Search results for "Phengite"
showing 10 items of 12 documents
METAMORPHIC EVOLUTION OF SPESSARTINE QUARTZITES (COTICULES) IN THE HIGH-PRESSURE, LOW-TEMPERATURE COMPLEX AT BAHIA MANSA, COASTAL CORDILLERA OF SOUTH…
2001
Lenses of spessartine quartzites (coticules) are associated with greenschist intercalations in coastal exposures at Bahia Mansa within the mainly metapsammopelitic Western Series, which forms most of the basement in the Coastal Cordillera of central to southern Chile. The chemical compositions of the coticules can be explained by protoliths formed from ferriferous and manganiferous hydrothermal precipitates mixed with aluminous alteration-derived material on top of oceanic crust. The peak conditions of metamorphism were calculated with multivariant reactions: 270–370 °C, 6–8 kbar. A retrograde P–T evolution was marked by decompression to 2 kbar during cooling below 300°C, influx of an exter…
Miocene high-pressure metamorphism in the Cyclades and Crete, Aegean Sea, Greece: Evidence for large-magnitude displacement on the Cretan detachment
2001
The Cyclades in the backarc region of the present Hellenic subduction zone are known for widespread Late Cretaceous to Eocene high-pressure metamorphism in the Cycladic blueschist unit. We report 40 Ar/ 39 Ar and Rb/Sr phengite ages of 24–21 Ma for high- pressure metamorphism (8–10 kbar, 350–400 °C) in the lowest tectonic unit in the Cyclades, the Basal unit, which structurally underlies the Cycladic blueschist unit. The Basal unit is correlated with the Tripolitza unit of the External Hellenides in the forearc region of the Hellenic subduction zone. The Tripolitza unit is unmetamorphosed on Crete, where it is separated from the underlying high-pressure (8–10 kbar, 300–400 °C) Plattenkalk a…
Characterization of an early metamorphic stage through inclusions in zircon of a diamondiferous quartzofeldspathic rock from the Erzgebirge, Germany
2003
About 1000 zircon grains from a diamondiferous quartzofeldspathic rock of the Saxonian Erzgebirge were investigated for inclusions using optical microscopy and confocal laser-Raman spectroscopy. Cathodoluminescence imagery was applied to characterize the growth zone of zircon where the inclusions occurred. The most abundant inclusion minerals are microdiamonds. Coesite was not detected. However, garnet and jadeite occur as rare inclusions in zircon cores where diamonds are lacking. Jadeite was detected for the first time in quartzofeldspathic rocks from the crystalline complex of the Erzgebirge. The compositions of the pristine garnets in the zircons are similar to those of core areas of mi…
Maximum entropy method : an unconventional approach to explore observables related to the electron density in phengites
2009
The maximum entropy method (MEM) is used here to get an insight into the electron density [rho(r)] of phengites 2M (1) and 3T, paying special attention to the M1-formally empty site and charge distribution. Room temperature single crystal X-ray diffraction data have been used as experimental input for MEM. The results obtained by MEM have been compared with those from conventional structure refinement which, in turn, has provided the prior-electron density to start the entropy maximization process. MEM reveals a comparatively non-committal approach, able to produce information related to the M1-site fractional occupancy, and yields results consistent with those from the difference Fourier s…
Time of formation and peak of Variscan HP-HT metamorphism of quartz-feldspar rocks in the central Erzgebirge, Saxony, Germany
1998
The Variscan Erzgebirge represents an antiform with a core of gneisses and mica schists, surrounded by a phyllitic mantle. The Gneiss-Eclogite Unit (GEU), in the central part, is a composite tectonometamorphic assemblage characterized by a HP-HT imprint and comprises migmatitic para- and orthogneisses, HT mylonites, HP granulites, eclogites and garnet peridotites. It is tectonically sandwiched between two major units with distinctly lower PT histories. The GEU experienced a characteristic “kinked” retrograde PT path after HP-HT equilibration with: (1) strong near-isothermal decompression at high temperatures; (2) extensive re-equilibration at medium pressures, followed (3) by rapid cooling …
Timing of subduction and exhumation in a subduction channel: Evidence from slab melts from La Corea Mélange (eastern Cuba)
2011
article i nfo High pressure igneous rocks (tonalites), generated by partial melting of subducted basaltic rocks accreted to the mantle wedge, are present in the La Corea serpentinite-matrix melange (eastern Cuba) as centimeter- to meter-sized blocks and as concordant to crosscutting veins within high-pressure parent amphibolite blocks. The slab melts have adakitic signatures, in agreement with formation after partial melting of metabasite. Thermobarometric calculations indicate 620-680 °C and 13-15 kbar during crystallization of tonalites and down to 250-300 °C, 6 kbar during retrogression, indicating counter-clockwise P-T paths (hot subduction- cool exhumation). Free water required for mel…
Hydrothermal origin and age of jadeitites from Sierra del Convento Mélange (Eastern Cuba)
2012
Jadeitite (jadeite jade) from Sierra del Convento (eastern Cuba) occurs in a subduction-related serpentinite-matrix melange associated with a variety of high-pressure tectonic blocks including garnet-amphibolites and related anatectic trondhjemites. The eastern Cuban jadeitite is massive and characterized by rare quartz inclusions and omphacite exsolution in jadeite crystals, as well as replacement or infilling by omphacite. Minor minerals include epidote, biotite, albite, phengite, titanite, rutile, zircon, and apatite. Oscillatory zoning in jadeite crystals and zircon ages suggest hydrothermal crystallization in veins formed in serpentinized peridotite, probably of the mantle wedge. Al-Na…
The fate of subducted oceanic slabs in the shallow mantle: Insights from boron isotopes and light element composition of metasomatized blueschists fr…
2012
Abstract Serpentine muds from South Chamorro Seamount (SCS), drilled during ODP Leg 195 at Site 1200 contain metamafic clasts that experienced blueschist-facies metamorphism (including the critical mineral assemblage pumpellyite – Na-amphibole – epidote). These schists represent fragments from the actual slab–mantle interface at ~ 27 km depth. Their heterogeneous lithology with a metasomatic character indicates significant mobility of major elements in the Mariana forearc, a region of melange formation as it can also be observed in onland exposures such as the Catalina Schist. As the Mariana forearc blueschists show no late stage alteration they permit the direct study of material transfer …
40Ar/39Ar laser probe dating of detrital white micas from Cretaceous sedimentary rocks of the Eastern Alps: Evidence for Variscan high-pressure metam…
1997
The detritus of Cretaceous synorogenic sandstones of the northern margin of the Austroalpine microplate contains evidence for a high-pressure metamorphic basement and obducted oceanic crust exposed in early Alpine time. 40 Ar/ 39 Ar laser-probe data of detrital white micas give excellent plateau ages in a narrow range from 320 to 360 Ma. White micas cover the whole range from muscovites up to phengites (3.04 to 3.48 Si per formula unit). Heavy mineral spectra contain chrome spinel, glaucophane, chloritoid, epidote, and garnet, as well as zircon, tourmaline, and rutile. Glaucophane, chloritoid, and phengite correlate in their abundance. These minerals also correlate positively with the stabl…
Computational study of defects in ideal phengite
2009
Phengite is the name of a series designating the “potassic dioctahedral micas between, or close to, the joins muscovite-aluminoceladonite and muscovite-celadonite” (Rieder et al. 1998). These micas play a important role in most petrogenetic reactions occurring in high-pressure (HP) metamorphic environments; they are useful geothermobarometers and participate in reactions as H2O carriers in the subduction zone. In this work we have employed atomistic simulations techniques to model defects, evaluate the most stable defect species and determine the most likely diffusion mechanism in crystals. We have calculated the defect formation energies for vacancies, impurities and interstitials, Frenkel…