Search results for "Plasmon"
showing 10 items of 614 documents
Colloidal Self-assembled Nanosphere Arrays for Plasmon-enhanced Light Trapping in Thin Film Silicon Solar Cells
2014
To realize high-efficiency thin-film silicon solar cells it is crucial to develop light-trapping methods that can increase absorption of the near- bandgap light in the silicon material. That can be achieved using the far-field scattering properties of metal nanoparticles (MNP) sustaining surface plasmons. The MNPs should be inserted in the back of the cell, embedded in the transparent conductive oxide (TCO) layer which separates the rear mirror from the silicon layers. In this way, a plasmonic back reflector (PBR) is constructed that can redirect light at angles away from the incidence direction and thereby increase its path length in the cell material. In this work, a novel technique is pr…
Manipulating and squeezing the photon local density of states with plasmonic nanoparticle networks
2010
International audience; In this Brief Report, we show that when interconnected networks of gold particles are deposited onto a clean planar surface, they strongly modify the photonic local density of states LDOS in the immediate proximity of the self-assembled nanoparticles. They represent unique architectures for the subwavelength patterning of initially flat photonic LDOS. Moreover, we show that their local spectral signatures are well suited for the generation of sites able to enhance molecular fluorescence intensity.
Self Calibrating Nano-Ruler
2012
The aim of a nanoruler is to measure distances on a length scale in the order of nanometers. This concept can be realized by two plasmonic nanoparticles (usually spheres), which are placed within a short distance to each other. Since the plasmon modes of both particles are coupled, they influence each other along the interparticle axis (i.e. longitudinal plasmon mode, resulting in a shift of the resonance wavelength compared to the single particle. Because the resulting resonance wavelength depends on the interparticle distance, the spectral investigation of such a dimer allows the determination of the interparticle distance.
Génération et détection d'électrons chauds dans des dispositifs plasmoniques
2021
Hot carrier-based devices are quite promissing for ultrafast photodetection and toset off enhanced physicochemical reactions. Controlling their generation at the nanoscale within plasmonic devices is a key for the future development of hybrid hot carriers technologies. Indeed, Surface PlasmonPolaritons (SPPs) can be exploited to confine light and enhance the number of excited hot carriers. We aim at studying the excitation and dynamics of hot carriers, enhanced by plasmonics, with two different approaches.In a first approach, we aim at controlling the delocalized generation of hot carriers by a propagative SPP. A plasmonic waveguide with a grating coupler is employed. Hot electrons are indi…
Gold nanostars co-coated with the Cu(II) complex of a tetraazamacrocyclic ligand
2015
The twelve-membered tetraazamacrocyclic ligand L1 bears an appended lipoic acid unit, whose disulphide ring is an efficient grafting moiety for the surface of gold nanostars (GNS). The GNS that were used featured a localized surface plasmon resonance (LSPR) absorption at ∼800 nm, i.e. in the near infrared (NIR). We investigated different approaches for coating them with the Cu(2+) complex of L1. While the direct reaction of [CuL1](2+) with as-prepared GNS led to aggregation, an initial coating step with polyethyleneglycol-thiol (PEG-SH) was found to be advantageous. Displacement reactions were carried out on pegylated GNS either with [CuL1](2+), directly generating [Cun(L1@GNS)](2n+), or wi…
Construction of Chimeric Dual-Chain Avidin by Tandem Fusion of the Related Avidins
2011
BackgroundAvidin is a chicken egg-white protein with high affinity to vitamin H, also known as D-biotin. Many applications in life science research are based on this strong interaction. Avidin is a homotetrameric protein, which promotes its modification to symmetrical entities. Dual-chain avidin, a genetically engineered avidin form, has two circularly permuted chicken avidin monomers that are tandem-fused into one polypeptide chain. This form of avidin enables independent modification of the two domains, including the two biotin-binding pockets; however, decreased yields in protein production, compared to wt avidin, and complicated genetic manipulation of two highly similar DNA sequences i…
Power monitoring in dielectric-loaded surface plasmon-polariton waveguides
2011
We report on propagating mode power monitoring in dielectric-loaded surface plasmon-polariton waveguides (DLSPPWs) by measuring the resistance of gold stripes supporting the DLSPPW mode propagation. Inevitable absorption of the DLSPPW mode in metal causes an increase in the stripe temperature and, thereby, in its resistance whose variations are monitored with an external Wheatstone bridge being accurately balanced in the absence of radiation in a waveguide. The investigated waveguide configuration consists of a 1-µm-thick and 10-µm-wide polymer ridges tapered laterally to a 1-µm-wide ridge placed on a 50-nm-thin and 4-µm-wide gold stripe, all supported by a magnesium fluoride substrate. Usi…
Fiber-coupled dielectric-loaded plasmonic waveguides.
2010
Fiber in- and out-coupling of radiation guided by dielectric-loaded surface plasmon-polariton waveguides (DLSPPWs) is realized using intermediate tapered dielectric waveguides. The waveguide structures fabricated by large-scale UV-lithography consist of 1-microm-thick polymer ridges tapered from 10-microm-wide ridges deposited directly on a magnesium fluoride substrate to 1-microm-wide ridges placed on a 50-nm-thick and 100-microm-wide gold stripe. Using fiber-to-fiber transmission measurements at telecom wavelengths, the performance of straight and bent DLSPPWs is characterized demonstrating the overall insertion loss below 24 dB, half of which is attributed to the DLSPPW loss of propagati…
Podoplanin serum and urine concentration in transitional bladder cancer
2016
Background Podoplanin (PDP) is a mucin - a type of transmembrane protein expressed in numerous tissues during ontogeny and in adult animals, including the brain, heart, kidney, osteoblasts and lymphoid organs. Objective The aim of this study was to determine podoplanin concentration in the blood serum and urine of patients with bladder cancer. Quantifying podoplanin concentration and its correlation with various clinicopathological parameters may be useful for more accurate predictions and identifying high-risk patients. Methods The present study included 82 patients with bladder cancer confirmed by transurethral resection or cystectomy and 27 healthy volunteers. The Surface Plasmon Resonan…
Patients with colorectal tumors with microsatellite instability and large deletions in HSP110 T17 have improved response to 5-fluorouracil–based chem…
2014
Background & Aims Patients with colorectal tumors with microsatellite instability (MSI) have better prognoses than patients with tumors without MSI, but have a poor response to 5-fluorouracil–based chemotherapy. A dominant-negative form of heat shock protein (HSP)110 (HSP110DE9) expressed by cancer cells with MSI, via exon skipping caused by somatic deletions in the T 17 intron repeat, sensitizes the cells to 5-fluorouracil and oxaliplatin. We investigated whether HSP110 T 17 could be used to identify patients with colorectal cancer who would benefit from adjuvant chemotherapy with 5-fluorouracil and oxaliplatin. Methods We characterized the interaction between HSP110 and HSP110DE9 using su…