Search results for "Phosphorus"
showing 10 items of 431 documents
3.17 Synthetically Derived Auxiliaries: Phosphorus Derivatives
2012
This chapter aims to give an overall view of chiral-pool based asymmetric synthesis of organophosphorus compounds more particularly bearing the chirality on the phosphorus atom (P-stereogenic). The enantiomerically pure organophosphorus compounds can be obtained either by resolution of the racemate or by stereoselective synthesis using particularly ephedrine or sparteine as the main chiral auxiliaries and borane as a P(III)-protecting group.
Synthesis of a New C3-Symmetric Tripodal P4-Tetradentate Ligand and Its Application to the Formation of Chiral Metal Complexes
2010
A novel C3-symmetric tetradentate tripodal ligand with phosphorus as coordinating atoms has been synthesized in good yields. Its coordination ability through the four phosphorus atoms, three at the...
Effects of different infant formula components on calcium dialysability
1999
The in vitro methods proposed for estimating calcium bioavailability can be useful in studying the effect of dietetic factors. The aim of our work was to study the possible influence of different infant formula components – calcium, phosphorus, lactose, citric acid, ascorbic acid and proteins – on calcium bioavailability, considering dialysability to be an estimate of bioavailability. The 1981 method of Miller et al. with slight modifications (concerted action no 10 – FLAIR project) was applied to 18 commercial infant formulas of six different types: adapted, follow-up, preterm, hydrolysates, lactose-free and soy-based. Significant positive linear correlations between the amount of calcium …
Paleolimnological evidence of environmental changes in seven subtropical reservoirs based on metals, nutrients, and sedimentation rates
2021
Made available in DSpace on 2022-04-28T19:40:54Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-11-01 Paleolimnological research can shed light on a broad range of environmental concerns; however, such studies are scarce in reservoirs. To address this lack of knowledge, a paleolimnological investigation was conducted to determine historical changes in sedimentation rates (SR), using 210Pb geochronology, and concentrations of nutrients and metals (Cr, Cu, Ni, Pb, Zn, Al, Mn, Fe) in seven subtropical reservoirs (São Paulo, Brazil). Sediment cores were collected in the dam areas. Increasing SR was observed in all reservoirs and was mainly attributed to eutrophication and changes in land…
Trace element data covering 96-7 ka BP from stalagmite CM (Santo Tomas Cave, Cuba)
2020
We present a new speleothem trace element and stable isotope record, which extends previous paleoclimate evidence from Cuban speleothems to the last 96 ka. Stable isotope samples were micromilled at a resolution of 0.10-0.33mm, and measured using an IRMS equipped with a Gasbench. Line scans of Element/Calcium ratios of the speleothem were measured by laser ablation ICPMS and were reduced to the resolution of the stable isotope records.
Phosphorylated micro- vs. nano-cellulose: a comparative study on their surface functionalisation, growth of titanium-oxo-phosphate clusters and remov…
2019
Controlled cellulose disassembly affords many variants including amorphous micro-sized cellulose crystals (MCC) and cellulose nano-sized crystals (CNC), which have emerged recently as green and sustainable nanomaterials. Unfortunately, their lower reactivity and thermal and chemical instability constitute an impediment for multifaceted nanoscience and nanotechnology usage. Herein, MCC and CNC are functionalised using two phosphorus derivatives (phosphoryl chloride and hexachlorocyclotriphosphazene), under acid-free, urea-free and corrosive-free, gentle experimental conditions. Notably, CNC can accommodate more phosphorus species compared to MCC, with the bulky phosphazene precursor being le…
Synthesis and properties of new phosphorus-functionalized bithiophene materials
2003
The synthesis and reactivity of the novel dithieno[3,2-b:2',3'-d]-phosphole system and its potential use in polymeric sensory materials was investigated. Due to the nucleophilic nature of the phosphorus atom, these materials were found to be easily tunable. Classical reactions at the phosphorus center were performed to modify the electronic structure of the system and the corresponding changes were detected by UV/Vis and fluorescence spectroscopy. Depending on the oxidation state of the central phosphorus atom or its substitution pattern, the dithieno[3,2-b:2',3'-d]-phospholes show varying wavelengths for absorption and emission allowing to distinguish between different compounds by means o…
Lifetime measurements in mirror nuclei31S and31P: A test for isospin mixing
2011
Using the 20Ne + 12C fusion-evaporation reaction at E20Ne = 33 MeV and the multidetector array GASP in conjuction with the EUCLIDES charged particle detector, angular correlations of coincident pairs of γ transitions and lifetimes in mirror nuclei 31S and 31P have been measured at the Piave-Alpi accelerator of the Laboratori Nazionali di Legnaro. A comparison of the determined B(E1) strengths of the analog mirror 7/2− → 5/2+ transitions indicates the presence of a violation of isospin symmetry.
Reevaluation of theP30(p,γ)S31astrophysical reaction rate from a study of theT=1/2mirror nuclei,S31andP31
2006
The $^{30}\mathrm{P}$($p,\ensuremath{\gamma}$)$^{31}\mathrm{S}$ reaction rate is expected to be the principal determinant for the endpoint of nucleosynthesis in classical novae. To date, the reaction rate has only been estimated through Hauser-Feschbach calculations and is unmeasured experimentally. This paper aims to remedy this situation. Excited states in $^{31}\mathrm{S}$ and $^{31}\mathrm{P}$ were populated in the $^{12}\mathrm{C}$($^{20}\mathrm{Ne}$,$n$) and $^{12}\mathrm{C}$($^{20}\mathrm{Ne}$,$p$) reactions, respectively, at a beam energy of 32 MeV, and their resulting $\ensuremath{\gamma}$decay was detected with the Gammasphere array. Around half the relevant proton unbound states …
Mirror energy differences in theA=31mirror nuclei,S31andP31, and their significance in electromagnetic spin-orbit splitting
2005
Excited states in $^{31}\mathrm{S}$ and $^{31}\mathrm{P}$ were populated in the $^{12}\mathrm{C}$($^{20}\mathrm{Ne}$,n) and $^{12}\mathrm{C}$($^{20}\mathrm{Ne}$,p) reactions, respectively, at a beam energy of 32 MeV. High spin states of positive and negative parity have been observed in $^{31}\mathrm{S}$ for the first time, and the yrast scheme of $^{31}\mathrm{P}$ has been extended. Large mirror energy differences between the first $9/{2}^{\ensuremath{-}}$ and $13/{2}^{\ensuremath{-}}$ states were observed, but only small differences for the first $7/{2}^{\ensuremath{-}}$ and $11/{2}^{\ensuremath{-}}$ levels. The significance of these observations is discussed in relation to the electromag…