Search results for "Photo"

Photocatalytic degradation of 4-nitrophenol in aqueous suspension by Using Functionalized Porphyrin-TiO2 Photocatalysis Under Visible Irradiation

2007

Hf02 based RRAM: from materials engineering to integrated modules

2015

10 mars 2015; International audience; no abstract

A novel approach for parameters determination in four lumped PV parametric model with operative range evaluations

2013

The paper presents a novel numerical approach for the parameters determination of crystalline silicon PV models four lumped parameters equivalent circuit. The novel approach basically deals with a new method, alternative to the iterative one known in literature, to calculate the series resistance. Particularly, it allows the evaluation of the lumped parameters on the basis of the manufacturer’s datasheet. The new approach has been validated both in the Maximum Power Point (MPP) and close to it by comparing values and curves obtained by means of the model implementation in Matlab/Simulink environment with those related to some five parameters models and manufacturer curves. Results show that…

Correction: Phenothiazine-based dyes for efficient dye-sensitized solar cells

2016

Correction for ‘Phenothiazine-based dyes for efficient dye-sensitized solar cells’ by Zu-Sheng Huang et al., J. Mater. Chem. C, 2016, 4, 2404–2426.

ISomerization of xylene: MINDO/3 study of the cyclization of benzenium cation into bicyclo[3.1.0]hexenyl cation

1989

Abstract A MINDO/3 study of thermal electrocyclic closing of the benzenium cation to form a bicyclo[3.1.0]hexenyl cation is presented. The calculated mechanism discusses the possibility of cyclization of xylenium cations on a silica catalyst or in superacid media. The structure and energy of the transition state, the enthalpies of isomerization and barriers of activation were calculated for the following processes: isomerization of 2,6-dimethylbenzenium cation into 2,6-dimethylbicyclo[3.1.0]hexenyl cation, isomerization of 2,4-dimethylbenzenium cation into 2,4-dimethylbicyclo[3.1.0]-hexenyl cation, and isomerization of benzenium cation into bicyclo[3.1.0]-hexenyl cation. Equilibrium and kin…

Photokinetic examination of (Z,E,E)-4,4′-distyrylazobenzene

1995

Abstract 4,4′-Distyrylazobenzenes demonstrate a photokinetic equilibrium and a superimposed thermal backward reaction in which the absorption coefficient of one of the partners in the equilibrium is principally unknown. Using the dependence of the photostationary state on the irradiation intensity, the photochemical quantum yields ϕ 1 A and ϕ 2 B were determined, as well as the thermal rate constant k , as a function of the irradiation and observation wavelengths. Experimental difficulties and the wavelength dependence of ϕ 1 A and ϕ 2 B are discussed.

Regge phenomenology in π0 and η photoproduction

2017

The $\ensuremath{\gamma}N\ensuremath{\rightarrow}{\ensuremath{\pi}}^{0}N$ and $\ensuremath{\gamma}N\ensuremath{\rightarrow}\ensuremath{\eta}N$ reactions at photon beam energies above 4 GeV are investigated within Regge models. The models include $t$-channel exchanges of vector ($\ensuremath{\rho}$ and $\ensuremath{\omega}$) and axial-vector (${b}_{1}$ and ${h}_{1}$) mesons. Moreover, Regge cuts of $\ensuremath{\rho}\mathbb{P},\phantom{\rule{0.28em}{0ex}}\ensuremath{\rho}{f}_{2},\phantom{\rule{0.28em}{0ex}}\ensuremath{\omega}\mathbb{P}$, and $\ensuremath{\omega}{f}_{2}$ are investigated. A good description of differential cross sections and polarization observables at photon beam energies fr…

THE KINETICS AND MECHANISM OF THE REACTION OF ONIUM CYCLOPENTADIENYLIDES WITH TETRAHALO-p-BENZOQUINONES

1989

Abstract The reaction of triphenylphosphonium cyclopentadienylide (1) with halogen-substituted p-benzoquinones (4) is shown to give a new class of dipolar (zwitterionic) dyes (5) containing phosphorus. The general structure of these molecules has been investigated by a combination of mass spectrometry and multinuclear (7H, 13C and 31P) nmr using the specialist techniques of DEFT spectroscopy, homonuclear (COSY) and heteronuclear 2-D nmr. In addition, stopped-flow (uv/visible) techniques have been used to study the kinetics of the reactions and hence demonstrate that the rate-limiting step is nucleophilic addition of the ylid nucleophile to the quinone, followed by a rapid loss of halide ion…

Photoelectrochemical study of passive films on stainless steel in neutral solutions

1991

Abstract Passive films formed on AISI 304 stainless steel in neutral solutions are studied using photoelectrochemical technique. Photocurrents were investigated as a function of the wavelength of the incident light, the electrode potential and the time. The results of the measurements together with capacity measurements indicate that the passive film on AISI 304 shows characteristics of a highly doped amorphous or highly disordered n-type semiconductor. The potential dependence of the optical gap values and of the photocurrent transients can be interpreted assuming that the passive film is an iron-chromium oxide solid solution.

Designed surface modes propagating along hyperbolic metamaterials

2013

We report on surface-wave propagation (SWP) that occurs in semi-infinite hyperbolic metamaterials whose optical axis is set in the interface plane. In practice it is implemented by a multi-layered metal-dielectric nanostructure that is cut normally to the layers. Our theoretical analysis shows that various conditions can be designed enabling distinct regimes of SWP. We concluded that hybridization of SWP polarization leads to tighter confinement near the interface as compared with conventional surface plasmon polaritons. By using the finite-element method (FEM), we demonstrate that the fields are enhanced on the walls of metallic films, and thus minimizing significantly its presence inside …