Search results for "Pitting"
showing 10 items of 43 documents
Electrochemical Impedance Spectroscopy Study of the Behaviour of Lanthanide-Rich Films Formed on Aluminium-Magnesium Alloys
1998
The film covering formed on AA5083 aluminium-magnesium alloy by immersion treatments in solutions containing CeCl 3 has been characterized by means of electrochemical techniques. The measurement of linear polarization has enabled to establish that the treatments applied provide efficient protection against both uniform and pitting corrosion of alloy AA5083, used in shipbuilding, in solutions of NaCl. This study has been focused on the use of Electrochemical Impedance Spectroscopy as a characterization technique for these film coverings.
Influence of applied strain on the microstructural corrosion of AlMg2 as-cast aluminium alloy in sodium chloride solution
2012
International audience; The corrosion behavior of ISO AlMg2 (AA5052) was studied at the microscale using the Electrochemical Microcell Technique. The influence of plastic deformation on the corrosion resistance of this alloy was also examined. After polishing, pitting at small copper-enriched precipitates and structural etching were observed. After deformation, numerous slip bands were found in grains. After 5.5% plastic strain, the global electrochemical behavior of samples was significantly affected. Pitting potential was decreased in sites containing slip bands or in sites with large strain gradients (measured using microgauges deposited by lithography).
A Mechanical–Electrochemical Approach for the Determination of Precursor Sites for Pitting Corrosion at the Microscale
2006
International audience; The influence of metallurgical defects and residual surface stresses generated by polishing on the pitting susceptibility of duplex stainless steels was studied by combining macro- and microelectrochemical measurements with thermal-mechanical simulation and metallography tests. It has been shown that pits initiate in both phases at metallurgical point defects (such as oxide inclusions in the ferrite and dislocation lines in the austenite). By contrast, the surface stress state was the driving force for pit initiation along the austenite/ferrite interface. Experiments at the macroscale revealed that this process represents about 40% of the total number of pits observe…
A simple model for the calculation of the axial load-carrying capacity of corroded RC columns
2015
In the present paper, a simplified model is used to determine the axial load-carrying capacity of compressed short reinforced concrete columns subjected to corrosion processes. The model considers members with circular and square cross-sections and accounts for—cover spalling, —concrete core confinement induced by transverse steel reinforcement, —buckling of longitudinal reinforcing bars. Strength reduction in concrete cover and core due to cracking induced by rust formation, reduction of steel area in longitudinal bars and transverse stirrups due to general and pitting corrosion and loss of confinement pressure are considered. The load-carrying capacity and load-axial strain curves here ge…
Shear and flexural strength prediction of corroded R.C. beams
2017
Abstract The purpose of the work was the study of the structural safety of R.C. beams subjected to corrosion processes though the derivation of moment-curvature diagrams and moment-to-shear interaction diagrams. Normal-strength reinforced concrete beams with longitudinal bars in the presence of transverse stirrups and subjected to corrosion processed are considered. Experimental results available in the literature related to corrosion processes, for steel bars, crack openings and bond degradation due to rust formation are reviewed. Then analytical laws relating to crack opening, bond degradation with attack penetration depth, through a rearranged form of Faraday’s law, are presented. An ana…
Risk of failure in existing RC balcony and strength verification under degradation phenomena
2020
Abstract In the present paper, the safety conditions of reinforced concrete (RC) balconies subject to degradation phenomena caused by carbonation, presence of chlorides or water infiltration were examined. After a brief review of the typical damages of balconies occurring with detachments of plaster and bricks expulsion, some cases of collapses of balconies recently occurred were presented. Therefore, a calculation model was proposed for a hand verification of the flexural and shear strength of existing corroded T beams cast in place of lightened RC orthotropic slabs forming the balcony and for the calculus of deflection including slippage of steel bars. Diffused and pitting corrosion on st…
Role of plastic deformation and microstructure in the micro-electrochemical behaviour of Ti–6Al–4V in sodium chloride solution
2013
Abstract The role of alloying elements and the influence of plastic deformation on the micro-electrochemical behaviour and the pitting corrosion susceptibility of TiAl6V4 have been investigated in 10 g/L NaCl using the electrochemical microcell technique. Local electrochemical measurements have revealed that both the increase of surface roughness and the increase of dislocation density have impact on the electrochemical behaviour of TiAl6V4 after plastic deformation. It has been shown the surface roughness induced by slip band emergence is the predominant parameter responsible for the increase of the cathodic current. It has also been shown that cathodic reactions occur preferentially at su…
Influence of the microstructure and laser shock processing (LSP) on the corrosion behaviour of the AA2050-T8 aluminium alloy
2011
International audience; The corrosion behaviour of AA2050-T8 was studied after polishing and after laser shock processing (LSP) treatment using the electrochemical microcell technique and the SVET. After polishing, pitting at constituent particles and intergranular corrosion were observed. By contrast, no intergranular corrosion developed after LSP. Microcell measurements revealed that LSP increases the pitting potential. SVET measurements revealed that local anodic currents are systematically lower on LSP-treated surfaces than on polished ones. The current density on the LSP-treated surface remains constant around 50 μA cm−2 up to 123 min after immersion, while on the polished surface it r…
Mechanical properties and corrosion behaviour of low carbon martensitic stainless steel after machining
2014
The influence of different combinations of cutting conditions on the mechanical behaviour (microhardness), the microstructure and the corrosion behaviour in NaCl solution (using the electrochemical microcell technique and pulse potentiodynamic testing) of a low carbon martensitic stainless steel (grade X4CrNiMo16.5.1 stainless steel) after tempering treatment was studied. Microhardness was increased on the machined surface. In addition, the electrochemical experiments have shown that the machined materials have a heterogeneous electrochemical behaviour. Significant effect of machining on pitting corrosion was noticed. The pitting potential was found to decrease as the microhardness increase…
Use of the electrochemical microcell technique and the SVET for monitoring pitting corrosion at MnS inclusions
2004
The purpose of this paper is to report on use of the electrochemical microcell technique and the scanning vibrating electrode technique for monitoring pitting corrosion on the same stainless steel microstructure. First, the electrochemical behaviour of sites containing a single inclusion was investigated in order to the determine both the successive steps occurring during the inclusions activation and some key-parameters such as the onset potential for MnS dissolution and the pitting potential. Then, the local current distribution around a pitting site was monitored at open circuit potential in order to locate anodic and cathodic regions and to obtain informations on the galvanic coupling b…