Search results for "Pitting corrosion"
showing 6 items of 36 documents
Renforcement de la résistance à la corrosion localisée de l’acier inoxydable 304L grâce au traitement de surface par laser impulsionnel
2013
L’acier inoxydable 304L est utilise dans de nombreux domaines. Cependant, il peut, dans certaines conditions, etre sensible a la corrosion par piquration. Dans cette etude, nous nous sommes interesses aux potentialites du traitement de fusion superficielle par laser nanopulse pour l’amelioration de la resistance a la corrosion de cet acier. Ce traitement consiste a focaliser un faisceau laser sur la surface du materiau, provoquant sa fusion quasi instantanee sur quelques microns, immediatement suivie d’un refroidissement ultra-rapide allant jusqu’a 1011 K/s. Les parametres laser impliquent des modifications des proprietes physico-chimiques. Nous avons notamment etudie l’influence du recouvr…
The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels
2007
Abstract In this paper, the electrochemical microcell technique is combined with ex situ (SIMS and XPS) and in situ (SVET) techniques to study the electrochemical behaviour and pitting corrosion of inclusion-contaning stainless steels. Dissolution of metallurgical heterogeneities, depassivation and pitting mechanisms are first discussed in 1 M NaClO4, pH 3, and 1 M NaCl, pH 3, by considering the chemical composition and morphology of inclusions. The influence of the chemical composition of passive films on the electrochemical reactions and the microgalvanic coupling processes occurring at the corrosion potential is also investigated on the same specimen microstructure.
The use of linear regression methods and Pearson’s correlation matrix to identify mechanical–physical–chemical parameters controlling the micro-elect…
2008
Abstract Machining introduces residual stresses at the specimen surface and modifies the microstructure and the texture in a small volume close to the surface. Such changes are important in controlling the corrosion behaviour of machined workpieces in the presence of an aggressive environment. In the present paper, the relationships between cutting parameters and the surface and subsurface characteristics of machined copper were first quantified experimentally using a complete plan of L 8 (2 3 ) and a linear regression method. The influence of surface characteristics on the local polarisation curves of machined surfaces was then investigated. The shear-type crystallographic orientation gene…
Recent advances in local probe techniques in corrosion research – Analysis of the role of stress on pitting sensitivity
2007
Local probe techniques have been largely applied to predict the spatial distribution of the electrochemical reactions and to quantify the corrosion rate. These local probe techniques are now being developed to capture the temporal information, in-situ and in real-time. Nevertheless only few works have been devoted to investigate with these local probes the role of stress on pitting sensitivity on passive materials. In this paper, a part of the most recent studies based on combination of local electrochemical measurements with finite element mapping of surface stress gradients are reported illustrating the role of inclusions under straining and the mechanical effect of surface preparation on…
Hand verification for flexural strength of existing R.C. floors subject to degradation phenomena
2015
Abstract In the present paper, a simplified model for hand verification of the flexural and shear strength of existing corroded T beams cast in place of lightened R.C. orthotropic slabs forming floors is presented and discussed. Diffused and pitting corrosion on steel bars, compressive concrete strength degradation and concrete bond strength degradation are included in the model. The original contribution of the paper is evaluation of the flexural and shear strength considering both the cases of strain compatibility and absence of compatibility and considering the main parameters governing the corrosion process. An arch-resistant model for the calculus of the flexural and shear strength of …
A Mössbauer study of the crystalline structure of the passive film formed on iron in aqueous sulfate solution containing sulfite in low concentration
1993
Electrochemically induced passivation of evaporated, enriched 57Fe in 0.5 mol dm−3 Na2SO4 + 0.001 mol dm−3 NaHSO3 aqueous solution (pH 6.5) was followed by conversion electron Mossbauer spectroscopy. The transformation of amorphous iron oxide or hydroxide into crystalline γ-FeOOH could be observed with the increase of the polarization time. The comparison of the original quantity of evaporated, enriched 57Fe layer on the surface of the samples with the dissolved iron, measured in the solutions after the polarization, proved the existence of pitting corrosion at this pH.