Search results for "Photos"
showing 10 items of 701 documents
Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by RuII photocatalysis
2014
The preparation of [FeIV(O)(MePy2tacn)]2+ (2, MePy2tacn = N-methyl-N,N-bis(2-picolyl)-1,4,7-triazacyclononane) by reaction of [FeII(MePy2tacn)(solvent)]2+ (1) and PhIO in CH3CN and its full characterization are described. This compound can also be prepared photochemically from its iron(II) precursor by irradiation at 447 nm in the presence of catalytic amounts of [Ru II(bpy)3]2+ as photosensitizer and a sacrificial electron acceptor (Na2S2O8). Remarkably, the rate of the reaction of the photochemically prepared compound 2 toward sulfides increases 150-fold under irradiation, and 2 is partially regenerated after the sulfide has been consumed; hence, the process can be repeated several times.…
Compared regimes of NDVI and Rainfall in semi-arid regions of Africa
2006
International audience; Bi-monthly normalized difference vegetation index (NDVI) at an 8km spatial resolution from the advanced very high resolution radiometers (AVHRR) was used from 1981 to 1995 to analyse the vegetation response to rainfall supply in semi-arid regions of Africa. Within the 200-600 mm annual rainfall belt, for which the apparent NDVI response to rainfall was the strongest, three regions were selected which exhibited different patterns in their NDVI regimes and/or relationships with rainfall. The regions, located in western, southern and eastern Africa, were split into coherent sub-regions in terms of mean regime of photosynthetic activity through a cluster analysis. Overal…
Optical counterpart to Swift J0243.6+6124
2020
Context. Swift J0243.6+6124 is a unique system. It is the first and only ultra-luminous X-ray source in our Galaxy. It is the first and only high-mass Be X-ray pulsar showing radio jet emission. It was discovered during a giant X-ray outburst in October 2017. While there are numerous studies in the X-ray band, very little is known about the optical counterpart. Aims. Our aim is to characterize the variability timescales in the optical and infrared bands in order to understand the nature of this intriguing system. Methods. We performed optical spectroscopic observations to determine the spectral type. Long-term photometric light curves together with the equivalent width of the Hα line were u…
A New Algorithm for the Retrieval of Sun Induced Chlorophyll Fluorescence of Water Bodies Exploiting the Detailed Spectral Shape of Water-Leaving Rad…
2021
Sun induced chlorophyll fluorescence (SICF) emitted by phytoplankton provides considerable insights into the vital role of the carbon productivity of the earth’s aquatic ecosystems. However, the SICF signal leaving a water body is highly affected by the high spectral variability of its optically active constituents. To disentangle the SICF emission from the water-leaving radiance, a new high spectral resolution retrieval algorithm is presented, which significantly improves the fluorescence line height (FLH) method commonly used so far. The proposed algorithm retrieves the reflectance without SICF contribution by the extrapolation of the reflectance from the adjacent regions. Then, the SICF …
Pigment organization and energy transfer dynamics in isolated photosystem I (PSI) complexes from Arabidopsis thaliana depleted of the PSI-G, PSI-K, P…
2002
Abstract Green plant photosystem I (PSI) consists of at least 18 different protein subunits. The roles of some of these protein subunits are not well known, in particular those that do not occur in the well characterized PSI complexes from cyanobacteria. We investigated the spectroscopic properties and excited-state dynamics of isolated PSI-200 particles from wild-type and mutant Arabidopsis thaliana plants devoid of the PSI-G, PSI-K, PSI-L, or PSI-N subunit. Pigment analysis and a comparison of the 5K absorption spectra of the various particles suggests that the PSI-L and PSI-H subunits together bind approximately five chlorophyll a molecules with absorption maxima near 688 and 667nm, that…
Ultrafast excitation dynamics of low energy pigments in reconstituted peripheral light-harvesting complexes of photosystem I
2000
AbstractUltrafast dynamics of a reconstituted Lhca4 subunit from the peripheral LHCI-730 antenna of photosystem I of higher plants were probed by femtosecond absorption spectroscopy at 77 K. Intramonomeric energy transfer from chlorophyll (Chl) b to Chl a and energy equilibration between Chl a molecules observed on the subpicosecond time scale are largely similar to subpicosecond energy equilibration processes within LHCII monomers. However, a 5 ps equilibration process in Lhca4 involves unique low energy Chls in LHCI absorbing at 705 nm. These pigments localize the excitation both in the Lhca4 subunit and in LHCI-730 heterodimers. An additional 30–50 ps equilibration process involving red …
Inhibitory Effects of the Insecticides Allethrin, Lindane, and Jacutin-Fogetten Sublimate on Photosynthetic Electron Transport
1979
Abstract The inhibitory effects of the insecticides Allethrin, Lindane, and Jacutin-Fogetten sublimate on photosynthetic electron transport of broken chloroplasts were tested. 50 μmol l-1 Allethrin caused an inhibition of 80% of the benzoquinone and ferricyanide Hill-reactions. 39 μmol l-1 Lindane inhibited the basal, coupled and uncoupled electron transport to ferricyanide up to 35%. The precipitate formed by the sublimation of Jauctin-Fogetten containing Lindane depressed electron transport much more than pure Lindane. 50 μg ml-1 of the sublimate led to an 80% inhibition of ferricyanide Hill-reaction.
Oxidative stress induces distinct physiological responses in the two Trebouxia phycobionts of the lichen Ramalina farinacea
2010
† Background and Aims Most lichens form associations with Trebouxia phycobionts and some of them simultaneously include genetically different algal lineages. In other symbiotic systems involving algae (e.g. reef corals), the relative abundances of different endosymbiotic algal clades may change over time. This process seems to provide a mechanism allowing the organism to respond to environmental stress. A similar mechanism may operate in lichens with more than one algal lineage, likewise protecting them against environmental stresses. Here, the physiological responses to oxidative stress of two distinct Trebouxia phycobionts (provisionally named TR1 and TR9) that coexist within the lichen R…
The organic air pollutant cumene hydroperoxide interferes with NOantioxidant role in rehydrating lichen
2013
Organic pollutants effects on lichens have not been addressed. Rehydration is critical for lichens, a burst of free radicals involving NO occurs. Repeated dehydrations with organic pollutants could increase oxidative damage. Our aim is to learn the effects of cumene hydroperoxide (CP) during lichen rehydration using Ramalina farinacea (L.) Ach., its photobiont Trebouxia spp. and Asterochloris erici. Confocal imaging shows intracellular ROS and NO production within myco and phycobionts, being the chloroplast the main source of free radicals. CP increases ROS, NO and lipid peroxidation and reduces chlorophyll autofluorescence, although photosynthesis remains unaffected. Concomitant NO inhibit…
Different strategies to achieve Pb-tolerance by the two Trebouxia algae coexisting in the lichen Ramalina farinacea.
2012
Lichen thalli are permeable to airborne substances, including heavy metals, which are harmful to cell metabolism. Ramalina farinacea shows a moderate tolerance to Pb. This lichen comprises two Trebouxia phycobionts, provisionally referred to as TR1 and TR9, with distinct physiological responses to acute oxidative stress. Thus, there is a more severe decay in photosynthesis and photosynthetic pigments in TR1 than in TR9. Similarly, under oxidative stress, antioxidant enzymes and HSP70 protein decrease in TR1 but increase in TR9. Since Pb toxicity is associated with increased ROS formation, we hypothesized greater Pb tolerance in this phycobiont. Accordingly, the aim of the present study was …