Search results for "Physical properties"
showing 10 items of 44 documents
Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium(III) complex
2007
A new, but archetypal compound [ Ir( ppy- F-2) (2)Me(4)phen] PF6, where ppy- F2 is 2-(2',4'- fluorophenyl) pyridine and Me(4)phen is 3,4,7,8- tetramethyl- 1,10- phenanthroline, was synthesized and used to prepare a solid-state light-emitting electrochemical cell (LEEC). This complex emits blue light with a maximum at 476 nm when photoexcited in a thin film, with a photoluminescence quantum yield of 52%. It yields an efficient single-component solid-state electroluminescence device with a current efficiency reaching 5.5 cd A(-1) and a maximum power efficiency of 5.8 Lm Watt(-1). However, the electroluminescence spectrum is shifted with respect to the photoluminescence spectrum by 80 nm resul…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2014
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4'-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2':6',2''-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4'-(4-bromophenyl)-2,2':6',2''-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2015
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4′-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2′:6′,2′′-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4′-(4-bromophenyl)-2,2′:6′,2′′-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Reduction of saturated fat in chocolate by using sunflower oil-hydroxypropyl methylcellulose based oleogels
2021
The suitability of sunflower oil-hydroxypropyl methylcellulose (HPMC) based oleogel obtained by emulsion template approach as partial cocoa butter (CB) replacer in chocolates was investigated. A level of 50% CB replacement was optimum, as higher level of replacement affected the sensory appearance in comparison to the control chocolate (without added oleogel). Four levels of HPMC (0.5, 1, 1.5 and 2%) were considered. Textural and calorimetric properties, as well as sensory properties obtained by Free Choice Profile of the formulated chocolates were investigated. Partial replacement of CB by the sunflower-HPMC based oleogel reduced significantly the chocolate hardness. Higher HPMC concentrat…
Geomorphological, chemical and physical study of “calanchi” landforms in NW Sicily (southern Italy)
2012
Abstract This work deals with an integrated geomorphological and chemical–physical study of “calanchi” landforms in two sites (Ottosalme and Catalfimo) of NW Sicily (southern Italy), developed on dominant silty-clay deposits. The calanchi fronts are characterized by different morphological features and dominant geomorphic processes. Sharp knife-edged ridges and concentrated water runoff dominate at Ottosalme, and smoother landforms affected by mass movements (mud flows and translational slides) prevail at Catalfimo. We focused on some geochemical and physical parameters such as pH , total dissolved salts, sodium adsorption ratio ( SAR ), porosity, plastic and liquid limits as possible cause…
Sustainability in the restoration and management of the historic architecture in Palermo
2015
This research investigates the energy and environmental sustainability in the restoration and conservation of historic buildings. It focuses on the architectural heritage of Palermo, which can be a significant case study for the Mediterranean area. Its objective is to analyse the current energy performance of this historic architecture and its potential for energy improvement. Therefore, it aims at proposing a methodology to combine the enhancement of energy and environmental performances of the historic architecture of Palermo with the need of its material and aesthetic conservation, in the frame of the current regulations.
Анализ и оптимизация устойчивости балок на сплошном упругом основании часть I (балки конечной длины) [Analysis and optimization of a beam on elastic …
2017
Problems of defining the optimal (against buckling) cross section area distribution for beams interacting with elastic foundation are considered. The stability of limited pinned beams and infinite continuous beams is analyzed. For all beams under consideration, the stability analysis is performed as for constant as for variable distributions of strength beam characteristics. The critical length is determined and the variational statement of beam stability problems is presented for this beam type. The exact solution of optimal problem is presented in the case of linear dependence of limited beam bending hardness on beam cross section area. For the case of squared and cubic dependences, the n…
Анализ и оптимизация устойчивости балок на сплошном упругом основании часть II (бесконечные балки) [Analysis and optimization of a beam on elastic fo…
2017
Problems of defining of optimal (against buckling) cross section area distribution for beams interacting with elastic foundation are considered. The stability of limited pinned beams and infinite continuous beams is analyzed. For all beams under consideration, the stability analysis is performed as for constant as for variable distributions of strength beam characteristics. The critical length is determined and the variational statement of beam stability problems is presented for this beam type. For infinite continuous beams, the stability problems are investigated as for constant as for periodic distribution of strength characteristics. In the second case, the analysis of infinite beam can…
Effects of saliva and nasal secretion on some physical properties of four different resin materials
2009
WOS: 000284036700028
Dissemination/Communication Plan. Period concerning the plan: 01.01.2018-31.12.2020.
2018
The plan concerning different dissemination/communication activities during three years of the project implementation is given. Scientific results are proposed to be disseminated in well-recognized bi-annual international conferences, such as European Conference on Composite Materials (ECCM) and International Conference on Composite Materials (ICCM). Self-archiving of the main project results is planned within subject-based open-access repositories, such as ResearchGate and Zenodo. Two scientific publications in Q1-Q2 SCI journals and two popular scientific publications in popular scientific Latvian journals are foreseen. All data files obtained within the project are to be stored in centra…