Search results for "Phosphole"
showing 3 items of 23 documents
CCDC 880668: Experimental Crystal Structure Determination
2012
Related Article: A.L.Brazeau, M.M.Hanninen, H.M.Tuononen, N.D.Jones, P.J.Ragogna|2012|J.Am.Chem.Soc.|134|5398|doi:10.1021/ja300587z
CCDC 734967: Experimental Crystal Structure Determination
2010
Related Article: B.R.Aluri, S.Burck, D.Gudat, M.Niemeyer, O.Holloczki, L.Nyulaszi, P.G.Jones, J.Heinicke|2009|Chem.-Eur.J.|15|12263|doi:10.1002/chem.200901753
Redox-induced coordination isomerization of a phosphoniobenzophospholide.
2003
1-Triphenylphosphoniobenzo[c]phospholide 1 reacts with [M(CO)(5)Br] (M = Mn, Re) and [Mn(CO)(3)(naphthalene)][BF(4)] to give complexes cis-[M(CO)(4)(1)Br] (5 a,b) and [Mn(CO)(3)(1)][BF(4)] (6 a[BF(4)]), respectively, featuring eta(1)(P)- and eta(5)(pi)-coordination of the phosphole ring. The corresponding reactions with [M(2)(CO)(10)] proceed with conservation of the metal-metal bond and yield, depending on the reaction temperature, dinuclear complexes [M(2)(CO)(8)(1)] (M=Mn, 7 a) or [M(2)(CO)(6)(1)(2)] (M=Mn, Re, 8 a,b) with mu(2)-bridging eta(1)(P):eta(2)(Pdbond;C) coordination of the phosphole moiety. All complexes formed were characterized by spectroscopic data; 5 b, 6 a[BF(4)], and 8 a…