Temperature-Driven Transition.

2020

Catanionic vesicles are emerging interesting structures for bioapplications. They self-generate by a pairing of oppositely charged ionic surfactants that assemble into hollow structures. Specifically, the anionic-cationic surfactant pair assumes a double-tailed zwitterionic behavior. In this work, the multilamellar-to-unilamellar thermal transition of several mixed aqueous systems, with a slight excess of the anionic one, were investigated. Interestingly, it was found that the anionic counterion underwent a dissociation as a consequence of a temperature increase, leading to the mentioned thermal transition. The present work proposed the spectroscopic techniques, specifically multinuclear NM…

Microemulsions: Phase transitions and their dynamics

2007

By differential scanning microcalorimetry we investigate temperature-induced phase transitions and their dynamics in mixtures of water, oil and a non-ionic surfactant. Special emphasis is on an investigation of the transition from a lamellar to a microemulsion phase and on the emulsification failure. The first-order phase transition from a lamellar to a microemulsion phase leads to heat changes up to 1k BT per surfactant molecule. These large values for the latent heat are quantitatively described by an interfacial model which takes into account the temperature dependence of the spontaneous curvature.

PTPlot: a tool for exploring the gravitational wave power spectrum from first-order phase transitions

2022

PTPlot is a tool for exploring the gravitational wave power spectrum from first-order phase transitions, and evaluating the likelihood of detecting a signal with the LISA mission. The results plotted by this tool are based on the paper Detecting gravitational waves from cosmological phase transitions with LISA: an update, arXiv:1910.13125, which has been published in JCAP. Please cite both that paper, and this Zenodo deposit, if possible. The source for PTPlot is available at https://bitbucket.org/dweir/ptplot.

Stochastic approach to highway traffic

2004

We analyze the characteristic features of jam formation on a circular one-lane road. We have applied an optimal velocity model including stochastic noise, where cars are treated as moving and interacting particles. The motion of N cars is described by the system of 2 N stochastic differential equations with multiplicative white noise. Our system of cars behaves in qualitatively different ways depending on the values of control parameters c (dimensionless density), b (sensitivity parameter characterising the fastness of relaxation), and α (dimensionless noise intensity). In analogy to the gas-liquid phase transition in supersaturated vapour at low enough temperatures, we observe three differ…

Heterobimetallicd—f Metal Complexes as Potential Single-Source Precursors for MOCVD: Structure and Thermodynamic Study of the Sublimation of [Ni(sale…

1998

Heterobimetallic [Ni(salen)Ln(hfa)3] species [H2salen and Hhfa being N,N′-ethylenebis(salicylideneimine) and hexa-fluoroacetylacetone respectively], where Ni(salen) acts as a neutral chelating ligand towards LnIII, form a series of isostructural compounds for Ln = YIII and any lanthanideIII cation from La to Yb. They are also isostructural with some of the [Cu(salen)Ln(hfa)3] compounds. They sublime without decomposition under vacuum which makes them potential single-source precursors in MOCVD. Sublimation, thermal behaviour, pressure and composition of the vapour phase versus temperature have been studied for the yttrium derivative, by means of thermal analyses, and mass spectrometry using…

A Route to Grow Oxide Nanostructures Based on Metal Displacement Deposition: Lanthanides Oxy/Hydroxides Characterization

2012

Novel structural phases and the properties of LaX (X = P, As) under high pressure: first-principles study

2020

The particle swarm optimization algorithm and density functional theory (DFT) are extensively performed to determine the structures, phase transition, mechanical stability, electronic structures, and thermodynamic properties of lanthanide phosphates (LaP and LaAs) in the pressure range of 0 to 100 GPa. Two novel high-pressure structures of LaP and LaAs are first reported here. It is found that LaX (X = P, As) undergo a phase transition from NaCl-type structure (Fm3m) to CsCl-type structure (P4/mmm) at 19.04 GPa and 17.22 GPa, respectively. With the elevation of the pressure, C2/m-LaP and Imma-LaAs are the most stable structures up to 70.08 GPa and 85.53 GPa, respectively. Finally, the analy…

The role of connectivity in the properties of sedimented materials

2003

Effective-medium theories for both random packings of elastic discs and mats of randomly sedimented elastic fibers can be constructed such that the effective material stiffness depends on the stiffness and geometry of the constituents of the material, and the number density of contacts. It is demonstrated that the number density of contacts together with the geometry of the constituents also determine the porosity of these materials. The simplicity and similar structure of the effective-medium estimates for the properties of these two qualitatively different materials indicate that the number density of contacts may play a similar role in an appropriate effective-medium description of a lar…