Search results for "Photoluminescence"
showing 10 items of 811 documents
Theoretical Prediction and Experimental Confirmation of Charge Transfer Vibronic Excitons and Their Phase in ABO3 Perovskite Crystals
2002
AbstractThe current theoretical and experimental knowledge of new polaronic-type excitons in ferroelectric oxides - charge transfer vibronic excitons (CTVE) is discussed. It is shown that quantum chemical Hartree-Fock-type calculations using a semiempirical Intermediate Neglect of Differential Overlap (INDO) method (modified for ionic/partly ionic solids) as well as photoluminescence studies in ferroelectric oxygen-octahedral perovskites confirm the CTVE existence. Our INDO calculations for KTaO3 and KNbO3 have demonstrated that the triplet exciton is a triad centre containing one active O atom and two Ta atoms sitting on the opposite sites from this O atom. The total energy of a system is …
Luminescence center excited state absorption in tungstates
2001
The excited state absorption of intrinsic luminescence center (self-trapped exciton) in tungstates (CaWO4, ZnWO4, PbWO4 and CdWO4) was studied. The transient absorption and luminescence spectra, decay kinetics and lifetime dependencies on temperature have been measured. The model of self-trapped exciton and nature of observed absorption bands were discussed.
Room temperature polariton luminescence from a GaN∕AlGaN quantum well microcavity
2006
The authors report on the demonstration of strong light-matter coupling at room temperature using a crack-free UV microcavity containing GaN/AlGaN quantum wells (QWs). Lattice-matched AlInN/AlGaN distributed Bragg reflectors (DBRs) with a maximum peak reflectivity of 99.5% and SiO2/Si3N4 DBRs were used to form high finesse hybrid microcavities. State-of-the-art GaN/Al0.2Ga0.8N QWs emitting at 3.62 eV with a linewidth of 45 meV at 300 K were inserted in these structures. For a 3 lambda/2 microcavity containing six QWs, the interaction between cavity photons and QW excitons is sufficiently large to reach the strong coupling regime. A polariton luminescence is observed with a vacuum field Rabi…
Random population model to explain the recombination dynamics in single InAs/GaAs quantum dots under selective optical pumping
2011
18 páginas, 3 tablas, 9 figuras.-- et al.
Formation of self-trapped excitons through stimulated recombination of radiation-induced primary defects in alkali halides
1998
Abstract A self-trapped exciton formation through photostimulated recombination of an F and an H center — the exciton-created primary defect pair, is proposed and experimentally examined in alkali halides at low temperatures.
Environment assisted photoconversion of luminescent surface defects in SiO 2 nanoparticles
2017
Abstract Time-resolved photoluminescence investigation on SiO 2 nanoparticles was carried out in controlled atmosphere, with the aim to discern the effects induced on the typical blue luminescence band by high power UV Nd:YAG laser photons (4.66 eV) and by some selected molecular species of the air (O 2 , N 2 , CO 2 , H 2 O). These factors ultimately determine both the brightness and photostability of the emitting defect, so as to limit the unique and attracting potentialities offered by this system in many applicative fields. Here it is highlighted that the effects due to photons and molecules, singularly considered, are not additive, the radiation being more dramatic in reducing the emiss…
Enhancement of the Lifetime of Metastable States in Er-Doped Si Nanocrystals by External Colored Noise
2015
The changes in the lifetime of a metastable energy level in Er-doped Si nanocrystals in the presence of an external source of colored noise are analyzed for different values of noise intensity and correlation time. Exciton dynamics is simulated by a set of phenomenological rate equations which take into account all the possible phenomena inherent in the energy states of Si nanocrystals and Er^{3+} ions in the host material of Si oxide. Electronic deexcitation is studied by examining the decay of the initial population of the Er atoms in the first excitation level 4I_{13/2} through fluorescence and cooperative energy transfer upconversion. Our results show that the deexcitation process of th…
Interplay between spin-crossover and luminescence in a multifunctional single crystal iron( ii ) complex: towards a new generation of molecular senso…
2019
Multifunctional mononuclear iron( ) complex coordinated with six phosphorescent ligands exhibiting correlated spin-crossover transition and enhanced fluorescence.
Different regimes of electronic coupling and their influence on exciton recombination in vertically stacked InAs/InP quantum wires
2006
8 páginas, 8 figuras.
WS2/MoS2 Heterostructures via Thermal Treatment of MoS2 Layers Electrostatically Functionalized with W3S4 Molecular Clusters
2020
The preparation of 2D stacked layers that combine flakes of different nature, gives rise to countless number of heterostructures where new band alignments, defined at the interfaces, control the electronic properties of the system. Among the large family of 2D/2D heterostructures, the one formed by the combination of the most common semiconducting transition metal dichalcogenides WS2/MoS2, has awaken great interest due to its photovoltaic and photoelectrochemical properties. Solution as well as dry physical methods have been developed to optimize the synthesis of these heterostructures. Here a suspension of negatively charged MoS2 flakes is mixed with a methanolic solution of a cationic W3S…