Search results for "Physics::Optics"

Optical and Acoustic Vibrations Confined in Anatase TiO2 Nanoparticles under High-Pressure

2014

International audience; The effect of an applied high pressure on the optical and acoustic vibrations of small anatase TiO2 nanoparticles is studied using Raman scattering. All the Raman peaks show a significant variation of their frequency with pressure, except for the low-frequency peak which is due to acoustic vibrations confined in the nanoparticles. These variations (or lack thereof) are compared to first-principles calculations of the stiffness tensor and phonons of bulk anatase TiO2 as a function of pressure. In particular, the variation of the shape of the low-frequency peak is explained by the increase of the elastic anisotropy of anatase TiO2 as pressure is increased.

Reversible Photodoping of TiO2 Nanoparticles for Photochromic Applications

2018

Financial support from the Estonian Research Council (IUT2-25, IUT2-26, and PUTJD680) is gratefully acknowledged. This work was supported by the Academy of Finland (decision numbers 141481 and 286713) and by the EU through the European Regional Development Fund (Center of Excellence for Zero Energy and Resource Efficient Smart Buildings and Districts-ZEBE, 2014-2020.4.01.15-0016). Work is supported by the Latvian Academy of Sciences in the framework of FLPP (Plasmonic oxide quantum dots for energy saving smart windows, lzp-2018/1-0187).

Local Berry curvature signatures in dichroic angle-resolved photoelectron spectroscopy from two-dimensional materials

2020

Orbital polarization and Berry curvature signatures are mapped out by circular dichroism in angle-resolved photoemission.

Extraordinary tuning of a nanocavity by a near-field probe

2011

Abstract We report here an experimental observation of an extraordinary near-field interaction between a local probe and a small-volume solid-state nanocavity. We directly compare the normally observed near-field interaction regime driven by the perturbation theory and then report the extraordinary interaction regime. Subsequently, we show that the cavity can take up to 2 min to recover from this interaction after removing the probe and that leads to an extraordinary blue-shift of the cavity resonance wavelength (∼15 nm) which depends on the probe motion above the cavity and not the position. The reasons for this effect are not fully understood yet but we try to give some explanations.

Influence of annealing atmosphere on photoelectrochemical response of TiO2 nanotubes anodized under controlled hydrodynamic conditions

2021

[EN] The influence of three annealing atmospheres (air, nitrogen and argon) and the use of controlled hydrodynamic conditions (from 0 to 5000 rpm) on morphological, structural, chemical and photoelectrochemical properties of TiO2 nanotubes have been evaluated. For this purpose, different characterization techniques have been used: Field Emission Scanning Electron Microscopy, Raman Confocal Laser Spectroscopy, X-Ray Diffraction, X-Ray Photoelectron Spectroscopy, Incident Photon-to-electron Conversion Efficiency measurements, ultraviolet-visible absorption spectra, Mott-Schottky analysis and photoelectrochemical water splitting tests. According to the results, it can be concluded that both hy…

O2 Diffusion in Amorphous SiO2 Nanoparticles Probed by Outgassing

2012

An experimental study of the O2 diffusion process in nanoparticles of amorphous SiO2 in the temperature range from 98 to 157 °C was carried out by Raman and photoluminescence techniques. We studied O2 diffusion in high purity silica nanoparticles with a mean diameter of 14, 20, and 40 nm detecting the outgassing of molecules trapped during the manufacturing. The kinetics of diffusion is well described for all the investigated nanoparticles by the Fick’s equation proving its applicability to nanoscale systems. The diffusion coefficient features an Arrhenius law temperature dependence in the explored temperature range, and the diffusion coefficient values are in good agreement with extrapolat…

New Twists of 3D Chiral Metamaterials

2018

Rationally designed artificial materials, called metamaterials, allow for tailoring effective material properties beyond ("meta") the properties of their bulk ingredient materials. This statement is especially true for chiral metamaterials, as unlocking certain degrees of freedom necessarily requires broken centrosymmetry. While the field of chiral electromagnetic/optical metamaterials has become rather mature, the field of elastic/mechanical metamaterials is just emerging and wide open. This research news reviews recent theoretical and experimental progress concerning 3D chiral mechanical and optical metamaterials, with special emphasis on work performed at KIT.

A New Method for Determining the Ångström Turbidity Coefficient from Broadband Filter Measurements

2000

Abstract In this work, a new method for determining Angstrom turbidity coefficients is presented. This method is based on broadband filter irradiance measurements. By combining measurements obtained with different filters it is possible to obtain a single value of the turbidity coefficient representative of the whole measurement range of the pyrheliometer. The results provided by this new method are compared with the original Angstrom method and turbidity coefficient values derived by spectroradiometric measurements. The results reproduce the actual values, as measured by a spectroradiometer, better than the previous best correlation did, thus demonstrating the advantage of analyzing the op…

2020

Abstract. An ice cloud chamber was developed at the Johannes Gutenberg University of Mainz for generating several thousand data points for mass and sedimentation velocity measurements of ice crystals with sizes less than 150 µm. Ice nucleation was initiated from a cloud of supercooled droplets by local cooling using a liquid nitrogen cold finger. Three-dimensional tracks of ice crystals falling through the slightly supersaturated environment were obtained from the reconstruction of sequential holographic images, automated detection of the crystals in the hologram reconstructions, and particle tracking. Through collection of the crystals and investigation under a microscope before and after …

Effects of ice crystal habit on thermal infrared radiative properties and forcing of cirrus

2007

[1] The impact of assumed ice crystal morphology on thermal infrared (IR) radiative properties of subtropical cirrus is quantified. In particular, the crystal-shape-dependent profiles of downwelling and upwelling thermal IR (broadband and spectral) irradiances and the radiative forcing of cirrus (at the top and bottom of the atmosphere) are investigated. For this purpose, airborne measurements of ice crystal size distribution (in terms of ice crystal maximum dimension) from the CRYSTAL-FACE campaign and a recently published library of thermal IR optical properties of nonspherical ice crystal habits are implemented into radiative transfer simulations. Two cirrus cases are studied in detail: …