Search results for "Phase Transition"
showing 10 items of 1281 documents
Chapter III Phase transitions at surfaces
1995
Abstract The statistical mechanics of phase transitions is briefly reviewed, with an emphasis on surfaces. Flat surfaces of crystals may act as a substrate for adsorption of two-dimensional (d=2) monolayers and multilayers, offering thus the possibility to study phase transitions in restricted dimensionality. Critical phenomena for special universality classes can thus be investigated which have no counterpart in d=3. Also phase transitions can occur that are in a sense “in between” different dimensionalities (e.g., multilayer adsorption and wetting phenomena are transitions in between two and three dimensions, while adsorption of monolayers on stepped surfaces allows phenomena in between o…
Polymer mixtures in confined geometries: Model systems to explore phase transitions
2005
While binary (A,B) symmetric polymer mixtures ind = 3 dimensions have an unmixing critical point that belongs to the 3d Ising universality class and crosses over to mean field behavior for very long chains, the critical behavior of mixtures confined into thin film geometry falls in the 2d Ising class irrespective of chain length. The critical temperature always scales linearly with chain length, except for strictly two-dimensional chains confined to a plane, for whichT; c ∝N; 5/8 (this unusual exponent describes the fractal contact line between segregated chains in dense melts in two spatial dimensions, d = 2). When the walls of the thin film are not neutral, but preferentially attract one …
Screening Order–Disorder Phase Transition in 1-D Perovskite-like Crystals of [Azetidinium]CdBr3
2022
In search for new polar compounds, we have synthesized the organic–inorganic hybrid [C3H8N]CdBr3 (AZECdBr3). This is a bromide analog of [C3H8N]CdCl3, which has been studied by us earlier. The chloride compound exhibited ferroelectric properties, so it seemed reasonable to check the properties of AZECdBr3. The AZECdBr3 crystals reveal three phase transitions (PTs): the first one (I → II) of the second order at 437.0/436.7 K (heating/cooling), the next (also of the second order) at 231.0 K (II → III), and the last one (classified as a first-order transition) at 197.0/194.0 K (III → IV). On the basis of the DSC data, the thermodynamic parameters have been estimated. The single-crystal X-ray m…
Dielectric-Optical Switches: Photoluminescent, EPR, and Magnetic Studies on Organic–Inorganic Hybrid (azetidinium)2MnBr4
2022
A new organic–inorganic hybrid, AZEMnBr, has been synthesized and characterized. The thermal differential scanning calorimetry, differential thermal analysis, and thermogravimetric analyses indicate one structural phase transition (PT) at 346 and 349 K, on cooling and heating, respectively. AZEMnBr crystallizes at 365 K in the orthorhombic, Pnma, structure, which transforms to monoclinic P21/n at 200 K. Due to the X-ray diffraction studies, the anionic MnBr42– moiety is discrete. The azetidinium cations show dynamical disorder in the high-temperature phase. In the proposed structural PT, the mechanism is classified as an order–disorder type. The structural changes affect the dielectric resp…
Photoelectrical Properties of the SBN Relaxor Ceramics in the Range of the Broad Phase Transition
2014
AbstractA study of the effects of white light on photocurrent kinetics and the low and infra-low frequency relaxation of polarization in the barium-strontium niobate SBN‑75 ceramics is reported. It is found that at a low intensity illumination in the range of the relaxor phase the space charge is mainly responsible for manifestation of photo-electrical properties of SBN-75 ceramics.
Effect of impurities on Raman and photoluminescence spectra of AlN bulk crystals
2003
ABSTRACTRaman scattering and photoluminescence (PL) spectroscopy with sub-bandgap excitation has been applied to explore tracing of common impurities (in particular of oxygen) in AlN. Bulk AlN crystals grown by the high temperature sublimation method were studied. PL bands have been observed at around 375 nm and at 560–660 nm and have been attributed to oxygen and to nitrogen vacancy/aluminium excess defects, respectively. The 375 nm UV PL band was found to shift with oxygen concentration. Micro-Raman spectra of the bulk AlN samples were measured in different polarisations. Besides normal Raman modes of AlN the presence of additional vibrational modes was detected. The modes were discussed …
Fouling mechanism elucidation in membrane bioreactors by bespoke physical cleaning
2018
Abstract Cake layer deposition on a membrane surface can determine both external and internal membrane fouling through negatively affecting the total filtration resistance while exerting a positive effect as a pre-filter. Membranes are usually subjected to a periodic cake layer removal through routine physical cleaning, specifically permeate backwashing of hollow fiber membranes, or enhanced cleaning through, for example, chemically-enhanced backwashing. Physical cake layer removal is crucial for sustaining permeability, yet the effect of different physical cleaning modes remains poorly evaluated. The present work attempts to analyze physical cake layer removal through the application of sp…
From Continuous to Discontinuous Transitions in Social Diffusion
2018
Models of social diffusion reflect processes of how new products, ideas or behaviors are adopted in a population. These models typically lead to a continuous or a discontinuous phase transition of the number of adopters as a function of a control parameter. We explore a simple model of social adoption where the agents can be in two states, either adopters or non-adopters, and can switch between these two states interacting with other agents through a network. The probability of an agent to switch from non-adopter to adopter depends on the number of adopters in her network neighborhood, the adoption threshold $T$ and the adoption coefficient $a$, two parameters defining a Hill function. In c…
Local Quench, Majorana Zero Modes, and Disturbance Propagation in the Ising chain
2016
We study the generation and propagation of local perturbations in a quantum many-body spin system. In particular, we study the Ising model in transverse field in the presence of a local field defect at one edge. This system possesses a rich phase diagram with different regions characterized by the presence of one or two Majorana zero modes. We show that their localized character {\it i}) enables a characterization of the Ising phase transition through a local-only measurement performed on the edge spin, and {\it ii}) strongly affects the propagation of quasiparticles emitted after the sudden removal of the defect, so that the dynamics of the local magnetization show clear deviations from a …
Contrail Formation: Analysis of Sublimation Mechanisms
2018
We study losses of ice crystals in a persistent, soot-rich contra i l in the wake behind a medium-sized aircraft at cru i se. Constrain i n g a model covering ice nucleation, growth, and subl i m a t i o n phases with a n aircraft data set, we track the subl i m a t i o n history over two minutes of cont r a i l age and rela t e ice crystal numbers to the number of soot particles emitted by th e aircraft engines.